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Flexible electrochromic tungsten/iron mixed oxide films synthesized by an atmospheric pressure plasma jet
摘要: Flexible electrochromic organo-tungsten- iron oxide (WFexOyCz) films are rapidly deposited onto flexible (60 Ω/□ polyethylene terephthalate/indium tin oxide; PET/ITO) substrates by a low temperature-atmospheric pressure-plasma polymerization method with an atmospheric pressure plasma jet (APPJ) for a short exposed duration of 48 s. The precursor vapors of tungsten hexacarbonyl [W(CO)6] and biscyclopentadienyl iron [ferrocene; Fe(C5H5)2] are mixed with O2 gases at various gas flow rates, injected into air plasma jet and sprayed onto PET/ITO substrates at room temperature (~23oC) and at atmospheric pressure (1.013 × 105 Pa). Flexible electrochromic WFexOyCz films are synthesized with a specific addition of oxygen gases with superior lithium electrochromic properties as demonstrated by a potential sweep alternating between -1 V and 2 V at a scan rate of 40 mV/s in a 1 M LiClO4-propylene carbonate electrolyte. With amorphous WFexOyCz films produced with an APPJ by adding oxygen gases at a specific flow rate of 0.5 sccm, a high value in oxygen deficiency up to 0.189 allows more Li+ ions to intercalate into and deintercalate out of the film. Significant coloration and bleaching are proven by the high values in optical transmittance modulation (ΔT) of up to 70.3%, optical density (ΔOD) up to 0.77 and color efficiency (η) up to 61.3 cm2/C, at a wavelength of 800 nm, respectively.
关键词: Electrochromic materials,Iron oxide,Tungsten oxide,Flexible electrochromic film,Atmospheric pressure plasmas,Plasma polymerization
更新于2025-09-23 15:21:21
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In-fiber Dispersion Compensated Polarizer and Mode-locked Fiber Laser Application
摘要: Microplasma jets propagating in a helium flow surrounded by open air at ambient temperature have attracted the attention of many researchers for their putative ability to deliver high fluxes of reactive oxygen and nitrogen species to a target situated some centimeters away. This is of particular interest in biomedical applications. In this paper, we use Schlieren images to show that ignition of the plasma jet causes a reduction in the length of the laminar zone of the helium flow.
关键词: Atmospheric-pressure plasmas,hydrodynamics
更新于2025-09-23 15:21:01