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Synthesis, Morphology, Optical and Electrical Properties of Cu <sub/> 1? <i>x</i> </sub> Fe <sub/><i>x</i> </sub> O Nanopowder
摘要： The pure and Fe-doped CuO nanoparticles of the series Cu1?xFexO (x = 0, 0.027, 0.055, 0.097 and 0.125) were synthesized by a simple low temperature sol–gel method. Synthesized samples were characterized by a series of techniques including Field Emission Scanning Electron Microscope (FESEM), Energy Dispersive X-ray electron spectroscopy (EDX), Diffuse Reflectance Spectroscopy (DRS), Fourier Transform Infrared Spectroscopy (FTIR), Hall Effect Set-up and Current–Voltage (I–V) characteristics. FESEM analysis shows formation of disc type structure increasing in grain size with Fe concentration in CuO. EDX confirmed the incorporation of iron in CuO. FTIR results of pure and Fe doped CuO samples have confirmed the formation of monoclinic CuO. The optical band gap estimated using Diffuse Reflectance Spectroscopy (DRS) shows the increment in the band gap values with Fe substitution. The Hall measurements show predominantly p-type conduction in all the samples and carrier densities decrease with increased Fe substitution. I–V characteristics of pure and Fe doped CuO nanoparticles show rectification behaviour of Schottky diodes.
关键词： Defect States,Hall Effect,Schottky Diode,Cation Vacancies,Fe-Substituted CuO
更新于2025-11-19 16:56:35
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Engineering cation vacancies to improve the luminescence properties of Ca <sub/>14</sub> Al <sub/>10</sub> Zn <sub/>6</sub> O <sub/>35</sub> : Mn <sup>4+</sup> phosphors for LED plant lamp
摘要： In the recent years, Mn4+-doped phosphors for indoor plant cultivation have received extensive concern owing to the far-red emission that can match well with the absorption spectra of plant pigments. Whereas, many Mn4+-doped phosphors still face some challenges such as poor light efficiency and low thermal stability. It is an effective way to resolve these problems via cation vacancies engineering. Herein, the Ca14-xAl10Zn6-yO35: Mn4+ phosphors are successfully synthesized by combustion method. The luminescence intensity of Ca14-xAl10Zn6-yO35: Mn4+ phosphor is enhanced through engineering Ca2+ and Zn2+ vacancies according to the charge compensation mechanism. The optimal content of each of Ca2+ and Zn2+ vacancies is equal to be 0.3. Furthermore, the defect formation is accompanied with lattice distortion, which plays a vital role in driving the excited phonon traps to reduce the energy loss by non-radiation transitions. Therefore, the thermal stability of Ca14-xAl10Zn6-yO35: Mn4+ phosphor is also improved via engineering cation vacancies. In addition, the Ca14-xAl10Zn6-yO35: Mn4+ phosphors can be effectively excited by blue light and it exhibits far-red emission due to the Mn4+ spin-forbidden 2E→4A2 transition. The results suggest that the Ca14-xAl10Zn6-yO35: Mn4+ phosphors can have a tremendous potential in indoor plant cultivation.
关键词： defects,cation vacancies,LED plant lighting,phosphors,charge compensation
更新于2025-09-11 14:15:04