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[IEEE 2017 IEEE Workshop on Recent Advances in Photonics (WRAP) - Hyderabad (2017.12.18-2017.12.19)] 2017 IEEE Workshop on Recent Advances in Photonics (WRAP) - Effect of Moth-Eye Antireflective Coatings in Extraction of Far Field Intensity of an Organic Light Emitting Diode (OLED)
摘要： In this work, the OLED is modelled using Moth-eye Anti Reflective coatings to extract maximum far field intensity compared to Conventional OLED. Finite difference time domain method is used to simulate the OLED structure. The presented structure shows maximum far field intensity of 3.6μV/m.
关键词： Moth eye Antireflectors,Organic Light Emitting Diode,Total Internal Reflection
更新于2025-09-04 15:30:14
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Stable Hall voltages in presence of dynamic quasi-continuum bands in poly(3,4-ethylene-dioxythiophene)
摘要： Topological and thermal disorder complicate the mobility characterization in poly(3,4-ethylenedioxythiophene) systems and presently leaves the exact transport mechanisms not fully understood. Here we show that ac-Hall measured by lock-in amplifier is able to resolve the Hall voltage in semimetallic polymers between room temperature and 32 K. These results are evaluated using an organic random phase model. This accounts for the role of tail states and, particularly, for thermal disorder of molecular semiconductors. We report band mobilities up to 3.7 cm2 V?1 s?1 in semimetallic polymers occurring in delocalized bands that originate from significant electron coherence across the polymer chains.
关键词： Weak localization,Conducting polymers,PEDOT,Hall-effect,Organic phase model,Electron coherence
更新于2025-09-04 15:30:14
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Gas Adsorption and Fluorescent Sensing Properties of Two Porous Lanthanide Metal-Organic Frameworks Based on 3,5-Bis(2-carboxy-phenoxy)-Benzoic Acid
摘要： Two porous isomorphic 3D Eu(Ⅲ)/Nd(Ⅲ) lanthanide metal?organic frameworks (Ln-MOFs), formulated as {[Eu(BCPB)(H2O)(DMF)]·H2O·1.5CH3OH}n (1) and {[Nd(BCPB)(H2O)(DMF)]·2H2O}n (2), have been designed and synthesized by using the tripodal ligand of 3,5-bis(2-carboxy-phenoxy)-benzoic acid (H3BCPB) under solvothermal condition. Complexes 1 and 2 display 3D (3,6)-c net with the point symbol of {4.62}2{42.610.83}. Furthermore, fluorescent measurements showed 1 has highly selective detection for Fe3+ and CrO4 2- ions in aqueous solution, which shows that it acts as a chemical sensor for detecting Fe3+/CrO4 2- in aqueous solution. Meanwhile, gas adsorption properties of 1 and 2 have also been studied at different temperatures for N2, CH4 and CO2.
关键词： Fluorescent Properties,Adsorption Properties,Lanthanide Metal?Organic Frameworks,3,5-Bis(2-Carboxy-Phenoxy)-Benzoic Acid
更新于2025-09-04 15:30:14
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Experimental performance of commercial OPV panels tested outdoor
摘要： This work presents the experimental performance of commercial versions of organic photovoltaic (OPV) panels. Twenty four commercialized OPV panels of two different sizes (2.52 × 0.52 m and 1.29 × 0.52 m) were examined. Unfortunately, the company that provides the panels does not inform the technology behind the OPV they commercialize, but it provided a datasheet. We designed an outdoor test bench to make a parallelization between the commercial technology and scientific literature. The panels were bonded over a 0.04-m-thick acrylic layer to provide mechanical resistance and a clear view of the backside. The test bench was designed to allow panel tilt angles to be varied manually. We measured the total, beam, and diffuse radiation, along with the solar spectrum and all environmental conditions. Various topologies were tested, and results of power conversion efficiency (PCE) are presented. PCE was approximately 2% for all OPV panels, and was nearly stable during the four months of testing. PCE provided in the datasheet is ~3%, suggesting a loss of efficiency during the burn-in period.
关键词： outdoor tests,Organic photovoltaics (OPV),photovoltaic technology
更新于2025-09-04 15:30:14
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EXPRESS: Application of Different Fourier Transform Infrared (FT-IR) Methods in the Characterization of Lime-Based Mortars with Oxblood
摘要： Organic compounds have frequently been added into lime mortars for property modifications, in order to satisfy various functional needs in building techniques. This study applies Fourier transform infrared (FT-IR) spectroscopy in transmission, reflection, and attenuated total reflection (ATR) modes to characterize lime-based mortar specimens containing oxblood, which has been used as additive as a common practice of long history in many parts of the world. The specimens were prepared basing upon a 19th-century Italian historic recipe, with the intention to have a better understanding on the possible characteristics of such mortars. Thermal analysis, color measurement and static contact angle test were also used. After curing, the specimens show a distinctive dark-red color on the top surface, which is different from the bulk. Color measurements on the surface suggest that this color was formed at an early stage and was able to maintain stable for a relatively long period of time. Both transmission and reflection FT-IR confirm the preferential accumulation of proteins on the top surface, which should have induced their water repellency according to the static contact angle test. In addition, specimens show weaker calcite bands in FT-IR transmission, reflection, as well as ATR spectra; the pattern of ATR spectra after the thermal analysis to 500 °C suggests the formation of amorphous calcium carbonate, which is related to the presence of oxblood.
关键词： Mortar,oxblood,attenuated total reflection,ATR,reflection Fourier transform infrared,FT-IR,building techniques,organic additives
更新于2025-09-04 15:30:14
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Tailoring the Linear and Second-Order Nonlinear Optical Responses of the Titanium-MIL-125 Metal-Organic Framework through Ligand Functionalization: A First Principles Study
摘要： Density functional theory calculations have been performed to investigate the linear and second order nonlinear optical (NLO) properties of titanium-based MIL-125 metal-organic frameworks in crystalline form, in which the 1,4-benzene-dicarboxylate (BDC) linkers are modified by introducing different functional groups or by extending BDC ligand to contain two (MIL-126) and three (MIL-127) benzene rings. Our results reveal that the functionalization of BDC linker tends to increase the dielectric constants and the magnitude of birefringence of MIL-125, especially for the aminated derivatives. Correspondingly, the incorporation of substituent group will improve the phase matching performance of MIL-125. As for the second harmonic generation (SHG) susceptibility, the SHG activity of the pristine MIL-125 is comparable to KDP, which can be attributed mostly to the contributions of TiO5(OH) octahedra. It is noted that after introducing substituent group into BDC linker, the organic part will have a remarkable influence on the SHG intensity. However, the specific effect on the NLO response is dependent on the type of functional group incorporated into BDC ligand, and only the inclusion of amine group that is strongly electron-donating can obviously enhance the SHG activity of MIL-125. In addition, MIL-126 and MIL-127 with longer aromatic linking unit are not suitable to act as NLO materials due to their poor phase matching abilities, but they are the promising candidates for the low dielectric constant materials. The present study can provide theoretical insights to design new second-order NLO materials based on MIL-125.
关键词： Nonlinear Optical Properties,Density Functional Theory,Hybrid Materials,Ligand Functionalization,Metal-Organic Framework,Plasmonics,Optical,Magnetic
更新于2025-09-04 15:30:14
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Construction of a Layered Hydrogen-Bonded Organic Framework Showing High-Contrast Mechanoresponsive Luminescence Turn-On
摘要： This paper probes the mechanoresponsive luminescence and aggregation-induced emission (AIE) properties of N-phenylcarbazole-based thiophene/dicyanovinyl (T?DCV) derivatives. In bis-T?DCV planar molecule 1, a layered hydrogen-bonded organic framework (HOF) structure is formed with the assistance of multiple C?H···N and strong interlayer interactions. The formation of such a layer packing HOF structure can quench the solid fluorescent emission when aggregated as nanosuspensions but guarantees the high-contrast luminescence on?off switching (1.2 × 103 fold) in the solid state. Moreover, the grinding-induced destruction of HOF 1 is reflected by powder X-ray diffraction measurements, in which the destruction of the α and β rings in the planar HOF stripe and the close interlayer stacking could be observed. This work achieves the successful construction of long-wavelength emission AIE molecules (2 and 3) by introducing sufficient steric hindrance rotors to disturb the intermolecular π?π stacking and/or dipole?dipole interactions.
关键词： high-contrast luminescence,aggregation-induced emission,mechanoresponsive luminescence,hydrogen-bonded organic framework,thiophene/dicyanovinyl derivatives
更新于2025-09-04 15:30:14
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Electronic Tuning of Metal Nanoparticles for Highly Efficient Photocatalytic Hydrogen Peroxide Production
摘要： We here present an innovative approach to increase the electron density of metallic Pd nanoparticles loaded on TiO2 photocatalysts by coordinating Pd with surface-anchored organic ligands. X-ray photoelectron spectroscopy and X-ray absorption near edge structure measurements confirm the negative charge on the Pd nanoparticle induced by electron donation from amine groups of the ligands. The electronically modified Pd on TiO2 exhibits unprecedentedly high photocatalytic H2O2 production from O2 reduction. Mechanistic investigations suggest that the enhanced performance results from electronic tuning of Pd nanoparticles, leading to enhanced charge separation on TiO2 support, improved activity of Pd nanoparticles as an oxygen reduction center, and improved selectivity for O2 reduction to produce H2O2.
关键词： immobilized organic ligands,oxygen reduction reaction,electronic tuning,hydrogen peroxide,photocatalysis
更新于2025-09-04 15:30:14
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Quantitative determination of a model organic/insulator/metal interface structure
摘要： By combining X-ray photoelectron spectroscopy, X-ray standing waves and scanning tunneling microscopy, we investigate the geometric and electronic structure of a prototypical organic/insulator/metal interface, namely cobalt porphine on monolayer hexagonal boron nitride (h-BN) on Cu(111). Specifically, we determine the adsorption height of the organic molecule and show that the original planar molecular conformation is preserved in contrast to the adsorption on Cu(111). In addition, we highlight the electronic decoupling provided by the h-BN spacer layer and find that the h-BN–metal separation is not significantly modified by the molecular adsorption. Finally, we find indication of a temperature dependence of the adsorption height, which might be a signature of strongly-anisotropic thermal vibrations of the weakly bonded molecules.
关键词： hexagonal boron nitride,X-ray standing waves,X-ray photoelectron spectroscopy,cobalt porphine,Cu(111),scanning tunneling microscopy,organic/insulator/metal interface
更新于2025-09-04 15:30:14
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Collection efficiency of <i>α</i>-pinene secondary organic aerosol particles explored via light-scattering single-particle aerosol mass spectrometry
摘要： We investigated the collection ef?ciency and effective ionization ef?ciency for secondary organic aerosol (SOA) particles made from α-pinene + O3 using the single-particle capabilities of the aerosol mass spectrometer (AMS). The mean count-based collection ef?ciency (CEp) for SOA across these experiments is 0.30 (±0.04 SD), ranging from 0.25 to 0.40. The mean mass-based collection ef?ciency (CEm) is 0.49 (±0.07 SD). This sub-unit collection ef?ciency and delayed vaporization is attributable to particle bounce in the vaporization region. Using the coupled optical and chemical detection of the light-scattering single-particle (LSSP) module of the AMS, we provide clear evidence that “delayed vaporization” is somewhat of a misnomer for these particles: SOA particles measured as a part of the AMS mass distribution do not vaporize at a slow rate; rather, they ?ash-vaporize, albeit often not on the initial impact with the vaporizer but instead upon a subsequent impact with a hot surface in the vaporization region. We also ?nd that the effective ionization ef?ciency (de?ned as ions per particle, IPP) decreases with delayed arrival time. CEp is not a function of particle size (for the mobility diameter range investigated, 170–460 nm), but we did see a decrease in CEp with thermodenuder temperature, implying that oxidation state and/or volatility can affect CEp for SOA. By measuring the mean ions per particle produced for monodisperse particles as a function of signal delay time, we can separately determine CEp and CEm and thus more accurately measure the relative ionization ef?ciency (compared to ammonium nitrate) of different particle types.
关键词： aerosol mass spectrometer,collection efficiency,α-pinene,ionization efficiency,delayed vaporization,particle bounce,secondary organic aerosol
更新于2025-09-04 15:30:14