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Hybrid of quantum dots for interfacial tension reduction and reservoir alteration wettability for enhanced oil recovery (EOR)
摘要： Nanoparticle stabilized emulsions in enhanced oil recovery are more attractive and practical than conventional emulsions which stabilized by colloidal particles and different surfactants due to their advantages and special characteristics such as high stability in harsh condition, move long distance in reservoirs without high retention due to small size of nanoparticles. Only one third of original oil in place (OIP) is usually produced and two third of oil in place will be trapped to reservoir rockthus suitable chemical enhanced oil recovery (C-EOR) methods should be used. In this research, we have suggested a novel, economical and commercial method for synthesis N-doped graphene quantum dots (N-GQDs)/MoS2 quantum dots (MQDs) nanohybrids for preparing different percentage of Nanoemulsions which can reduce alterfacial tension significantly so it can used for Enhanced Oil Recovery (EOR) application. MoO3 material was used as a base of MQDs. MQDs was synthesized via exfoliation of MoS2 nanoparticles by Butyl lithium under N2 atmosphere condition. N-GQDs were synthesized by citric acid and urea materials via hydrothermal method. GQDs/MQDs were prepared via a simple sol-gel method for 5 h string. Synthetic materials were characterized with X-ray diffraction (XRD), Fourier transform infrared (FT-IR), UV–visible absorption, Scanning Microscopic Electron (SEM), EDX profile and mapping, Transmission electron microscopy (TEM), High Resolution Transmission electron microscopy (HRTEM) and differential scanning calorimetry (DSC). Then, emulsions were prepared with two different cationic and anionic surfactants and the stability and morphology of emulsion droplets were investigated in condition close to reservoir environment. Our results show that 10% GQDs/MQDs in cationic surfactant and 50% GQDs/MQDs in anionic surfactant have good stability and very small and fine emulsion droplets in simulated reservoir conditions in laboratory. The Interfacial Tension (IFT) measurement shows N70% improvement which indicates the high ability of these nanohybrids in reducing the surface tension than previous nanohybrids. Contact angle values show that these nanohybrids can alter the wettability of reservoir rock from oil-wet to water-wet so the trapped oil in the porous region of rock can be easily extracted in the presence of a layer of these nanohybrids. Furthermore, according to the results of altering the density and viscosity of nanohybrids, these are not as limiting parameters and only about 1% increasing observed for density and viscosity, respectively. Coreflooding test revealed the high oil recovery efficiency (22%) at very low nanofluid concentration (0.01 wt%).
关键词： Molybdenum disulfide quantum dots,Graphene quantum dots,Nanohybrids emulsion,Enhanced oil recovery (EOR),Quantum dot hybrids,Rock reservoir alteration wettability
更新于2025-09-23 15:21:01
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Effect of laser surface melting on surface integrity of Ala??4.5Cu composites reinforced with SiC and MoS2
摘要： Two types of composites were prepared with Al?4.5Cu alloy as a matrix using stir casting method. One was reinforced with 10 wt.% of SiC and 2 wt.% of MoS2. The other was reinforced with 10 wt.% of SiC and 4 wt.% of MoS2. Their surfaces were remelted using a CO2 laser beam with an objective to study the influence of laser surface melting (LSM). The topography, microhardness, corrosion resistance and wear resistance of the laser melted surfaces were studied. Overall surface integrity after LSM was compared with as-cast surface. LSM enhanced the microhardness and wear resistance of the surface in each case. Porosity of the laser melted surface was low and corrosion resistance was high. Thus, LSM can be conveniently applied to enhancing the surface integrity of the aluminium composites. However, there is an optimum laser specific energy, around 38 J/m2 in this study, for obtaining the best surface integrity.
关键词： microhardness,aluminium composites,laser surface melting,corrosion resistance,molybdenum disulfide,silicon carbide
更新于2025-09-23 15:21:01
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Molybdenum disulfide/silver/p-silicon nanowire heterostructure with enhanced photoelectrocatalytic activity for hydrogen evolution
摘要： Suitable semiconductor and its efficient coupling with catalysts is vital to hydrogen evolution reaction (HER). Herein, Ternary heterostructured MoS2/Ag/p-type silicon nanowires (SiNWs) array photocathode are constructed by a simple two-step method, where Ag is self-reduced on SiNWs via Galvanic Displacement method and MoS2 is subsequently loaded by direct thermal decomposition. Ag interfacial layer is introduced between Si and MoS2 to facilitate the charge transfer and suppress the recombination of photo-generated electron-hole pairs. MoS2/Ag/SiNWs exhibits an onset potential of 62 mV and photocurrent density of 50 mA cm?2 at ?1.0 VRHE, as well as good stability. Besides, MoS2/Ag/SiNWs is capable of generating 325.9 mL hydrogen per minute. The superior HER catalytic activity of MoS2/Ag/SiNWs is contributed to the improved charge transport at the solid–solid interfaces by virtue of Ag layer, allowing more electrons flow from SiNWs to MoS2 and thus effectively separating the photoelectrons and holes. This work demonstrates the potential of novel heterostructure for robust and efficient photoelectrochemical HER.
关键词： Heterostructure,Molybdenum disulfide,Hydrogen evolution,Ag layer,P-type silicon wires array
更新于2025-09-23 15:21:01
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Fabrication cobalt-doped indium oxide/molybdenum disulfide ternary nanocomposite toward carbon monoxide gas sensing
摘要： This paper demonstrated a high-performance carbon monoxide (CO) gas sensor based on cobalt (Co)-doped indium oxide (In2O3) nanoparticles/molybdenum disulfide (MoS2) nanoflowers nanocomposite. Co-In2O3 nanoparticles were synthesized by a co-precipitation method, and flower-like MoS2 was prepared by one-step hydrothermal route. Layer-by-layer self-assembly technique was employed to fabricate Co-In2O3/MoS2 film sensor on an epoxy substrate with interdigital electrodes. Scanning electron microscopy (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) were carried out to fully examine the morphology, microstructure, and elementary composition of the as-prepared samples. The CO-sensing characteristics of the Co-In2O3/MoS2 film sensor were systematically investigated under room temperature through exposing the sensor to various concentration of CO gas. The Co-In2O3/MoS2 sensor achieved high sensitivity, fast response/recovery speed, excellent repeatability and stable long-term stability. An approach of combining gas-sensing experiments with density-functional theory (DFT) simulation based on first-principle was used to further explore the CO-sensing mechanism of the Co-In2O3/MoS2 sensor. The Co2+ ion doping, and heterojunctions created at interfaces of Co-In2O3 and MoS2 were attributed to the high-performance CO sensing.
关键词： CO gas sensor,LbL self-assembly,molybdenum disulfide,first-principle theory,Co-doped indium oxide
更新于2025-09-23 15:21:01
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Revealing the Role of Gold in the Growth of Two-dimensional Molybdenum Disulfide by Surface Alloy Formation
摘要： Formation of Mo-Au surface alloy during Au-assisted chemical vapor deposition (CVD) of MoS2 was confirmed by a series of control experiments. We adapted a metalorganic chemical vapor deposition (MOCVD) system to conduct two-dimensional MoS2 growth in a controlled environment. Sequential injection of Mo and S precursors, which does not yield any MoS2 on a SiO2/Si, grows atomically thin MoS2 on Au, indicating formation of an alloy phase. Transmission electron microscopy of a cross-section of the specimen confirmed the confinement of the alloy phase near the surface only. These results show that the reaction intermediate is the surface alloy and that the role of Au in the Au-assisted CVD is formation of an atomically thin reservoir of Mo near the surface. This mechanism is clearly distinguished from that of MOCVD, which does not involve formation of any alloy phases.
关键词： Molybdenum Disulfide,Surface Alloy,Two-dimensional Material,Chemical vapor deposition,Metalorganic Chemical Vapor Deposition
更新于2025-09-23 15:21:01
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High-performance lateral MoS2-MoO3 heterojunction phototransistor enabled by in-situ chemical-oxidation; ??????????-|?°§????????oé????§è??MoS2-MoO3é?￠??????è′¨??? è′¨??????????????????;
摘要： Construction of in-plane p-n junction with clear interface by using homogenous materials is an important issue in two-dimensional transistors, which have great potential in the applications of next-generation integrated circuit and optoelectronic devices. Hence, a controlled and facile method to achieve p-n interface is desired. Molybdenum sulfide (MoS2) has shown promising potential as an atomic-layer n-type semiconductor in electronics and optoelectronics. Here, we developed a facile and reliable approach to in-situ transform n-type MoS2 into p-type MoO3 to form lateral p-n junction via a KI/I2 solution-based chemical oxidization process. The lateral MoS2/MoO3 p-n junction exhibits a highly efficient photoresponse and ideal rectifying behavior, with a maximum external quantum efficiency of ~650%, ~3.6 mA W?1 at 0 V, and a light switching ratio of ~102. The importance of the built-in p-n junction with such a high performance is further confirmed by high-resolution photocurrent mapping. Due to the high photoresponse at low source-drain voltage (VDS) and gate voltage (VG), the formed MoS2/MoO3 junction p-n diode shows potential applications in low-power operating photodevices and logic circuits. Our findings highlight the prospects of the local transformation of carrier type for high-performance MoS2-based electronics, optoelectronics and CMOS logic circuits.
关键词： optoelectronics,lateral p-n junction,molybdenum disulfide,photocurrent
更新于2025-09-23 15:19:57
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MoS2 Nanosheets Sensitized with Quantum Dots for Room-Temperature Gas Sensors
摘要： The Internet of things for environment monitoring requires high performance with low power-consumption gas sensors which could be easily integrated into large-scale sensor network. While semiconductor gas sensors have many advantages such as excellent sensitivity and low cost, their application is limited by their high operating temperature. Two-dimensional (2D) layered materials, typically molybdenum disulfide (MoS2) nanosheets, are emerging as promising gas-sensing materials candidates owing to their abundant edge sites and high in-plane carrier mobility. This work aims to overcome the sluggish and weak response as well as incomplete recovery of MoS2 gas sensors at room temperature by sensitizing MoS2 nanosheets with PbS quantum dots (QDs). The huge amount of surface dangling bonds of QDs enables them to be ideal receptors for gas molecules. The sensitized MoS2 gas sensor exhibited fast and recoverable response when operated at room temperature, and the limit of NO2 detection was estimated to be 94 ppb. The strategy of sensitizing 2D nanosheets with sensitive QD receptors may enhance receptor and transducer functions as well as the utility factor that determine the sensor performance, offering a powerful new degree of freedom to the surface and interface engineering of semiconductor gas sensors.
关键词： Nitrogen dioxide,Room temperature,Gas sensor,Molybdenum disulfide,Quantum dot
更新于2025-09-23 15:19:57
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Changes in the Photoluminescence of Monolayer and Bilayer Molybdenum Disulfide during Laser Irradiation
摘要： Various postsynthesis processes for transition metal dichalcogenides have been attempted to control the layer number and defect concentration, on which electrical and optical properties strongly depend. In this work, we monitored changes in the photoluminescence (PL) of molybdenum disulfide (MoS2) until laser irradiation generated defects on the sample flake and completely etched it away. Higher laser power was required to etch bilayer MoS2 compared to monolayer MoS2. When the laser power was 270 μW with a full width at half-maximum of 1.8 μm on bilayer MoS2, the change in PL intensity over time showed a double maximum during laser irradiation due to a layer-by-layer etching of the flake. When the laser power was increased to 405 μW, however, both layers of bilayer MoS2 were etched all at once, which resulted in a single maximum in the change of PL intensity over time, as in the case of monolayer MoS2. The dependence of the etching pattern for bilayer MoS2 on laser power was also reflected in position changes of both exciton and trion PL peaks. The subtle changes in the PL spectra of MoS2 as a result of laser irradiation found here are discussed in terms of PL quantum efficiency, conversion between trions and excitons, mean interatomic spacing, and the screening of Coulomb interaction.
关键词： photoluminescence,defects,etching,laser irradiation,molybdenum disulfide
更新于2025-09-23 15:19:57
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Preparation of Few-Layered Wide Bandgap MoS2 with Nanometer Lateral Dimensions by Applying Laser Irradiation
摘要： In this study, we report a new method for the quick, green, and one-step preparation of few-layered molybdenum disulfide (MoS2) nanosheets with wide bandgap. MoS2 nanosheets with small lateral dimension and uniform size distribution were synthesized for various applications. MoS2 powder was synthesized using the hydrothermal method; then, thinned by applying laser irradiation with different energies from 40 to 80 mJ. Transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-Vis absorption spectra, and photoluminescence (PL) spectra were applied for the characterization of the MoS2 nanosheets in terms of morphology, crystal structures, and optical properties. The widest calculated bandgap 4.7 eV was for the sample under 80 mJ laser energy. The results confirmed the successful preparation of highly pure, uniform, and few-layered MoS2 nanosheets. Furthermore, it was possible to enhance the production rate of MoS2 nanosheets (including nanosheets and nanoparticles) through laser irradiation. Thus, the present paper introduces a simple and green alternative approach for preparing few-layered MoS2 nanosheets of transition metal dichalcogenides or other layered materials.
关键词： low lateral dimension,few-layered,laser,molybdenum disulfide
更新于2025-09-23 15:19:57
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Two-Mode MoS <sub/>2</sub> Filament Transistor with Extremely Low Sub-Threshold Swing and Record High On/Off Ratio
摘要： With rapid development of integrated circuits, urge requirements for transistor with lower sub-threshold swing (SS) and better contact properties, are needed. To optimize the SS and contact issues, we propose a concept of molybdenum disulfide (MoS2) filament transistor with two-mode. We successfully fabricated the proposed devices in a wafer-scale. Mode I can enable the device with extremely low SS down to 2.26 mV/dec by switching contact filament between on and off while mode II can realize record high on/off ratio 2.6×109 by using filament as quasi-zero dimensional (quasi-0D) contact. Compared to conventional three dimensional (3D) contact, quasi-0D contact using conductive filament improves the current density nearly 50 times. We also built spice model to simulate the electrical behaviors and successfully predict proposed transistor owns extremely low SS in mode I (using abrupt filament formation/rupture) and excellent quasi-0D contact in mode II. The two-mode MoS2 filament transistor can significant improve the SS and contact comparing to those of the state-of-the-art transistors, which has the great potential to boost the development of next generation mainstream transistors.
关键词： sub-threshold swing,molybdenum disulfide,quasi-0D contact,filament transistor,on/off ratio
更新于2025-09-19 17:15:36