研究目的
To develop Al2O3-Ce:GdYAG composite ceramic phosphors with high thermal conductivity and luminous efficacy for high-power white LED applications.
研究成果
The Al2O3-Ce:GdYAG composite ceramic phosphors exhibit improved thermal conductivity and luminous efficacy compared to Ce:GdYAG ceramics, with optimal performance at a molar ratio of 0.8 and thickness of 0.4 mm, achieving 112.6 lm/W luminous efficacy and 71.4 CRI. These properties make them suitable for high-power white LED applications, offering a promising alternative to existing phosphor materials.
研究不足
The thermal stability decreases with increasing temperature due to thermal quenching, and the transmittance of the ceramics decreases with higher Al2O3 content, which may affect light extraction. The CRI values, while improved, are still moderate (up to 71.4), indicating potential for further enhancement in color quality.
1:Experimental Design and Method Selection:
The study used solid-state reactive sintering to prepare translucent Al2O3-Ce:GdYAG composite ceramics with varying Al2O3 contents and thicknesses. The method was chosen to achieve uniform dispersion of Al2O3 particles in the Ce:GdYAG matrix for improved thermal and optical properties.
2:Sample Selection and Data Sources:
Commercial raw materials including α-Al2O3, Y2O3, Gd2O3, and CeO2 were used. Samples were prepared with molar ratios of Al2O3/Ce:GdYAG of 0,
3:5, 6, 7, and 8, and thicknesses from 4 mm to 1 mm. List of Experimental Equipment and Materials:
Equipment included a planetary ball mill (QM-3SP2, Nanjing Chi Shun Technology Development Co., Ltd), X-ray diffraction system (XRD, Model D/max2200 PC, Rigaku, Japan), high-resolution field-emission scanning electron microscope (FESEM, S-4800, Hitachi, Japan), fluorescence spectrophotometer (F-4600, Hitachi, Japan), laser pulse apparatus for thermal diffusivity, high temperature specific heat meter (MHTC96, Setaram, France), and a high accuracy array spectroradiometer with an integrating sphere (HASS-2000, Hangzhou, China). Materials included α-Al2O3 (
4:99%, Fenghe Ceramic Co., Ltd), Y2O3 (999%, Fujian Changting Golden Dragon Co., Ltd), Gd2O3 (999%, Jining Zhongkai New Materials Co., Ltd), CeO2 (99%, Alfa Aesar Co., Ltd), tetraethyl orthosilicate (TEOS), and MgO as sintering aids. Experimental Procedures and Operational Workflow:
Raw materials were mixed via ball milling, dried, calcined, pressed into green bodies, and sintered under vacuum. Sintered samples were polished, annealed for thermal etching, and characterized using XRD, SEM, PL/PLE measurements, thermal diffusivity, specific heat, density measurements, and optical property testing with blue LED packaging.
5:Data Analysis Methods:
Thermal conductivity was calculated using κ = α·Cp·ρ. Optical properties such as luminous flux, efficacy, CRI, and CCT were analyzed from spectroradiometer data.
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X-ray diffraction system
D/max2200 PC
Rigaku
Characterizing phase information of composite ceramics
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field-emission scanning electron microscope
S-4800
Hitachi
Collecting SEM images and EDS data
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fluorescence spectrophotometer
F-4600
Hitachi
Measuring photoluminescence and excitation spectra
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planetary ball mill
QM-3SP2
Nanjing Chi Shun Technology Development Co., Ltd
Mixing raw materials for ceramic preparation
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high temperature specific heat meter
MHTC96
Setaram
Recording specific heat of ceramics
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spectroradiometer with integrating sphere
HASS-2000
Hangzhou
Testing electroluminescent properties of LED devices
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α-Al2O3
Fenghe Ceramic Co., Ltd
Raw material for composite ceramics
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Y2O3
Fujian Changting Golden Dragon Co., Ltd
Raw material for composite ceramics
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Gd2O3
Jining Zhongkai New Materials Co., Ltd
Raw material for composite ceramics
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CeO2
Alfa Aesar Co., Ltd
Raw material for composite ceramics
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