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[IEEE 2019 28th Wireless and Optical Communications Conference (WOCC) - Beijing, China (2019.5.9-2019.5.10)] 2019 28th Wireless and Optical Communications Conference (WOCC) - Crosstalk Prediction of Cables Based on Cosserat Elastic Rod Theory
摘要: A rhodium(III)-catalyzed domino annulation of simple olefins with diazo oxindoles to give spirooxindole pyrrolone products is described. This reaction can be formally viewed as the result of an anomalous tandem C(cid:2)H activation, carbene insertion, Lossen rearrangement, and a nucleophilic addition process. The potential utility of this reaction was further demonstrated by the late-stage diversification of drug molecules.
关键词: Lossen rearrangement,olefins,rhodium catalysis,oxindoles,C(cid:2)H activation
更新于2025-09-11 14:15:04