研究目的
Investigating the photoluminescence characteristics of Sm3+-doped LnBWO6 (Ln=La, Gd and Y) phosphors as new orange-red phosphors for potential application in white LEDs.
研究成果
Sm3+-doped LnBWO6 phosphors, especially LaBWO6, exhibit strong orange-red emission under near-UV and blue excitation with good thermal stability. The concentration quenching is due to dipole-dipole interaction, and the materials show potential for use in white LEDs.
研究不足
The quantum efficiency of the samples is low, possibly due to irregular morphology from the solid-state synthesis method. The energy transfer between the host and Sm3+ ions is inefficient, and some emission behaviors under specific excitations need further investigation.
1:Experimental Design and Method Selection:
High-temperature solid-state reaction method was used to prepare Sm3+-doped LnBWO6 phosphors. The rationale was to synthesize pure phase phosphors for luminescence studies. Theoretical models included Van Uitert's model for concentration quenching and equations for critical distance and activation energy.
2:Sample Selection and Data Sources:
Samples were prepared with varying Sm3+ concentrations in LaBWO6, GdBWO6, and YBWO6 hosts. Raw materials included H3BO3, WO3, La2O3, and Sm2O3, all of analytical or high purity grade.
3:List of Experimental Equipment and Materials:
Equipment included Panalytical X'pert pro X-ray diffractometer, Lambda 650S spectrophotometer, Cary Eclipse fluorescence spectrophotometer, Edinburgh Instruments FL980 UV-vis-NIR spectrophotometer, HAAS-2000 color analyzer, C9920-02 quantum yield measurement system, and EX-1000 thermal quenching analyzer. Materials included agate mortar, alumina crucible, muffle furnace, and BaSO4 reference.
4:Experimental Procedures and Operational Workflow:
Raw materials were weighed, ground, sintered at 950°C for 10h, and cooled. XRD, diffuse reflectance, PL spectra, decay lifetimes, CIE coordinates, quantum yield, and temperature-dependent PL were measured at room temperature.
5:Data Analysis Methods:
Data were analyzed using fitting with exponential functions, calculation of critical distance and activation energy, and linear regression for concentration quenching mechanism.
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X-ray diffractometer
X'pert pro
Panalytical
Recording powder X-ray diffraction patterns of the phosphors.
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Spectrophotometer
Lambda 650S
Perkin Elmer
Recording diffuse reflectance spectra.
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Fluorescence spectrophotometer
Cary Eclipse
Agilent Technologies
Recording photoluminescence emission and excitation spectra.
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Spectrophotometer
FL980 UV-vis-NIR
Edinburgh Instruments
Conducting decay lifetimes measurements.
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Quantum yield measurement system
C9920-02
Hamamatsu
Measuring photoluminescence quantum yield.
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Color analyzer
HAAS-2000
Everfine
Measuring CIE 1931 chromaticity coordinates.
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Thermal quenching analyzer
EX-1000
Everfine
Recording temperature-dependent PL emission spectra.
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Agate mortar
Grinding raw materials.
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Alumina crucible
Holding mixed powders for sintering.
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Muffle furnace
Sintering samples at high temperature.
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