- 标题
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Inkjet Printing of SiO2 Hollow Spheres/Polyimide Hybrid Films for Foldable Low-k ILD
摘要: We demonstrate inkjet printing as a viable method for flexible interlayer dielectrics (ILDs) films with a low dielectric constant, excellent mechanical characteristics, and thermal properties in foldable organic light emitting diodes (OLEDs). SiO2 hollow spheres (SHSs)/polyimide (PI) hybrid films were printed by SiO2 coated polystyrene (PS) ink and PI ink. The relative permittivity of the hybrid films decreased from 3.45 to 1.87. The thermally stable PI fims maintained their weight below 500 °C from the TGA result. The dielectric constant and current density retained their properties after 50,000 cycles of bending at a 1 mm bend radius. We propose that the inkjet printing of SHSs/PI hybrid films described herein is a promising approach for flexible ILDs in foldable OLEDs.
关键词: SiO2 hollow sphere,polyimide,foldable OLEDs,low-k material,inkjet printing,interlayer dielectric
更新于2025-09-10 09:29:36
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Optimization of dispersant-free colloidal ink droplets for inkjet patterning without the coffee-ring effect using 1-octanethiol-coated copper nano-ink with a Standard Clean-1-treated substrate
摘要: Inkjet-printed patterns and droplets were formed by the inkjet printing method on a Standard Clean-1 (SC-1)-treated substrate using anti-oxidized copper nano-ink. The hydrophobicity of the substrate increased after the SC-1 treatment. Copper nanoparticles were coated with 1-octanethiol vapors via a dry coating method to produce anti-oxidized nanoparticles, which were dispersed in a solvent to form a nano-ink. Droplets of the 1-octanethiol-coated copper nano-ink at 50 wt% concentration had a uniform morphology when printed on the SC-1-treated glass substrate. The minimum printed pattern line width was 55 μm on the SC-1-treated glass and had a resistivity of 1.73 × 10–7 ?·m. This resistivity was 4.3-times lower than that of the untreated substrate. Moreover, the pattern printed using the nano-ink made with 1-octanethiol-coated copper nanoparticles showed good adhesion and provided approximately 2.1-times lower resistivity. The dispersion of the nanoparticles within the droplet was more hydrophobic and formed uniform inkjet-printed patterns that had lower resistivity compared with those made with the uncoated nanoparticle-containing ink.
关键词: SC-1 treatment,Coffee-ring effect,1-Octanethiol-coated copper nano-ink,Inkjet printing,Resistivity
更新于2025-09-10 09:29:36
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Synthesis and Electrochemical Characterization of AgNP Ink Suitable for Inkjet Printing
摘要: To meet the growing demand for inkjet printable nanoparticle-based conductive inks, novel synthetic approaches are needed. In this study, spherical silver nanoparticles (AgNPs) with a mean diameter of approximately 2.5 nm were synthesized by the reduction of silver nitrate using an aqueous hydrazine solution in the presence of poly(acrylic acid) as a capping agent. The main goal of this work was the implementation of cyclic voltammetry as an electrochemical method for studying both the absorption of poly(acrylic acid) on the grain surface and nanoparticle interactions. The same technique was used to determine equimolar additions of hydrazine to obtain a high yield of reduced silver. All solutions used in the experiments were prepared at a high molar concentration. Silver nanoparticle-based ink was prepared by dispersing dried nanoparticles into a mixture of water and ethylene glycol and was stable for over seven months. For a comprehensive study of the prepared nanoink, UV-visible and electronic microscopy measurements were carried out. An inkjet technology was applied to deposit conductive ink to form linear silver tracks on a flexible substrate. These tracks exhibited a resistivity of 8.0×10-8 ?m.
关键词: conductive ink,poly(acrylic acid),cyclic voltammetry,Inkjet printing,silver nanoparticles
更新于2025-09-09 09:28:46
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[IEEE 2018 20th International Conference on Transparent Optical Networks (ICTON) - Bucharest (2018.7.1-2018.7.5)] 2018 20th International Conference on Transparent Optical Networks (ICTON) - Structuring of Magnetic Nanoparticle Fluids for Decorative and Functional Printing and Coating
摘要: Printing and coating of magnetic inks is widely used in the field of magnetic barcode labels. Nanoparticle inks have gained increasing interest in the field of printed electronics. Controlling the transport of magnetic nanoparticle fluids by external magnetic fields is nowadays mainly applied in environmental and biomedical research, e.g. in order to transport functionalised magnetic particles for drug delivery, sensing, thermal cancer therapy, or for the extraction of pollutants in waste water cleaning. Application examples of field assisted nanoparticle assembly or fluid control in coating and printing, e.g. for the structural colour generation in photonics, are recently emerging. In this paper, we address the topic of field assisted patterning by the design of a versatile magnetic pattering and structuring platform for field assisted nanoparticle assembly and locally tailored pattern formation in printing and thin film coating. 2D finite element modelling for tailored magnetic field patterning, as well as experimental inkjet printing and coating results for Fe2O3 iron oxide nanoparticles on glass are presented and discussed. The developed print patterning technique is of interest for decorative and functional printing and coating, e.g. for further developments in the application field of smart security tags.
关键词: superparamagnetic nanoparticles,coating,patterning system design,inkjet printing,nanoparticle inks,field assisted patterning
更新于2025-09-09 09:28:46
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Printable Fabrication of a Fully Integrated and Self-Powered Sensor System on Plastic Substrates
摘要: Wearable and portable devices with desirable flexibility, operational safety, and long cruising time, are in urgent demand for applications in wireless communications, multifunctional entertainments, personal healthcare monitoring, etc. Herein, a monolithically integrated self-powered smart sensor system with printed interconnects, printed gas sensor for ethanol and acetone detection, and printable supercapacitors and embedded solar cells as energy sources, is successfully demonstrated in a wearable wristband fashion by utilizing inkjet printing as a proof-of-concept. In such a “wearable wristband”, the harvested solar energy can either directly drive the sensor and power up a light-emitting diode as a warning signal, or can be stored in the supercapacitors in a standby mode, and the energy released from supercapacitors can compensate the intermittency of light illumination. To the best of our knowledge, the demonstration of such a self-powered sensor system integrated onto a single piece of flexible substrate in a printable and additive manner has not previously been reported. Particularly, the printable supercapacitors deliver an areal capacitance of 12.9 mF cm?2 and the printed SnO2 gas sensor shows remarkable detection sensitivity under room temperature. The printable strategies for device fabrication and system integration developed here show great potency for scalable and facile fabrication of a variety of wearable devices.
关键词: wearable and flexible devices,printable supercapacitors,printable gas sensors,monolithically integrated self-powered systems,inkjet printing
更新于2025-09-09 09:28:46
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A Diamine Silver(I) Carbonate: Ammonium Formate: Polyol-Based Water Soluble Ink for Inkjet Printing of Conductive Patterns
摘要: Electron devices are components used in ICT where information is encoded in the electronic charge channel. Among them, those manufactured through digital printing, benefited from a tremendous research effort the creation of a palette of functionalities provided by solution processed materials, to achieve dielectric, metallic and semiconductive behavior. The degree of metallicity of available printable inks very seldom goes below the threshold of 200 mΩ/□ which is fundamental for the fabrication of high quality conductors. Here we describe the formulation of a ink, based on Diamine Silver(I) Carbonate, Ammonium Formate and Polyols, providing several physicochemical characterizations and describing the process leading to sheet resistance below 200 mΩ/□ after a annealing at 120 °C for 5 minutes.
关键词: annealing,inkjet printing,metal pattern,Ag,metal-organic
更新于2025-09-04 15:30:14
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Inkjet-Printed High- <i>Q</i> Nanocrystalline Diamond Resonators
摘要: Diamond is a highly desirable material for state-of-the-art micro-electromechanical (MEMS) devices, radio-frequency filters and mass sensors, due to its extreme properties and robustness. However, the fabrication/integration of diamond structures into Si-based components remain costly and complex. In this work, a lithography-free, low-cost method is introduced to fabricate diamond-based micro-resonators: a modified home/office desktop inkjet printer is used to locally deposit nanodiamond ink as ?50–60 μm spots, which are grown into ≈1 μm thick nanocrystalline diamond film disks by chemical vapor deposition, and suspended by reactive ion etching. The frequency response of the fabricated structures is analyzed by laser interferometry, showing resonance frequencies in the range of ≈9–30 MHz, with Q-factors exceeding 104, and (f0 × Q) figure of merit up to ≈2.5 × 1011 Hz in vacuum. Analysis in controlled atmospheres shows a clear dependence of the Q-factors on gas pressure up until 1 atm, with Q ∝ 1/P. When applied as mass sensors, the inkjet-printed diamond resonators yield mass responsivities up to 981 Hz fg?1 after Au deposition, and ultrahigh mass resolution up to 278 ± 48 zg, thus outperforming many similar devices produced by traditional top-down, lithography-based techniques. In summary, this work demonstrates the fabrication of functional high-performance diamond-based micro-sensors by direct inkjet printing.
关键词: selective seeding,mass sensors,diamonds,micro-resonators,inkjet printing
更新于2025-09-04 15:30:14
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CHARACTERISATION OF COPPER NANOPARTICLE INK PRINTED FSS FOR CELLULAR SIGNALS SUPPRESSION
摘要: This paper proposes a copper nanoparticle ink printed frequency selective surface (FSS) for cellular signals suppression. The FSS pattern is deposited on a polyimide film by using an inkjet printing technique. The printed FSS elements undergo the post-processing called sintering, where the optimum exposure duration and temperature are determined in order to form a conductive path across the metal pattern. Later, the conductivity of the printed FSS structure deposited on polyimide film is observed. The signal suppression ability of the printed FSS is conducted using the Computer Simulation Technology (CST) Microwave Studio software.
关键词: cellular signals suppression,inkjet printing,copper nanoparticle ink,frequency selective surface,sintering
更新于2025-09-04 15:30:14