研究目的
To develop a mild strategy for coating cotton fabrics with Cu2(OH)PO4 nanoparticles to achieve self-cleaning properties under visible and near-infrared irradiation.
研究成果
The CHP-IP6 coated cotton fabrics exhibit high photocatalytic activity and stability under visible and NIR irradiation, with effective self-cleaning properties. This suggests potential applications in textiles such as tablecloths, household apparel, and industrial workwear, contributing to energy-saving and environmental protection.
研究不足
The study is limited to laboratory-scale experiments; scalability and long-term durability under real-world conditions are not addressed. The photocatalytic efficiency under NIR light is lower compared to visible light, and the method may require optimization for industrial applications.
1:Experimental Design and Method Selection:
A mild hydrothermal method using phytic acid (IP6) as a soft template was employed to synthesize Cu2(OH)PO4 nanoparticles. The nanoparticles were then coated onto cotton fabrics using a process involving silane coupling agents and dopamine for immobilization.
2:Sample Selection and Data Sources:
White plain weave 100% cotton fabric was used as the substrate. Methylene blue (MB) was used as a model pollutant for photocatalytic degradation tests.
3:List of Experimental Equipment and Materials:
Cotton fabric, Cu(NO3)2·3H2O, Na2HPO4·2H2O, phytic acid (IP6), dopamine, glutaraldehyde, KH550, ethanol, deionized water, MB, hydrogen peroxide. Equipment included XRD, FTIR, SEM, TEM, EDX, XPS, TGA, UV-Vis-NIR spectrophotometer, color spectrophotometer, atomic absorption spectrometer.
4:Experimental Procedures and Operational Workflow:
Synthesis of CHP-IP6 nanoparticles via hydrothermal method at 120°C for 8 hours. Coating of nanoparticles onto cotton fabrics using KH550 and dopamine for functionalization. Characterization of materials using various spectroscopic and microscopic techniques. Photocatalytic activity tests under visible and NIR light using a xenon lamp with cut-off filters, monitoring MB degradation. Self-cleaning tests by applying MB stains and exposing to sunlight.
5:Data Analysis Methods:
Degradation efficiency calculated as C/Co from UV-Vis absorbance at 665 nm. Specific surface area and pore size determined by BET and BJH methods. Elemental analysis via EDS and XPS. Thermal stability assessed by TGA.
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X-ray diffractometer
D8-advance
Bruker
Characterization of crystalline structure of samples
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FTIR spectrometer
IRPrestige-21
Shimadzu
Recording FTIR spectra of samples
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SEM
JSM-6700F
JOEL
Studying morphologies of samples
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EDS
Oxford X-Max
Oxford Instruments
Energy dispersive spectroscopy for component verification
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UV-VIS-NIR spectrophotometer
U4100
Hitachi
Recording diffuse reflectance spectra
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UV-Vis spectrophotometer
UV-1080
Hitachi
Determining MB concentration at 665 nm
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TEM
Philips CM120
Philips
Studying morphologies of samples
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XPS
Quantum 2000
Physical Electronics
Analysis of surface chemical composition
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Atomic absorption spectrometer
TAS-990AFG
Beijing Purkinje General Instrument Co. Ltd.
Analysis of Cu(II) ion concentration
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Color spectrophotometer
Color-Eye 7000A
X-Rite
Testing K/S values for color strength
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TGA
Q500
TA
Thermogravimetric analysis
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Xenon lamp
Light source for photocatalytic tests
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