研究目的
Investigating the effect of graphene on the corrosion resistance of micro-arc oxidation coatings applied to laser-MIG hybrid welded joints of dissimilar aluminum alloys.
研究成果
MAO coatings significantly improve the corrosion resistance of laser-MIG hybrid welded joints, with ceramic-graphene composite coatings offering slightly better resistance than simple coatings due to increased compactness and reduced porosity. The 7-HAZ is the most corrosion-susceptible zone, and micro-galvanic corrosion couplings between second phases and the matrix exacerbate corrosion in certain zones.
研究不足
The study is limited to specific aluminum alloys and welding methods; the graphene concentration was fixed at 0.1 g/L, and the corrosion tests were conducted in a NaCl solution, which may not represent all real-world conditions. The width of the heat-affected zone is less than 1 cm, requiring small exposed areas for testing.
1:Experimental Design and Method Selection:
The study involved preparing micro-arc oxidation (MAO) coatings with and without graphene on a laser-MIG hybrid welded joint of 6061 and 7075 aluminum alloys. The MAO process was conducted in an alkaline-silicon electrolyte, and graphene was added to the electrolyte for composite coatings. The corrosion behavior was evaluated through electrochemical tests and immersion corrosion tests.
2:Sample Selection and Data Sources:
Samples were machined from the welded joint, divided into five zones: base metal of 6061Al (6-BM), heat-affected zone of 6061Al (6-HAZ), weld zone (WZ), heat-affected zone of 7075Al (7-HAZ), and base metal of 7075Al (7-BM). Data were obtained from SEM, EDS, XRD, and electrochemical measurements.
3:List of Experimental Equipment and Materials:
Equipment included SEM (EVO-18 ZEISS and VEGA3 TESCAN), EDS (INCA Oxford), XRD (X' Pert3 Powder), electrochemical workstation (CHI660E), and a circulating cooling system. Materials included 6061 and 7075 aluminum plates, ER5356 filler material, NaOH, EDTA-2Na, Na2SiO3, and graphene.
4:Experimental Procedures and Operational Workflow:
The welded joint was cleaned ultrasonically in acetone. MAO was performed in the electrolyte at a working frequency of 500 Hz, with temperature maintained at 30°C. Coatings were prepared with and without graphene. Surface and cross-section morphologies were observed, and elemental analysis was conducted. Electrochemical tests were performed in a 3.5% NaCl solution using a three-electrode cell.
5:5% NaCl solution using a three-electrode cell. Data Analysis Methods:
5. Data Analysis Methods: Data were analyzed using electrochemical software for polarization curves. SEM, EDS, and XRD were used for microstructural and compositional analysis.
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SEM
EVO-18
ZEISS
Observing surface and cross-section morphologies of coatings
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EDS
INCA
Oxford
Analyzing elemental distribution in coatings
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SEM
VEGA3
TESCAN
Observing surface and cross-section morphologies of coatings
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XRD
X' Pert3 Powder
Analyzing phase compositions of samples
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Electrochemical Workstation
CHI660E
Performing potentiodynamic polarization tests
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