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Quasi-continuous-wave laser surface melting of aluminium alloy: Precipitate morphology, solute segregation and corrosion resistance
摘要： A quasi-continuous wave laser surface melting is performed on 2219 aluminium alloy to improve the corrosion resistance. The fast cooling rate and the multi-directional solidification behavior of the process transform large and long-chained constituent particles into fine and isolated circular precipitates with alleviated solute segregation. The improved corrosion resistance is due to formation of low-flaw-density passive film, reduction of the driving force for corrosion and improvement of the re-passivation capability of the modified surface. The large and long-chained constituent particles are the preferred sites for corrosion initiation and propagation.
关键词： C: Segregation,B: Polarization,C: Pitting corrosion,A: Aluminium,B: EPMA
更新于2025-11-28 14:24:20
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Structural and Optical Properties of AlN/GaN and AlN/AlGaN/GaN thin films on Silicon Substrate prepared by Plasma Assisted Molecular Beam Epitaxy (MBE)
摘要： In this study, the Aluminium Nitride/Gallium Nitride (AlN/GaN) layers and Aluminium Nitride/Aluminium Gallium Nitride/Gallium Nitride (AlN/AlGaN/GaN) layer heterostructures were successfully created using technique known as plasma-assisted molecular beam epitaxy (MBE) on silicon substrate. Gallium (7N) and Aluminium (6N5) of high purity were used to grow GaN, AlN and AlGaN respectively. The structural and optical properties of the prepared AlN/GaN and AlN/AlGaN/GaN layer heterostructures were investigated by means of atomic force microscope (AFM), X-ray diffraction (XRD), photoluminescence spectroscopy (PL) and Raman spectroscopy. AFM measurement demonstrated that the root mean square of surface roughness for AlN/GaN and AlN/AlGaN/GaN heterostructures are 3.677 nm and 10.333 nm respectively. XRD data indicated that the samples have typical diffraction pattern of hexagonal structure. Raman spectra revealed all four Raman-active modes present inside both samples. PL spectra data showed the yellow luminescence which corresponds to the deep energy levels due to imperfections of AlN did not appear. Thus, PL observation indicated that the thin film of AlN/GaN and AlN/AlGaN/GaN layers have good optical quality and looks promising for various target applications in optoelectronics, photovoltaic and radiofrequency applications.
关键词： silicon,thin film,MBE,Aluminium Nitride,Gallium Nitride,Aluminium Gallium Nitride
更新于2025-09-23 15:23:52
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Investigation of nanomechanical and adhesion behavior for AlN coating and AlN/Fe2-3N composite coatings created by Active Screen Plasma Nitriding on Al 1050
摘要： This study investigated the effect of nitriding time and temperature on the mechanical properties of the composite AlN/Fe2-3N coating deposited on the pure aluminium substrate using the novel Active Screen Plasma Nitriding (ASPN) method. ASPN treatment was performed for 2, 5, 10, 15 h at temperatures of 450,500, and 550 (cid:1)C and Conventional Plasma Nitriding (CPN) treatment was carried out for 5 h at 500 (cid:1)C. All treatments were performed at the 10 KHz frequency with 80% duty cycle on the Al1050 substrate under 20%H2t80%N2 atmosphere. Phase and microstructure studies were performed using, respectively, the grazing incidence x-ray diffraction (GIXRD) system and the ?eld emission - scanning electron microscopy (FE-SEM) system equipped with energy-dispersive spectroscopy (EDS) analyzer. The mechanical strength of the coating was evaluated by the roughness, nano-hardness, nano-scratch, and adhesion strength tests performed on coated and uncoated specimens. According to the results, the uncoated Al1050 specimen, the CPN-treated specimen, and the ASPN-treated specimen had a mean nano-hardness of 0.7 ± 0.1 GPa, 10.9 ± 0.6 GPa, and 9.6 ± 0.5 GPa, respectively. It was also found that the single-phase AlN coating has a better adhesion strength and scratch strength (LC3 ? 12 N) than the composite AlN/Fe2-3N coating (LC3 ? 10 N). Examination of scratch mechanisms in hard AlN and AlN t Fe2-3N coatings deposited on a soft aluminium substrate showed that the failures in these coatings are due to tensile-type Hertzian cracks. However, as the load increases, the substrate undergoes increasing deformation and failures shift to chipping and interfacial spallation.
关键词： Adhesion strength,Active screen plasma nitriding,Pure aluminium,Conventional plasma nitriding,Scratch resistance,Nanoindentation
更新于2025-09-23 15:23:52
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A lithium aluminium borate composite microwave dielectric ceramic with low permittivity, near-zero shrinkage, and low sintering temperature
摘要： A low temperature co-fired dielectric material with low shrinkage during the sintering process can enhance the circuit design of electronic devices. Lithium aluminium borate composite ceramic with a composition of Li2O:Al2O3:B2O3=1:1:2 (abbreviated: LAB) was prepared by a traditional solid-state reaction method. These ceramics have a low sintering temperature (675–750 °C), low permittivity, and near-zero shrinkage. When the sintering temperature was 725 °C, the LAB ceramics exhibited a small shrinkage of ~2.4% and the best microwave dielectric properties with εr = 3.9, Q × f = 35?500 GHz, and τ? = -64 ppm/°C. The LAB ceramics sintered at 700 °C have near-zero shrinkage of ~ 0.4% and good microwave dielectric properties. The ceramics transformed from (Li2B4O7 and Al2O3) to (Li2Al2B4O10 and Li4Al4B6O17) phases with increasing the sintering temperature, which may be the reason why they show marginal shrinkage. In addition, the ceramics could be co-fired with Ag, indicating that this material is a good candidate for low-temperature co-fired ceramic devices.
关键词： Low temperature co-fired ceramic,Lithium aluminium borate composite,Near-zero shrinkage
更新于2025-09-23 15:23:52
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Modeling and optimization of characterization of nanostructure anodized aluminium oxide membranes
摘要： This study indicates the importance of statistical analysis and modeling to investigate the synthesis and optimization of anodized aluminium oxide (AAO) properties for template-assisted synthesis of nanostructure particles. The response surface methodology was used to optimize pore size and porosity of AAO. The impacts of four main parameters including type of acidic electrolyte, concentration of acid, bath temperature and electrical potential of anodization on characterization of AAO were investigated. Statistical analysis showed that the linear and quadratic terms of these variables had significant effects. Based on the statistical analysis, a possible mechanism of the anodization was proposed. The proposed mechanism helped us to develop an analytical model. The analytical model could predict the experimental results with an appropriate accuracy. Results indicated the rate-limiting reaction in anodization process is water dissociation which was conducted at the pore bottom of the AAO. In addition, concentrated electrical field at pore base induced water splitting so that the activation energy of water dissociation decreased ten times and reached to 9898.5 J/mol.
关键词： Statistical analysis,Anodized aluminium oxide,Electrochemical synthesis,Pore perforation,Nanoporous materials
更新于2025-09-23 15:23:52
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Characterisation of AlN nano thin films prepared by PLD
摘要： Aluminium nitride (AlN) nano thin films have been prepared by pulsed laser deposition (PLD) in this paper. The microstructure and grain size of the nano thin films were characterised by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The results showed that the PLD conditions such as laser fluence, ambient pressure and substrate temperature influence the thickness, morphology and grain size of the nano thin films obviously, i.e. the surface of the nano thin films becomes rough while the grain size increases with increasing the laser fluence, ambient pressure and substrate temperature. In addition, there exists a preferred orientation growth in the thin films.
关键词： microstructure,pulsed laser deposition (PLD),aluminium nitride,grain size,Nano thin films
更新于2025-09-23 15:22:29
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Gradient microstructure and vibration fatigue properties of 2024-T351 aluminium alloy treated by laser shock peening
摘要： To investigate the improvement in vibration fatigue and the strengthening mechanism of laser shock peening, a nanosecond laser was used to strengthen the 2024-T351 aluminium alloy. Accordingly, the microstructure, residual stress, nanohardness and surface roughness of the treated alloy were measured. Subsequently, the vibration fatigue damage and fatigue life were evaluated, and the vibration fracture morphology was observed. The results showed that the grains in the peened surface were re?ned. A residual stress of ?141 MPa and a nanohardness of 3.1 GPa were obtained by laser shock peening. Based on the relationship between the peened microstructure and fracture morphology, it was deduced that an increase in the grain boundaries led to a lower crack initiation rate and a higher crack initiation life. The compressive residual stress decreased the crack growth rate and increased the crack growth life. Therefore, laser shock peening increases the total vibration fatigue life by about 63.5%.
关键词： Laser shock peening,Vibration fatigue,2024-T351 aluminium,Compressive residual stress,Microstructure
更新于2025-09-23 15:21:01
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Pore Formation during Laser Welding in Different Spatial Positions
摘要： The process of formation of pores, cavities and similar defects in welded joints of stainless steels and aluminum alloys, affecting their quality, directly depends on spatial weld position in laser welding. Reducing the angle of inclination from 90° to 0° during downhill and uphill welding of AISI 321 stainless steel in the pulse mode of laser generation leads to an increase in both the number of pores and their size. At the same time, defects in the form of pores are not observed in the continuous mode of laser generation. In laser welding of butt joints of AISI 321 steel, the flat and vertical weld positions are the most promising, as they provide the highest level of quality. In order to provide a stable formation of a high-quality butt joint of aluminum AMg6M alloy and to prevent the failure of laser equipment, the welding process should be carried out in a vertical uphill weld position.
关键词： different spatial position,aluminium alloy,stainless steel,quality,defects,porosity,laser welding
更新于2025-09-23 15:21:01
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Processing of Keyhole Depth Measurement Data during Laser Beam Micro Welding
摘要： Analysing the quality of weld seams is still a challenging task. An optical inspection of the surface is giving limited information about the shape and depth of the weld seam. An application for laser beam welding with high demands regarding the weld depth consistency is the electrical contacting of battery cells. The batteries themselves have a limited terminal or case thickness that must not be penetrated during the welding process to avoid leakage or damage to the cell. That leads to a minimum weld depth to ensure the electrical functionality, and a maximum weld depth indicated by the case thickness. In such applications, a destructive analysis is not suitable which leads to the demand for a non-destructive measurement during the process. Using a coaxial, interferometric measurement setup, the keyhole depth during the deep penetration welding is measureable. For a keyhole with a depth of a couple of millimetres, such a system is commercially available. In micro scale, however, these systems are facing several challenges such as scanning systems, small spot diameters of a few tens of micrometres and narrow keyholes. This study contains an investigation of an interferometric measurement of the keyhole depth and the suitability for laser micro welding. Therefore, the data processing of the achieved measurements is investigated, and the results are compared with the depth measurement of metallographic analysed samples. Stainless steel is used to investigate the behaviour and the stability of developed data processing strategy and the resulting depth values.
关键词： Laser welding,battery,copper,spatial power modulation,aluminium,keyhole depth measurement
更新于2025-09-23 15:21:01
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Effect of laser surface melting on surface integrity of Ala??4.5Cu composites reinforced with SiC and MoS2
摘要： Two types of composites were prepared with Al?4.5Cu alloy as a matrix using stir casting method. One was reinforced with 10 wt.% of SiC and 2 wt.% of MoS2. The other was reinforced with 10 wt.% of SiC and 4 wt.% of MoS2. Their surfaces were remelted using a CO2 laser beam with an objective to study the influence of laser surface melting (LSM). The topography, microhardness, corrosion resistance and wear resistance of the laser melted surfaces were studied. Overall surface integrity after LSM was compared with as-cast surface. LSM enhanced the microhardness and wear resistance of the surface in each case. Porosity of the laser melted surface was low and corrosion resistance was high. Thus, LSM can be conveniently applied to enhancing the surface integrity of the aluminium composites. However, there is an optimum laser specific energy, around 38 J/m2 in this study, for obtaining the best surface integrity.
关键词： microhardness,aluminium composites,laser surface melting,corrosion resistance,molybdenum disulfide,silicon carbide
更新于2025-09-23 15:21:01