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Mercury Free Microscopy: An Opportunity for Core Facility Directors
摘要: Mercury Free Microscopy (MFM) is a new movement that encourages microscope owners to choose modern mercury free light sources to replace more traditional mercury based arc lamps. Microscope performance is enhanced with new solid state technologies because they offer a more stable light intensity output and have a more uniform light output across the visible spectrum. Solid state sources not only eliminate mercury but also eliminate the cost of consumable bulbs (lifetime (cid:2)200 hours), use less energy, reduce the instrument down time when bulbs fail and reduce the staff time required to replace and align bulbs. With lifetimes on the order of tens of thousands of hours, solid state replacements can pay for themselves over their lifetime with the omission of consumable, staff (no need to replace and align bulbs) and energy costs. Solid state sources are also sustainable and comply with institutional and government body mandates to reduce energy consumption, carbon footprints and hazardous waste. MFM can be used as a mechanism to access institutional ?nancial resources for sustainable technology through a variety of stakeholders to defray the cost to microscope owners for the initial purchase of solid state sources or the replacement cost of mercury based sources. Core facility managers can take a lead in this area as “green” ambassadors for their institution by championing a local MFM program that will save their institution money and energy and eliminate mercury from the waste stream. Managers can leverage MFM to increase the visibility of their facility, their impact within the institution, and as a vital educational resource for scienti?c and administrative consultation.
关键词: funding opportunities,?uorescence imaging,light engines,light source
更新于2025-09-23 15:23:52
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Reporting of light irradiation conditions in 300 laboratory studies of resin-composites
摘要: Objective. To evaluate how the light delivered to resin-composites was described in recent articles. Method. PubMed was searched for 300 articles published between January 2017 and May 2018 with keywords relating to photocuring of dental materials. The articles examined a wide range of resin-composite properties and performance. For each article, the information provided about the light curing unit (LCU), the light curing conditions and the characteristics and quantity of the light used in the study were recorded. Specifically, the type of LCU used; the irradiance; how the irradiance was measured; the exposure times; whether the light energy (radiant exposure) received by the specimen was determined, or if only the light output at the LCU tip was measured; whether the distance between the tip of the LCU and the specimen was reported; and whether the emission spectrum from the LCU was reported. Where possible, the resin manufacturer’s minimum energy requirement (MER: the product of the recommended minimum exposure time and irradiance) was compared to the radiant exposure delivered to the specimen. Results. Of the 300 articles examined, 217 were published in 2017 and 83 in 2018. Of these articles, 130 (43%) were found in open access journals, and 170 (57%) were in subscription-based journals. The name of the LCU used was not provided in 31 articles, 14 articles did not provide the exposure time, and 227 articles did not report the distance to the specimen. An irradiance value was reported in 231 articles, but this was the irradiance received by the specimen in only 48 instances. The emission spectrum from the LCU was reported in 15 articles. There was a large range in the radiant exposures from below 10 J/cm2 to greater than 100 J/cm2. Significance. The majority of articles from 2017 and early 2018 did not include sufficient description of the characteristics and quantity of the light received by the resin-composite specimens to allow the study to be replicated. It is recommended that future articles should report: (1) the identity of the LCU used; (2) the radiant exposure received by the specimen (J/cm2); and (3) appropriate reference to the emission spectrum from the LCU.
关键词: Research reproducibility and replicability,Bond strength,Resins,Light curing,Bulk fill,Light measurement
更新于2025-09-23 15:23:52
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Comparing the Efficiency of N-Doped TiO2 and N-Doped Bi2MoO6 Photo Catalysts for MB and Lignin Photodegradation
摘要: In this study, we tested the efficiency of nitrogen-doped titanium dioxide (N-TiO2) and nitrogen-doped bismuth molybdate (N-Bi2MoO6) compounds as photocatalysts capable of degrading methylene blue and lignin molecules under irradiation with ultraviolet (UV) and visible light (VIS). Moreover, we compared TiO2 and Bi2MoO6 catalysts with N-TiO2 and N-Bi2MoO6 compounds using chemical coprecipitation. The catalysts were prepared starting from Ti(OCH2CH2CH3)4, Bi(NO3)3·5H2O, and (NH4)6Mo7O24 reagents. N-doping was achieved in a continuous reflux system, using ethylene diamine as a nitrogen source. The resulting materials were characterized using Scanning Electron Microscopy (SEM), X-Ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy (XPS). Additionally, we observed the decrease in particle size after processing the compounds in the reflux system. The results regarding photocatalytic degradation tests show a remarkable effect for nitrogen doped samples, achieving 90% of lignin degradation.
关键词: photocatalysis,lignin,visible light,UV light,bismuth molybdate,Titanium dioxide
更新于2025-09-23 15:23:52
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Light enhanced room temperature resistive NO2 sensor based on a gold-loaded organic–inorganic hybrid perovskite incorporating tin dioxide
摘要: A material is described for sensing NO2 in the gas phase. It has an architecture of type Au/MASnI3/SnO2 (where MA stands for methylammonium cation) and was fabricated by first synthesizing Au/MASnI3 and then crystallizing SnO2 on the surface by calcination. The physical and NO2 sensing properties of the composite were examined at room temperature without and with UV (365 nm) illumination, and the NO2-sensing mechanism was studied. The characterization demonstrated the formation of a p-n heterojunction structure between p-MASnI3 and n-SnO2. The sensor, best operated at a voltage of 1.1 V at room temperature, displays superior NO2 sensing performance. Figures of merit include (a) high response (Rg/Ra = 240 for 5 ppm NO2; where Rg stands for the resistance of a sensor in test gas, and Ra stands for the resistance of a sensor in air), (b) fast recovery (about 12 s), (c) excellent selectivity compared to sensors based on the use of SnO2 or Au/SnO2 only, both at room temperature under UV illumination; (d) a low detection limit (55 ppb), and (e) a linear response between 0.5 and 10 ppm of NO2. The enhanced sensing performance is mainly attributed to the high light absorption capacity of MASnI3, the easy generation and transfer of photo-induced electrons from MASnI3 to the conduction band of SnO2, and the catalytic effect of gold nanoparticles.
关键词: Light absorbing material,SPR effect,Photo generated electrons,Gas sensing,P-n junction,Catalytic effect,Heterojunction,SnO2,UV light,MASnI3
更新于2025-09-23 15:23:52
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Blue-light imaging has an additional value to white-light endoscopy in visualization of early Barrett's neoplasia: an international multicenter cohort study
摘要: Endoscopic features of early neoplasia in Barrett’s esophagus (BE) are subtle. Blue-light imaging (BLI) may improve visualization of neoplastic lesions. The aim of this study was to evaluate BLI in visualization of Barrett’s neoplasia. Methods: Corresponding white-light endoscopy (WLE) and BLI images of 40 BE lesions were obtained prospectively and assessed by 6 international experts in 3 assessments. Each assessment consisted of overview and magnification images. Assessments were as follows: assessment 1, WLE only; assessment 2, BLI only; and assessment 3, corresponding WLE and BLI images. Outcome parameters were as follows: (1) appreciation of macroscopic appearance and surface relief (visual analog scale scores); (2) ability to delineate lesions (visual analog scale scores); (3) preferred technique for delineation (ordinal scores); and (4) quantitative agreement on delineations (AND/OR scores). Results: Experts appreciated BLI significantly better than WLE for visualization of macroscopic appearance (median 8.0 vs 7.0, P < .001) and surface relief (8.0 vs 6.0, P < .001). For both overview and magnification images, experts appreciated BLI significantly better than WLE for ability to delineate lesions (8.0 vs 6.0, P < .001 and 8.0 vs 5.0, P < .001). There was no overall significant difference in AND/OR scores of WLE + BLI when compared with WLE, yet agreement increased significantly with WLE + BLI for cases with a low baseline AND/OR score on WLE, both in overview (mean difference, 0.15; P = .015) and magnification (mean difference, 0.10; P = .01). Conclusions: BLI has additional value for visualization of BE neoplasia. Experts appreciated BLI better than WLE for visualization and delineation of BE neoplasia. Quantitative agreement increased significantly when BLI was offered next to WLE for lesions that were hard to delineate with WLE alone.
关键词: neoplasia,white-light endoscopy,visualization,Barrett's esophagus,delineation,blue-light imaging
更新于2025-09-23 15:23:52
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[IEEE 2018 International Conference on Advanced Technologies for Communications (ATC) - Ho Chi Minh City, Vietnam (2018.10.18-2018.10.20)] 2018 International Conference on Advanced Technologies for Communications (ATC) - Demonstration of A Visible Light Receiver Using Rolling-Shutter Smartphone Camera
摘要: Visible Light Communication (VLC) which has a mass of applications is getting much attention in both academic field and industry. Specifically, light-to-camera (LTC) communications in which information is transmitted to user through visible light signals; whereas, rolling-shutter camera-based receivers are utilized to capture and decode transmitted signals. In this paper, we present a demonstration of LTC communications system which includes a pair of transmitter and receiver. We have used an Arduino Genuino board to implement VLC transmitters which can transmit the identification (ID) messages through light-emitting diodes (LEDs)-based front-ends. At the receiver, we have developed an Android application which utilizes the CMOS image sensor (CIS) of the smartphone camera to receive the light signals. Besides, some practical problems of our LTC prototype and their solutions are also introduced in this paper.
关键词: Optical Camera Communication,Light-to-Camera,Rolling Shutter,Visible Light Communications (VLC)
更新于2025-09-23 15:23:52
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A Hybrid Optical/Electric Memristor for Light-Based Logic and Communication
摘要: Light-based information processing has the potential to increase speed, security and scalability of electronics if issues in the device complexity could be resolved. We here demonstrate an integrated nano-electronic device that can combine, store, and manipulate optical and electronic information. Employing a mechanically flexible and multilayered structure, a device is realized that shows memristive behavior. Illumination is shown to control the device operation in several unique ways. First, the device produces photocurrent that allows us to read out the device state in a self-powered manner. More importantly, a varying light intensity modulates the switching transition in a proportional manner that is akin to a neuron with variable plasticity and which can be taught and queried using either light or electrical inputs. This behavior enables a multi-level light-controlled logic and teaching schemes that can be applied to light-based communication devices and provides a route towards ubiquitous and low-cost sensors for future internet of things applications.
关键词: light-based communication,memory,hybrid optoelectronics,light fidelity,memristor
更新于2025-09-23 15:23:52
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To the Theory of the Polarized Radiation Absorption in a Semiconductor (001) Quantum Well
摘要: The paper considers absorption of linearly polarized radiation in a semiconductor size-quantized well related to optical transitions both between the branches of light and heavy holes and between the size-quantized subbands. Main features of the light absorption in an infinitely deep symmetric well are elucidated. These features are characterized by intraband absorption of light and associated with the direct optical transitions of holes between the subbands of the semiconductor valence band formed due to the size quantization.
关键词: optical transition,semiconductor,size quantization,light absorption coefficient,polarized light,holes
更新于2025-09-23 15:23:52
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Handling Electromagnetic Radiation beyond Terahertz using Chromophores to Transition from Visible Light to Petahertz Technology
摘要: An increase of the operating frequencies of electromagnetic waves leads from the well-established terahertz technology to the visual and reaches petahertz radiation. It is shown that electromagnetic radiation close to petahertz is attractive for technology where knowledge about radio waves can be applied. The dimensions of such radiation are still classically macroscopic; however, molecular components such as resonators were used where quantum mechanics rules have to be considered. Constructions of coupled resonators for energy transfer are as well demonstrated as molecular components for optical metamaterials.
关键词: Dyes,FRET,Energy transfer,Reflectance,Petahertz,Visible light,Resonators,Metamaterials,Terahertz,Electromagnetic radiation
更新于2025-09-23 15:23:52
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Enhancing Reverse Intersystem Crossing via Secondary Acceptors: towards Sky-Blue Fluorescent Diodes with Tenfold-Improved Exter-nal Quantum Efficiency
摘要: How to simply but effectively facilitate reverse intersystem crossing (RISC) transition is always the key issue for developing high-performance thermally activated delayed fluorescence (TADF) dyes. In this work, as a proof of concept, a feasible strategy named 'acceptor enhancement' is demonstrated with a series of ternary blue emitters (xCzmPOnTPTZ) using diphenylphosphine oxide (PO) as secondary acceptors. Compared with its PO-free binary analogue, such simple introduction of PO groups in pCzPO2TPTZ dramatically enhances its RISC rate constant (kRISC) by 10 times to the level of ~105 s-1, accompanied by RISC efficiency (ηRISC) of 92%, which further improves the triplet-to-singlet upconversion for effective triplet harvesting in its devices. As the result, on the basis of a trilayer device structure, pCzPO2TPTZ realized a state-of-the-art external quantum efficiency (EQE) beyond 20% with tenfold improvement.
关键词: Organic Light-Emitting Diode,Thermally Activated Delayed Fluorescence,Excited State Transition,Blue Emission,Reverse Intersystem Crossing,Phosphine Oxide Acceptor
更新于2025-09-23 15:23:52