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Confined Preparation of N-doped Commercial P25 TiO2 Photocatalysts with Fast Charge Separation by Argon-diluted Nitrogen Plasma Treatment
摘要： N-doped TiO2 attracts enormous attention due to its cheapness and excellent visible-light-driven photocatalytic activity. An approach assisted by Nitrogen plasma to synthesize the N-doped TiO2 is presented in our work by using commercial available Degussa P25 as raw material. X-ray photoelectron spectroscope (XPS) and transmission electron microscope (TEM) measurement results show that the evidence of N doping and the formation of surface disorder layer, which can both serve as active sites. Electrochemical characterizations verified the excellent photo-generated charge separation feature of the obtained N-doped P25 TiO2. High absorption of visible light, fast charge separation and numerous active sites ensure the excellent photocatalytic activity for the N-doped P25 TiO2 in the photo-oxidation of organic molecules in water. It is noteworthy that the Argon-assistant Nitrogen plasma treatment is superior to conventional pure Nitrogen plasma treatment because of confined Nitrogen ionization. From the results, this plasma treatment method may open up a new way to the application of plasma technology in the activation commercial materials.
关键词： Charge Separation,Transient photocurrents,N-doped TiO2,Plasma Treatment
更新于2025-09-10 09:29:36
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Structure, Magnetic and Photochemical Properties of Fe–TiO2 Nanoparticles Stabilized in Al2O3 Matrix
摘要： Fe–TiO2 nanoparticles with Fe concentration from 0.24 to 5 wt % were synthesized in a Al2O3 matrix through multiple impregnations from organic solutions of Ti n-butoxide and Fe acetylacetonate. Microstructure, morphology and magnetic properties of the composites were studied using X-ray analysis, transmission electron microscopy, energy-dispersive analysis, M?ssbauer spectroscopy and magnetic susceptibility. It was shown that the deposition of the solution with low concentration of Ti n-butoxide leads to the formation of mostly extensive Fe–TiO2 films with a small fraction of individual Fe–TiO2 nanoparticles. On the contrary, the increase of Ti n-butoxide concentration results in the formation of a great number of individual Fe–TiO2 nanoparticles on Al2O3. The size of these particles increases from 2–3 nm to 5–8 nm with the increase of Fe content in the samples from 0.24 to 1.0 (wt %). M?ssbauer spectroscopy revealed two types of magnetic ions. The first type of paramagnetic Fe3+ demonstrate spin–lattice relaxation properties while another one substitutes Ti4+ in the TiO2 structure thus forming Fe–TiO2 stabilized particles in the matrix. According to the magnetic data antiferromagnetic and ferromagnetic types of exchange spin coupling occur in Fe–TiO2/Al2O3 composites. The increase of Fe concentration in the composites from 1 to 5 wt % results in the narrowing of the TiO2 band gap from 3.2 to 2.7 eV and shifting the absorption edge in visual spectrum from 350–400 to 450–500 nm.
关键词： M?ssbauer spectroscopy,magnetic properties,Fe-doped TiO2
更新于2025-09-10 09:29:36
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Synthesis and characterization of Al-Fe-Cu tri-doped TiO <sub/>2</sub> by in-situ hydrothermal for degradation of methylene blue dyes
摘要： Pure TiO2 and a series of Al-Fe-Cu tri-doped TiO2 were synthesized by using in-situ hydrothermal method. The synthesized materials were characterized using X-ray diffraction (XRD), Fourier Transform Infrared (FTIR) and Scanning Electron Microscope (SEM). The photocatalytic activity of the samples was evaluated for degradation of methylene blue (5mgL-1) in aqueous solution under uv-visible light (λ= <420 nm). The XRD pattern showed that all samples exhibited anatase phase after calcined at temperature 500°C with crystallite size in the range of 10.00-13.23 nm. The FTIR spectra showed three important vibrational modes for vOH, δOH and vTiO that were assigned at range 3411.75-3399.27 cm-1, 1626.91-1630.53 cm-1 and 503.30- 530.93 cm-1, respectively. The degradation rate of Al(1mmol)-Fe-Cu tri-doped TiO2 showed the highest photocatalytic degradation with 93% compared to pure TiO2, Al(2 mmol)-Fe-Cu tri-doped TiO2 and Al(3mmol)-Fe-Cu tri-doped TiO2 were calculated as 76%, 85% and 80%, respectively. Hence, it can be seen that, the amount of Al ion-doping have influence on the photocatalytic degradation.
关键词： Al-Fe-Cu tri-doped TiO2,methylene blue,photocatalytic degradation,in-situ hydrothermal
更新于2025-09-10 09:29:36
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Structure, photocatalytic and antibacterial activity study of Meso porous Ni and S co-doped TiO2 nano material under visible light irradiation
摘要： Undoped and Ni-S co-doped Mesoporous TiO2 nano materials were synthesized by using sol-gel method. The characteristic features of as prepared catalyst samples were investigated using various advanced spectroscopic and analytical techniques. The characterization results of the samples revelled that all the samples exhibited anatase phase (XRD), decreasing band gap (2.68 eV) (UV-Vis-DRS), small particle size (9.2 nm) (TEM), High surface area (142.156 m2/g) (BET), particles with spherical shape and smooth morphology (SEM), there is a frequency shift observed for co-doped sample (FT-IR) and the elemental composition electronic states and position of the doped elements (Ni and S) in the TiO2 lattice analyzed by XPS and EDX. These results supported the photocatalytic degradation of Bismarck Brown Red (BBR) achieved with in 110 min and also exhibited the antibacterial activity on Staphylococcus aureus (MTCC-3160), Pseudomonas fluorescence (MTCC-1688) under visible light irradiation.
关键词： Sol-gel,photocatalysis under visible light,Antibacterial Activity,Ni-S co-doped TiO2,degradation of Bismarck Brown Red
更新于2025-09-10 09:29:36
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Preparation of activated carbon nanotube foams loaded with Ag-doped TiO2 for highly efficient photocatalytic degradation under UV and visible light
摘要： Titanium oxide (TiO2) has been widely investigated as a photocatalytic material for degradation of organic pollutant in waste water. However, nanosized granular TiO2 nanoparticles are hard to be recycled and re-utilized in water and many cause secondary pollution of water. Hence, we constructed a foam-like photocatalyst, which was composed of carbonaceous support: activated carbon nanotube foams and Ag-doped TiO2 nanoparticles through a method of a template synthesis and carbonization strategy. The as-prepared photocatalyst evidenced to be hierarchical macroporous and mesoporous and exhibited remarkable photocatalytic performance toward the degradation of unsymmetrical dimethylhydrazine under UV and visible light. The structure characterization and photocatalytic performance investigation confirmed that the enhanced photoresponse was attributed to the high efficiency of charge separation and the surface plasmon resonance effect of metallic Ag. The adsorption synergetic effect of the hierarchical porous structure also played an important role in photodegradation. The as-prepared photocatalyst showed great potential in the treatment of waste water containing organic pollutant.
关键词： Ag-doped TiO2,Photocatalytic degradation,Activated carbon nanotube foams,Unsymmetrical dimethylhydrazine,UV and visible light
更新于2025-09-10 09:29:36
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Antibacterial and photocatalytic activity of anatase phase Ag-doped TiO2 nanoparticles
摘要： A simple and new solid-state molten-salt method to synthesise silver (Ag)-doped titanium dioxide (TiO2) nanoparticles for solar light-induced photocatalytic applications is examined. Ag-doped TiO2 nanoparticles with varied Ag content ranging from 3 to 10% were synthesised by a single-step molten-salt synthesis method. The effect of Ag content on the antibacterial and photocatalytic activity of nanoparticles was tested. The prepared nanoparticles were studied by scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) spectrometry, ultraviolet–visible (UV–vis) diffusive re?ectance spectrometer (UV–vis DRS) and powder X-ray diffraction. The SEM image of nanoparticles clearly showed the presence of agglomerated spherical particles. The EDX analysis of the particles con?rmed successful doping of particles in the presence of the Ag in the particles. The doping of Ag in TiO2 produced TiO2 pure anatase phase. According to UV–vis DRS results, increasing Ag-doped content in the Ag-doped TiO2 resulted in a higher visible absorption capability of the materials. Ag doping also improved the antibacterial and photocatalytic activity of TiO2 nanoparticles. The maximum photocatalytic activity under light irradiation was observed for 5% Ag-doped TiO2.
关键词： antibacterial activity,anatase phase,photocatalytic activity,molten-salt method,Ag-doped TiO2
更新于2025-09-09 09:28:46
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Effects of Fe and Ni co-doping on the Optical Properties of TiO <sub/>2</sub> Thin Films
摘要： In this work, the effects of Fe/Ni co-doping on structural and optical properties of TiO2 thin films were investigated by the X-ray diffraction, scanning electron microscope and UV-visible spectroscopy. The optical properties of transmittance, extinction coefficient, refractive index, real and imaginary parts of dielectric constant of the thin films, prepared by spray pyrolysis, revealed that the absorption in visible region increases due to the influence of Fe/Ni co-doping. The widening of the gap energies is observed as a result of doping. The increased optical gap as a consequence of doping can be explained by decreasing the size of nanoparticles, as confirmed by SEM and increasing the formation of oxygen vacancies as a result of Ni2+ substitution to Ti4+ and appearance of the Burstein-–Moss effect.
关键词： Optical properties,Gap energy,Fe and Ni,Co-doped TiO2
更新于2025-09-09 09:28:46
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Photoactivity of Ag/TiO2 Microsphere by One-Step Hydrothermal Method
摘要： Ag/TiO2 microsphere photocatalyst was prepared via one step hydrothermal method and prepared catalyst was used for photodegradation of rhodamine B under visible light. The Ag/TiO2 catalyst was characterized through X-ray diffraction (XRD) and scanning electron microscope (SEM). The results showed Ag was uniformly distributed in the titanium matrix. The 6 % Ag doped TiO2 catalyst had the higher photoactivity than other proportion to degrade rhodamine B 86.6 % within 60 min under visible light. The Ag doped TiO2 also had the good activity under solar light cut off UV light.
关键词： Ag doped TiO2,Photodegradation,Hydrothermal method,Microsphere
更新于2025-09-09 09:28:46
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Impact of Overlapping Fe/TiO <sub/>2</sub> Prepared by Sol-Gel and Dip-Coating Process on CO <sub/>2</sub> Reduction
摘要： Fe-doped TiO2 (Fe/TiO2) film photocatalyst was prepared by sol-gel and dip-coating process to extend its photoresponsivity to the visible spectrum. To promote the CO2 reduction performance with the photocatalyst, some types of base materials used for coating Fe/TiO2, which were netlike glass fiber and Cu disc, were investigated. The characterization of prepared Fe/TiO2 film coated on netlike glass fiber and Cu disc was analyzed by SEM and EPMA. In addition, the CO2 reduction performance of Fe/TiO2 film coated on netlike glass disc, Cu disc, and their overlap was tested under a Xe lamp with or without ultraviolet (UV) light, respectively. The results show that the concentration of produced CO increases by Fe doping irrespective of base material used under the illumination condition with UV light as well as that without UV light. Since the electron transfer between two overlapped photocatalysts is promoted, the peak concentration of CO for the Fe/TiO2 double overlapping is approximately 1.5 times as large as the Fe/TiO2 single overlapping under the illumination condition with UV light, while the promotion ratio is approximately 1.1 times under that without UV light.
关键词： UV light,Fe-doped TiO2,visible spectrum,photocatalyst,dip-coating,sol-gel,CO2 reduction
更新于2025-09-09 09:28:46
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Construction of Ti3+ self-doped TiO2/BCN heterojunction with enhanced photoelectrochemical performance for water splitting
摘要： Ti3+ self-doped TiO2/BCN heterojunction (Ti3+-TiO2/BCN) was constructed via a hydrothermal method with using NaBH4 as reducing agent. The BCN nanosheets function as a good support to block the agglomeration of Ti3+-TiO2 nanoparticles, which decreased the recombination of photogenerated charge carriers. The Ti3+-TiO2/BCN sample exhibited enhanced electronic conductivity and absorption in visible light region because of the introduction of Ti3+ and oxygen vacancies (Ov). The as-prepared Ti3+-TiO2/BCN sample showed enhanced photoelectrochemical (PEC) performance as confirmed by analyses of LSV, EIS, Bode plots and M–S. Under the visible light irradiation, the optimally Ti3+ self-doped TiO2/BCN heterojunction sample yield a photocurrent density of ～ 0.69 mA/cm2 at 1.23 V versus RHE, which is over three times as high as BCN and TiO2/BCN at the same conditions.
关键词： hydrothermal method,photoelectrochemical performance,NaBH4,water splitting,Ti3+ self-doped TiO2/BCN heterojunction
更新于2025-09-04 15:30:14