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Pest Control Lamp in Green Food Bases Based on Wind-solar Complementary Generation System
摘要： According to the energy complementary characteristics of wind energy and solar energy in time and space, in this study, the wind turbine and solar cells are used to design a pest control lamp in green food bases powered by a small power wind-solar complementary supply system and the intelligent controller is used to charge and discharge the batteries, realizing various protection functions. Application shows that the pest control lamp in green food bases system has the advantages of low manufacturing cost and high reliability, suitable for being used in farmland and woodland which are far from the grid.
关键词： generation system,green food bases,pest control lamp,Battery,wind turbine,solar cell
更新于2025-09-04 15:30:14
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Counteranion-Triggered and Excitation-Dependent Chemopalette Effect in a Supramolecular Dual-Emissive System Based on Cu <sub/>3</sub> Pz <sub/>3</sub>
摘要： Three Cu3Pz3-based isostructural complexes (Cu3L3)2(CuX)2 (labeled as 1-ClO4, 1-NO3, and 1-Br, where X = ClO4?, NO3?, and Br?, respectively) were prepared by solvothermal reactions of an angular bifunctional pyridyl?pyrazole ligand, 4-(pyridin-4′-ylthio)-3,5-dimethyl-1H-pyrazole (HL), with Cu(ClO4)2, Cu(NO3)2, and CuBr, respectively. Pyrazolate (Pz) groups are highly specific to form planar trinuclear Cu3Pz3 units. Two Cu3L3 units are further connected by two CuX units through NPy?Cu?NPy (Py = 4-pyridyl) bonds to form an octanuclear chairlike molecule (Cu3L3)2(CuX)2, which then self-assembles through intertrimeric cuprophilicity to construct chainlike supraaggregates featuring two luminophores, [Cu3Pz3]2 and CuPy2X. With different counteranions (ClO4?, NO3?, and Br?), the complexes give off various emissions from red to green upon UV irradiation. 1-ClO4 and 1-NO3 show only low-energy (LE) orange (λemmax = 585 nm) and red (λemmax = 640 nm) emissions, while 1-Br exhibits excitation-dependent (260?360 nm) emissions from yellow to green due to variation in the relative intensities of two resolvable emissions, high energy (HE, λemmax = 520 nm) and LE (λemmax = 630 nm). The dual emissions are assigned to 3CC (LE states) based on excimeric [Cu3Pz3]2 units and 3XLCT/3MLCT (HE states) based on CuPy2X units. This work realizes a chemopalette effect through regulations of the counteranion and excitation energy in a dual-emissive system. It provides valuable insights into the nature of dual-emissive materials and the further investigation of the photophysical mechanism in such a system.
关键词： Cu3Pz3-based complexes,excitation-dependent,dual-emissive system,counteranion-triggered,chemopalette effect
更新于2025-09-04 15:30:14
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Security Authentication of Dual Chaotic Image Watermarking in Spatial Domain with Spatial and Frequency Domain Characteristics Analysis
摘要： This article presents an advanced dual chaotic watermarking scheme to improve information security. To ensure confidentiality in digital image transmission, a secure dual watermarking scheme is proposed by applying the chaotic logistic system and hyper-chaotic dynamical system. Chaotic watermarking was conducted in the spatial domain, where suboptimal secure hashing with a variable length was selected in preprocessing stages. The secret key was generated by the chaotic sequence for pixel shuffling using a chaotic logistic map, so that a controlled amount of distortion was inserted into the host digital image. Watermarking was proceeded after the chaotic watermark had been embedded into the shuffled image. To strengthen the security, the hyper-chaotic system was used to generate chaotic blocks for block scrambling in order to achieve dual chaotic watermarking. Characteristics analysis was conducted for multiple examples in both spatial and frequency domains. Potential effects induced by the chaotic driving parameter on processing time and integrity authentication of chaotic dual watermarking were also analyzed in detail.
关键词： hashing,information security,shuffling,hyper-chaotic system,scrambling,watermarking,logistic map
更新于2025-09-04 15:30:14