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oe1(光电查) - 科学论文

3 条数据
?? 中文(中国)
  • Tunable luminescence and transmittance nature of CdS:PMMA nanocomposites for optoelectronic applications

    摘要: Optical and energy storage materials based on semiconductors are of great interest today. The present report explains the semiconductor nanocomposite centered on highly transparent Poly(methyl methacrylate) (PMMA) matrix and Cadmium Sulphide (CdS) nano particles. The solid ?lms of CdS:PMMA composite was prepared using simple and cost e?ective solution casting technique. The surface morphology and the presence of CdS particles in PMMA matrix was analysed using Scanning Electron Microscope (SEM) and Energy Dispersive X-ray spectra (EDX). The size of the particles was analysed using Atomic Force Microscopy (AFM) and Transmission Electron Microscope (TEM) and they revealed the presence of nano sized particles. The narrow size distribution of particles was identi?ed from TEM and AFM analysis. The transmittance of the CdS:PMMA nanocomposite solid ?lms was found to be above 90%. The blue and green emission of CdS:PMMA nanocomposite solid ?lms were observed from Photoluminescence (PL) spectra.

    关键词: Composite materials,Polymeric composite,Luminescence,Green emission,Particle distribution,Transmittance

    更新于2025-09-23 15:21:01

  • In Situ Ion Exchange Synthesis of Cauliflower-like AgBr/Ag3PO4/Sulfonated Polystyrene Sphere Heterojunction Photocatalyst With Enhanced Photocatalytic Activity

    摘要: The cauliflower-like AgBr/Ag3PO4/sulfonated polystyrene sphere (SPS) heterojunction photocatalyst was prepared using wastewater containing silver ion and SPS as raw materials via in situ ion change method. The AgBr/Ag3PO4/SPS photocatalyst was characterized by field emission scanning electron microscopy, X-ray diffraction and UV–Vis diffuse reflectance spectra (UV–Vis DRS). The results showed that AgBr nanoparticles and Ag3PO4 nanoparticles are highly dispersed on the surface of sulfonated polystyrene. And the heterogeneous junction structures are also formed between AgBr and Ag3PO4, which is benefit for the separation of photogenerated electrons and holes. Hence, the AgBr/Ag3PO4/SPS photocatalyst had an excellent activity for photocatalytic degradation of rhodamine B (RhB) in water under visible light irradiation. The cyclic test results showed that the AgBr/Ag3PO4/SPS photocatalyst also had a good stability.

    关键词: Semiconductor,Functional material,Polymeric composite,AgBr/Ag3PO4/SPS

    更新于2025-09-19 17:15:36

  • Optical linearity and bandgap analysis of RhB-doped PMMA/FTO polymeric composites films: A new designed optical system for laser power attenuation

    摘要: Thin films of PMMA doped with Rhodamine B-dye have deposited successfully on a fluorine-doped tin oxide (FTO) glass substrate as a new optical system by using a spin coating method. This new system is promising to be used in various technological applications as solar energy cells, electronic apparatuses, devices of optical filter properties and optoelectronic tools. X-ray diffraction (XRD) illustrates a uniform and semicrystalline structure in nature for the obtained thin films. A spectrophotometric investigation was applied on the prepared thin films at the range of (300–2500 nm) for the wavelength. Both linear refractive index and absorption index values were measured to be reduced as the wavelength was raised. Tauc’s plot indicated that direct and indirect transitions were displayed by the thin film. Both direct and indirect bandgaps were calculated and analyzed. Continuous waves of the green laser beam (operating at 532), and He-Ne laser beam (operating at 632.8 nm) were used to study the optical properties of the prepared thin films with different dye concentrations. The results illustrated that the polymeric composites films are highly attenuated for the laser beam of 532 nm. The designed RhB-doped PMMA/FTO composites can be extensively appropriate to the optoelectronic applications.

    关键词: Laser power attenuations,Polymeric composite films,Direct and indirect bandgap,Rhodamine B dye,PMMA/FTO films

    更新于2025-09-11 14:15:04