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Conducting Polymers || Electrical Properties of Polymer Light-Emitting Devices

DOI:10.5772/64358 出版年份:2016 更新时间:2025-09-19 17:15:36
摘要: In this chapter, we present a brief introduction to semiconducting properties of conjugated polymers and the motivation to apply this class of materials in electronic/optoelectronic devices such as polymer light-emitting diodes (PLEDs). We describe, in detail, the operating mechanisms of PLEDs, with particular focus on the effects of charge injection and transport and their dependence on the external electric field and temperature. The mechanisms of current injection from the electrodes into the organic semiconductor are initially treated using traditional models for thermionic emission and tunnelling injection. More recent models considering the influence of metal/semiconductor interface recombination and of energetic and spatial disorder in the injection currents are also introduced and discussed. In addition, models considering space-charge-limited currents and trap-filling-limited currents are employed to describe the charge transport characteristics in the bulk. Furthermore, we present a brief discussion on ideas concerning the effects of the disorder on the charge-carrier transport behaviour.
作者: Lucas Fugikawa Santos,Giovani Gozzi
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To describe the operating mechanisms of polymer light-emitting diodes (PLEDs), focusing on charge injection and transport processes, their dependence on external electric field and temperature, and the application of various theoretical models.

The basic models for PLED operating mechanisms can interpret dc electrical characterization data to extract parameters like charge carrier mobility and energy barriers. Critical analysis requires knowledge of material properties and electrode work functions. Models considering disorder are more accurate but harder to apply directly to experimental data. Future work should focus on improving these models for broader applicability.

The models presented are theoretical and may not fully capture all complexities of real PLEDs, such as variations in material properties or device fabrication. Direct application to experimental data can be challenging, especially for double-carrier devices with recombination effects. The chapter does not include new experimental validation.

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