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Effect of fullerene substituent on thermal robustness in polymer:fullerene bulk heterojunction solar cells
摘要： Effect of fullerene substituent on thermal robustness in polymer:fullerene bulk heterojunction solar cells using a conjugated polymer PTB7-Th. While 175 °C is the best annealing temperature for a solar cell with unmodified C70, it deteriorates a device with a substituted C70 (C70-PCBM). Additionally, annealing at 175 °C does not change the surface of PTB7-Th:C70 film but makes the surface of PTB7-Th:C70-PCBM film bumpy. The results suggest that the substituent promotes the migration of fullerene in polymer:fullerene solid composite.
关键词： fullerene,C70-PCBM,PTB7-Th,bulk heterojunction solar cells,thermal robustness
更新于2025-09-11 14:15:04
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Ultrasensitive Photoelectrochemical Assay with PTB7-Th/CdTe QDs Sensitized Structure as Signal Tag and 4-CD Precipitate as Efficient Quencher
摘要： Herein, an ultrasensitive photoelectrochemical (PEC) assay was developed for the monitoring of microRNA-141 (miRNA-141) based on poly{4,8-bis[5-(2-ethylhexyl)thiophen-2-yl]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl-alt-3-fluoro-2-[(2-ethylhexyl)-carbonyl]thieno[3,4-b]thiophene-4,6-diyl} (PTB7-Th)/CdTe quantum dots (CdTe QDs) sensitized structure as signal tag and the benzo-4-chloro-hexadienone (4-CD) precipitate as efficient quencher. PTB7-Th and CdTe QDs were successively modified on electrode surface to form a novel sensitized structure with eminent photovoltaic performances and surpassing film-forming ability. The PTB7-Th/CdTe QDs sensitized structure was served as signal tag for achieving a strong initial PEC signal. Besides, a tiny amount of target (miRNA-141) could be transformed into numerous DNA product via enzyme-assisted target cycling procedure, which further triggered the formation of DNA supersanwich structure on electrode surface for loading abundant manganese porphyrin (MnPP). Thereafter, MnPP as mimetic enzyme could catalyze 4-chloro-1-naphthol (4-CN) to generate 4-CD precipitate on sensing interface in the presence of H2O2, which could efficiently block electron transfer, leading to a significantly quenched PEC signal for determination of miRNA-141. The designed PEC biosensor performed a wide detection range from 0.1 fM to 1 nM with a low detection limit of 33 aM for miRNA-141, which paved a new avenue for highly accurate and ultrasensitive monitoring of multifarious analytes in bioanalysis and clinical diagnosis.
关键词： 4-CD precipitate,photoelectrochemical assay,ultrasensitive monitoring,miRNA-141,PTB7-Th/CdTe QDs,signal tag
更新于2025-09-10 09:29:36
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Planar capacitive type humidity sensor fabricated using PTB7-Th by facile solution processing approach
摘要： A capacitive humidity sensor using coplanar electrodes coated with poly[4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)benzo[1,2-b;4,5-b′]dithiophene-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene-)-2-carboxylate-2-6-diyl](PTB7-Th) thin film (Al/PTB7-Th/Al) has been fabricated and investigated. In the present work, we show that increased sensitivity is obtained by rough and non-uniform surface morphology of the polymer thin film which comprises distinct peaks and valleys. The sensor shows good sensing behavior with enhanced sensitivity, better linearity and larger bandwidth. The device showed sensitivity over an appreciable range of relative humidity levels (between 20 and 95% RH). Typical adsorption and desorption response times were measured to be 20 s each.
关键词： Sensitivity,Bandwidth,Linearity,PTB7-Th,Solution processing,Capacitive humidity sensor
更新于2025-09-04 15:30:14