研究目的
To combat surface fogging by developing transparent metasurfaces that harness sunlight for localized heating to delay fogging onset and reduce defogging time, outperforming existing methods like superhydrophilic and superhydrophobic coatings.
研究成果
The metasurfaces significantly improve anti-fogging and defogging performance by harnessing sunlight for localized heating, reducing defogging time by up to four-fold and inhibiting condensation under supersaturated conditions. They outperform conventional superhydrophilic and hydrophobic coatings in visibility retention, offering a durable and sustainable passive solution for various transparent applications, with potential for large-scale manufacturing on flexible substrates.
研究不足
The metasurfaces have reduced visible light transmittance (36%) compared to glass (87%), which may not be suitable for all applications requiring high transparency. The study is limited to laboratory conditions and specific sample sizes; scalability and long-term durability in real-world environments were not fully assessed. The experimental setup used controlled supersaturation and illumination, which may not fully replicate all environmental variations.
1:Experimental Design and Method Selection:
The study involved designing and fabricating metasurfaces using sputter deposition of gold nanoparticles and titanium dioxide layers on glass substrates. Experiments included clarity and distortion measurements, single droplet evaporation tests, defogging tests, and anti-fogging performance evaluations under supersaturated conditions. Theoretical models for clarity (C) and distortion (δ) were used, along with infrared thermography for temperature measurements.
2:Sample Selection and Data Sources:
Samples included untreated glass, superhydrophilic glass, hydrophobic glass, metasurfaces (untreated and hydrophobic variants), and a commercial tinted laminate. Data were collected from experiments involving exposure to supersaturated water vapor environments and illumination with sun-mimicking light sources.
3:List of Experimental Equipment and Materials:
Equipment included a wafer dicer (ADT ProVectus LA 7100), oxygen plasma system (Oxford Instruments Plasmalab 80 Plus), sputter deposition system (Von Ardenne CS 320 C), iCVD system (iLabTM Coating System, GVD Corporation), goniometer (DataPhysics OCA 35), microscopes (Olympus BX60), IR camera (FLIR SC7500), and spectroscopic systems. Materials included fused silica wafers, gold, titanium dioxide, trichlorovinylsilane (TCVS), perfluorodecyl acrylate (PFDA), and tert-butyl peroxide (TBPO).
4:Experimental Procedures and Operational Workflow:
Procedures involved sample preparation (cutting, cleaning, coating), exposure to supersaturated conditions, illumination with light sources, and measurement of clarity, distortion, evaporation times, and temperatures. Specific steps included fogging samples by cooling, transferring to experimental setups, and recording data with cameras and sensors.
5:Data Analysis Methods:
Data were analyzed using statistical methods (e.g., t-tests), calculations of clarity and distortion from image intensities, and temperature profiling. Software tools included goniometer software and custom analysis for thermal and optical data.
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oxygen plasma system
Plasmalab 80 Plus
Oxford Instruments
Treating specimens with oxygen plasma
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microscope
BX60
Olympus
Observing condensing droplets and clarity/distortion
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IR camera
SC7500
FLIR
Recording temperature profiles of samples and droplets
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absorptive neutral density filter
NE504B
Thorlabs
Commercial absorber used in thermal response measurements
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wafer dicer
ADT ProVectus LA 7100
ADT
Cutting fused silica wafers into specimen
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sputter deposition system
Von Ardenne CS 320 C
Von Ardenne
Fabricating metasurfaces by depositing gold nanoparticles and titanium dioxide
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iCVD system
iLabTM Coating System
GVD Corporation
Depositing ultrathin conformal films of poly(perfluorodecyl acrylate)
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goniometer
OCA 35
DataPhysics
Measuring advancing and receding contact angles
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light source
Flexilux 600 longlife 1.25 A
Sch?lly Fiberoptic GmbH
Providing sun-mimicking illumination for experiments
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tinted laminate
LLumar Esprit Series ATC 35 CH SR HPR
LLumar
Comparison sample with similar transmittance to metasurface
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