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Formation and properties of a Zr-based amorphous coating by laser cladding
摘要： (Zr0.53Al0.1Ni0.05Cu0.3Ti0.02)99Y1 (at%) coating with amorphous layer of about 180 lm thick was prepared on a steel substrate by using laser cladding method. The coating is compact and shows good metallurgical bonding with substrate. The microstructure, microhardness and corrosion behavior along the depth from the coating surface to the substrate were investigated. It is found that a gradient structure consisted of amorphous surface layer, amorphous–crystalline transitional layer and substrate is formed after the laser cladding. The microhardness and corrosion behavior exhibit variation with the microstructural evolution at different depths from the coating surface. The microhardness and corrosion resistance in 3.5 wt% NaCl solution of the amorphous surface layer are comparable to those of the as-cast Zr-based BMG with the same composition, and higher than those of the steel substrate.
关键词： Laser cladding,Hardness,Corrosion resistance,Amorphous coating,Microstructure
更新于2025-09-10 09:29:36
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Effect of current density and ZnO nano particles influence on the microstructure and mechanical strengthening properties of Zn-TiO<sub align="right">2-ZnO alloys at constant deposition time
摘要： In this work, the effect of current density and particle loading on microstructure and mechanical properties of Zn-TiO2-ZnO nanocomposite produced via electrocodeposition are investigated. The morphological characteristics of the nano-composite coatings were characterised by scanning electron microscope (SEM) equipped with energy dispersive spectrometer (EDS). Mechanical examination was carried out using Dura scan micro-hardness tester and CERT UMT-2 multi-functional tribological tester. The corrosion properties were evaluated using linear polarisation technique in 3.5% NaCl. The result showed that the coatings exhibited good stability and the quantitative particle loading significantly improved the micro-structural properties of the coating. It is also noticed that the hardness performance and corrosion resistance of the coatings were significantly impacted with over 70% improvement as against the as-received samples.
关键词： Zn-TiO2-ZnO,electrocodeposition,coatings,corrosion resistance,nanocomposite
更新于2025-09-09 09:28:46
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Atomic layer deposited TiO <sub/>2</sub> -IrO <sub/>x</sub> alloys enable corrosion resistant water oxidation on silicon at high photovoltage.
摘要： We synthesized by atomic layer deposition (ALD) TiO2-IrOx alloys that enable high photovoltages and catalyze water oxidation on silicon metal-insulator-semiconductor (MIS) photoanodes. The ratio of TiO2 to IrOx was precisely controlled by varying the number of ALD cycles for each precursor. Silicon with a 2 nm surface SiO2 layer was coated with TiO2-IrOx alloys ranging in composition from 18-35% iridium relative to the sum of titanium and iridium concentrations. IrOx catalyzed oxygen evolution and imparted a high work function to the TiO2-IrOx alloys, enabling photovoltages during water oxidation that exceeded 600 mV. TiO2 imparted stability and inhibited corrosion of the underlying silicon light absorber. After annealing in forming gas (5% H2 / 95% N2), TiO2-IrOx alloys were stable for 12 hours of continuous water oxidation in 1 M H2SO4. Key properties of the MIS junction affecting electrochemical operation were also extracted by electrochemical impedance spectroscopy. This work demonstrates that alloying by ALD is a promising approach for designing corrosion resistant Schottky contacts with optimized electronic and materials properties for catalyzed, solar driven water oxidation.
关键词： photovoltage,water oxidation,TiO2-IrOx alloys,Atomic layer deposition,corrosion resistance,silicon photoanodes
更新于2025-09-04 15:30:14