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Investigation of sol-gel and nanoparticle-based NiOx hole transporting layer for high-performance planar perovskite solar cells
摘要： We conduct a comprehensive study on and comparison of sol-gel and nanoparticles (NPs)-based nickel oxide hole-transporting layer (HTL) for high-performance planar perovskite solar cells (PSCs). The characteristics and film properties of sol-gel and NPs were systemically investigated using ultraviolet photoelectron spectroscopy (UPS), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and photoluminescence (PL), and its effect on device-performance was also examined using J-V characteristics, quantum-efficiency, and the VOC dependence of the light intensity. Through this comparison of two types of HTL and their device-performances, these studies can provide sufficient and robust information for nickel oxide-based PSCs, and furthermore, the overall results and discussions can be useful for high-performance PSCs.
关键词： Nickel oxide,Planar perovskite solar cells,Hole transporting layer,Sol-gel,Nanoparticles
更新于2025-11-19 16:46:39
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Dopant-free hole transporting materials with supramolecular interactions and reverse diffusion for efficient and modular p-i-n perovskite solar cells
摘要： The rational design of dopant-free organic hole-transporting layer (HTL) materials is still a challenge for realizing high-efficient and stable p-i-n planar perovskite solar cells (pero-SCs). Here, we synthesized two π-conjugated small-molecule HTL materials through tailoring the backbone and conjugated side chain to carefully control molecular conformation. The resultant BDT-TPA-sTh containing a planar fused benzo[1,2-b:4,5-b′]dithiophene (BDT) core and a conjugated thiophene side chain showed the planar conformation. X-ray crystallography showed a favorable stacking model in solid states under the parallel-displaced π-π and additional S-π weak-bond supramolecular interactions, thus achieving an obviously increased hole mobility without dopants. As an HTL material in p-i-n planar pero-SCs, the marginal solubility of BDT-TPA-sTh enabled inverse diffusion into the perovskite precursor solution for assisting the subsequent perovskite film growth and passivating the uncoordinated Pb2+ ion defects. As a result, the planar p-i-n pero-SCs exhibited a champion power conversion efficiency (PCE) of 20.5% and enhanced moisture stability. Importantly, the BDT-TPA-sTh HTL material also showed weak thickness-photovoltaic dependence, and the pero-SCs with blade-coated BDT-TPA-sTh as a HTL achieved a 15.30% PCE for the 1-cm2 modularized device. This HTL material design strategy is expected to pave the way toward high-performance, dopant-free and printing large-area planar p-i-n pero-SCs.
关键词： hole-transporting materials,p-i-n planar perovskite solar cells,reverse diffusion,supramolecular interactions
更新于2025-09-23 15:21:01
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The influence of fullerene on hysteresis mechanism in planar perovskite solar cells
摘要： Despite the rapid development of perovskite devices, the current density-voltage hysteresis still needs to be conquered. Here, the introduction of PCBM into the active layer of planar perovskite solar cells is carried out and hysteresis-free devices are produced. A photoluminescence blue-shift in PCBM-doped perovskite ?lms is observed. The e?ect of non-radiative recombination is obviously suppressed, and the photoluminescence lifetime is signi?cantly prolonged by 3-fold after PCBM introduction. The roles of PCBM in trap states and hysteresis mechanism are also discussed. This research could provide experimental and theoretical supports for suppressing and eliminating the hysteresis phenomena in perovskite solar cells.
关键词： Hysteresis,Trap states,Planar perovskite solar cells,PCBM
更新于2025-09-23 15:19:57
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Life cycle assessment of hole transport free planara??mesoscopic perovskite solar cells
摘要： Organo-metal lead halide perovskite solar cells (PSCs) attract attention due to their low cost and high power conversion efficiency. Some weak points of this technology are short lifetime, instability, and expensive metal electrode deposition. Eliminating the unstable hole transport layer (HTL) and using carbon-based materials as the counter electrode would address both. In this work, we present a cradle-to-gate life cycle assessment of two HTL-free PSC designs, which use solution phase deposition to achieve mesoscopic and planar structures. Environmental impacts of producing 1 m2 PSCs are converted to impacts per kWh electricity generation assuming 5 years of operational lifetime. We find that major impacts come from fluorine doped tin oxide (FTO) glass patterning due to the electricity consumption of FTO patterning and glass cleaning processes. Even though the electricity consumption when manufacturing both PSCs is similar, their different efficiencies make the environmental impacts per kWh of electricity higher for the mesoscopic PSC than for the planar PSC. Energy payback time values of planar PSCs and mesoscopic PSCs are 0.58 and 0.74 years, respectively, and these values are shorter than those of commercial first and second generation solar cells. However, the global warming potential (GWP) values of planar and mesoscopic PSCs are 75 and 94 g CO2-eq/kWh, respectively, and these values are still higher than those of commercial solar cells. To reach the GWP of commercial cells, the operational lifetime would have to be 8 and 10 years for planar and mesoscopic PSCs, respectively.
关键词： mesoscopic,environmental impacts,HTL-free,life cycle assessment,planar,perovskite solar cells
更新于2025-09-23 15:19:57
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Nonconfinement Structure Revealed in Dion–Jacobson Type Quasi‐2D Perovskite Expedites Interlayer Charge Transport
摘要： Dion–Jacobson (DJ) type 2D perovskites with a single organic cation layer exhibit a narrower distance between two adjacent inorganic layers compared to the corresponding Ruddlesden–Popper perovskites, which facilitates interlayer charge transport. However, the internal crystal structures in 2D DJ perovskites remain elusive. Herein, in a p-xylylenediamine (PDMA)-based DJ perovskite bearing bifunctional NH3+ spacer, the compression from confinement structure (inorganic layer number, n = 1, 2) to nonconfinement structure (n > 3) with the decrease of PDMA molar ratio is unraveled. Remarkably, the nonconfined perovskite displays shorter spacing between 2D quantum wells, which results in a lower exciton binding energy and hence promotes exciton dissociation. The significantly diminishing quantum confinement promotes interlayer charge transport leading to a maximum photovoltaic efficiency of ≈11%. Additionally, the tighter interlayer packing arising from the squeezing of inorganic octahedra gives rise to enhanced ambient stability.
关键词： exciton,planar perovskite solar cells,nonconfinement structures,Dion–Jacobson,quasi-2D perovskite
更新于2025-09-19 17:13:59
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Low Temperature Processed Highly Efficient Hole-Transport-Layer Free Carbon-based Planar Perovskite Solar Cells with SnO2 Quantum Dot Electron-Transport-Layer
摘要： The use of expensive hole transport layer (HTL) and back contact along with the stability issue of perovskite solar cells have been a detrimental factor when it comes to commercialization of the technology. In addition, high-temperature and long annealing time processed electron transport layers (ETLs, e.g., TiO2) prevents the flexible solar cell application in most polymer substrate. Herein, we opted for HTL-free carbon electrodes owing to their low-cost production and superior stability in air, compared to their noble metal counterparts. In this work, we fabricate planar perovskite solar cells using low-temperature solution processed SnO2 quantum dots (QDs) as ETL, which offers significant advantages over high temperature processed ETLs due to its excellent electron extraction and hole blocking ability. In addition, by integrating a low cost and stable carbon electrode, an impressive energy conversion efficiency of 13.64% with a device architecture glass/In doped SnO2/QD-SnO2/Perovskite/Carbon under 1 sun illumination at ambient conditions have been achieved. This work paves the way to achieve fully low-temperature processed printable perovskite solar cells (PSCs) at an affordable cost by integrating the QD SnO2 ETL and Carbon electrode.
关键词： low-temperature process,planar perovskite solar cells,hole transport layer free,carbon electrode,SnO2 Quantum Dot
更新于2025-09-19 17:13:59
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Record Photocurrent Density over 26a??mAa??cm <sup>a??2</sup> in Planar Perovskite Solar Cells Enabled by Antireflective Cascaded Electron Transport Layer
摘要： Here an antireflective cascaded SnO2/TiO2-Cl electron transport layer (ETL) is devised to enhance the performance of planar perovskite solar cells (PSCs). The primary optical reflection of planar PSCs at the front side can be dramatically reduced by using cascaded ETL. Based on this strategy, we achieved a record-high short-circuit current density of 26.1 mA cm-2 and a high PCE of 22.9% in FAPbI3-based planar PSCs.
关键词： planar perovskite solar cells,cascaded electron transport layers,anti-reflection,bilayer,short-circuit current density
更新于2025-09-19 17:13:59
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Highly Efficient CsPbBr3 Planar Perovskite Solar Cells via Additive Engineering with NH4SCN
摘要： Improving stability is a major aspect of the commercial application of perovskite solar cells (PSCs). The all inorganic CsPbBr3 perovskite material has been proven to have excellent stability. However, the CsPbBr3 film has a small range of light absorption and a serious charge recombination at the interface or inside the device, so that the power conversion efficiency is still lower than that of the organic-inorganic hybrid one. Here, we successfully fabricate high quality CsPbBr3 film via additive engineering with NH4SCN. By incorporating NH4+ and pseudo-halide ion SCN? into precursor solution, a smooth and dense CsPbBr3 film with good crystallinity and low trap state density can be obtained. At the same time, the results of a series of photoluminescence and electrochemical analyses including electrical impedance spectroscopy, space-charge limited current method, Mott-Schottky data, and so on, reveal that the NH4SCN additive can greatly reduce trap state density of the CsPbBr3 film, and also effectively inhibit interface recombination and promote charge transport in the CsPbBr3 planar PSC. Finally, the CsPbBr3 planar PSC prepared with molar ratio of 1.5 % NH4SCN achieves a champion efficiency of 8.47 %, higher than the pure one (7.12 %).
关键词： Additive engineer,Planar perovskite solar cells,CsPbBr3,Photovoltaic performance,NH4SCN
更新于2025-09-19 17:13:59
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Investigating the Role of Reduced Graphene Oxide as a Universal Additive in Planar Perovskite Solar Cells
摘要： In this work we present the effects of the incorporation of reduced graphene oxide (rGO) nanoflakes into the titania compact layer, the methylammonium lead iodide (CH3NH3PbI3) absorber and the Spiro-MeOTAD hole transporter which are typical components of a planar perovskite solar cell (PSC). The addition of rGO within the TiO2 electron transport layer (ETL) offers fast electron transport rates toward the anode and favors the growth of large, uniform perovskite crystals. When added in MAPbI3, rGO further increases the perovskite grains size and creates a more homogenous and smooth film with enhanced crystallinity, thus improving the power conversion efficiency (PCE) of the corresponding PSC. On the contrary, its presence in Spiro-MeOTAD is detrimental for the cells performance. For the first time in the literature a graphene derivative favors the performance of a MAPbI3–based PSC when incorporated as an additive in both the ETL and the perovskite absorber. As a result, we obtained devices with optimized electrical characteristics, resulting to stabilized 13.6% PCE, outperforming by 20% the reference (rGO-free) ones. Moreover, the presence of rGO offered additional stability to the solar cells which retained 40% of their initial PCE after 50 days of storage in mildly humid, dark environment.
关键词： Reduced graphene oxide,Lead acetate,Planar perovskite solar cells,MAPbI3 absorber,Titania compact layer
更新于2025-09-16 10:30:52
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The role of moisture in the preparation for efficient planar perovskite solar cells
摘要： Perovskite solar cells (PSC) have achieved a certificated efficiency of 25.2% within the past few years. Among effective methods, one of the most effective approaches obtaining highly-efficient PSCs is the moisture-assisted annealing process. However, the role of moisture in the preparation of high-performance PSCs is under intense debate. Herein the critical effect of moisture in the preparation of efficient Formamidinium (FA) based PSCs with improved-quality perovskite films is systematically investigated based on diverse characterizations. Consequently, the optimal amount of moisture is determined at 50% relative humidity (RH) which produces perovskite films of higher quality with larger and uniform grains size in comparison to the control films prepared in the glovebox. Specifically, prolonged lifetime, reduced defects densities and higher light harvesting capability of perovskite films annealed in 50RH% are confirmed by the photoluminescence (PL), the time-resolved PL (TRPL), the space charge limited current (SCLC) and the confocal laser scanning microscopy (CLSM), respectively. These results indicate the environments with a controlled level of moisture is preferable for achieving high-quality perovskite films and the compatibility of fabricating highly-efficient PSCs under ambient conditions with controlled moisture for future industrial mass production.
关键词： defects density,two-step deposition,Planar perovskite solar cells,moisture,space-charge-limited current
更新于2025-09-16 10:30:52