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- 2019
- Dye-sensitized solar cell
- Photoelectrode
- Light scattering layer
- Transmittance
- White pigment (R902+)
- Rutile titanium dioxide
- Optoelectronic Information Materials and Devices
- Tribhuvan University
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Investigation of arc dynamics during vacuum arc remelting of a Ti64 alloy using a photodiode based instrumentation
摘要： Understanding the arc dynamics during VAR is important for controlling the final quality of the ingot, as the spatial and temporal distribution of the arc dictates the electric current and energy inputs at the ingot top, which in turn affect the hydrodynamics of the metal in the molten pool and the solidification conditions of the ingot. The arc dynamics during vacuum arc remelting was quantitatively investigated based on the analysis of the light emitted by the arc and reflected by the molten pool using photodiodes placed inside a full-scale furnace. The measurements allowed us to determine the location of the arc luminosity centroid and to follow its displacement as a function of time. They were made during the melt of a Ti64 alloy with an imposed alternated electromagnetic stirring of high intensity. The arc dynamics was found to be most of the time periodic, asymmetrical, and strongly correlated to the evolution of the stirring magnetic field. The arc centroid exhibited three regular displacement patterns throughout the melt. A common characteristic to all three patterns was the relative stability of the centroid during stirring plateaus and its rapid motion during stirring ramps. An evolution towards a much more centered distribution of the centroid was observed with the arc power decrease during the hot-topping phase. Possible implications of the observed arc dynamics on the final quality of the VAR ingot are discussed.
关键词： Electric arc,Photodiodes,Titanium alloy,Vacuum arc remelting,Dynamics
更新于2025-09-23 15:21:21
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Biomolecular interaction and kinematics differences between P25 and E171 TiO2 nanoparticles
摘要： Titanium dioxide (TiO2) nanoparticles (NPs) are used abundantly as food additives (E171). For the purpose of risk assessment, it is imperative to understand the behavior of these nanoparticles in a food relevant environment, and their consequent toxicology impacts. However, most of such studies use model TiO2 NPs (P25) as substitutes for E171. To understand the suitability of this approach, we investigated the functional behavior of E171 and P25 in solutions of bovine serum albumin (BSA) and sucrose as model food ingredients. Our data showed that E171 were better dispersed in BSA than P25. In sucrose, E171 displayed a reduction in agglomerated size while P25 agglomerated extensively. Adsorption studies showed that P25 attracted more pronounced corona formation per unit mass of material compared to E171. In vitro sedimentation, diffusion and dosimetry (ISDD) results demonstrated that the time-weighted dosage of E171 was more than two-folds higher than P25, implying that any test performed using P25 to model E171 would underestimate actual dosage and potential toxicity. Taken collectively, this study demonstrated the specificity of TiO2 nanoparticle interaction with food ingredients, and the importance of using food-grade E171 TiO2 for food-relevant toxicological assessments.
关键词： ISDD,Nanoparticles,Titanium dioxide,Sucrose,Corona,Protein
更新于2025-09-23 15:21:21
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Modulating the photocatalytic activity of TiO2 (P25) with lanthanum and graphene oxide
摘要： The modulation and tuning of the photocatalytic activity of commercial titanium dioxide (TiO2) P25 nanoparticles is demonstrated through the incorporation of lanthanum (La) and/or graphene oxide (GO). These composite materials, which could have applications in commercial products, were prepared by a two-step hydrothermal method from the corresponding precursors. The effect of La (0.05 - 2 mol%) and GO (5 m%) content on the crystal structure, morphology and photocatalytic activity of TiO2 was investigated by XRS, SEM, EDS, TEM, UV-visible DRS, point of zero charge, photoluminescence and the decolorization of methylene blue. Lanthanum modified the recombination rate of the photogenerated electron-hole charges on TiO2 by inducing an increase in the structural defects, which resulted in a significant suppression, up to 90%, of the photocatalytic activity in the UVA light region. In contrast, the addition of GO enhanced the photocatalytic activity of TiO2. Materials with tuned intermediate photoactivity within the entire range from high to very low were prepared by dosing appropriate amounts of La and GO species. The strategy of combining La and GO represents a useful and simple method for tuning or for suppressing the photocatalytic activity of TiO2 under UVA light irradiation in materials and consumer products using TiO2.
关键词： lanthanides,rare earths,titanium dioxide,graphene oxide
更新于2025-09-23 15:21:21
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Low-temperature-dependent growth of titanium dioxide nanorod arrays in an improved aqueous chemical growth method for photoelectrochemical ultraviolet sensing
摘要： The growth of titanium dioxide nanorod arrays (TNAs) in aqueous solutions containing titanium butoxide and hydrochloric acid can be controlled by regulating the temperature from 115 to 150 °C as an adjustable physical parameter. The transparent colloidal solution of titanates is clouded on the basic growth of TNAs when heated at a certain temperature using an improved aqueous chemical growth method in a clamped Schott bottle. The structural, optical and electrical properties of grown TNAs films were thoroughly investigated and discussed. The distinct and high-intensity peaks observed in the X-ray diffraction pattern and Raman spectra of the grown TNAs show the rutile phase with high crystal quality. The crystallite size, diameter size, and thickness of TNAs decrease with decreasing growth temperature. The prepared TNAs were used to detect 365 nm ultraviolet (UV) photon energy (750 μW/cm2) in a photoelectrochemical cell structure with a maximum photocurrent of 26.31 μA and minimum photocurrent of 3.48 μA recorded for TNAs grown at 150 °C and 115 °C, respectively. The size, structural properties, charge transfer resistance, and electron lifetime play a key role in determining the UV sensing characteristics of the TNAs. Results show that TNAs are very promising in fabricating a UV sensor with a high response at 0 V bias even at a low growth temperature of 115 °C.
关键词： Photoelectrochemical ultraviolet sensing,Titanium dioxide nanorod arrays,Rutile phase,Aqueous chemical growth method,UV sensor
更新于2025-09-23 15:21:21
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Impact of Laser Structuring on Medical-Grade Titanium: Surface Characterization and In Vitro Evaluation of Osteoblast Attachment
摘要： Improved implant osteointegration offers meaningful potential for orthopedic, spinal, and dental implants. In this study, a laser treatment was used for the structuring of a titanium alloy (Ti6Al4V) surface combined with a titanium dioxide coating, whereby a porous surface was created. The objective was to characterize the pore structure shape, treatment-related metallographic changes, cytocompatibility, and attachment of osteoblast-like cells (MG-63). The treatment generated specific bottleneck pore shapes, offering the potential for the interlocking of osteoblasts within undercuts in the implant surface. The pore dimensions were a bottleneck diameter of 27 μm (SD: 4 μm), an inner pore width of 78 μm (SD: 6 μm), and a pore depth of 129 μm (SD: 8 μm). The introduced energy of the laser changed the metallic structure of the alloy within the heat-affected region (approximately 66 μm) without any indication of a micro cracking formation. The phase of the alloy (microcrystalline alpha + beta) was changed to a martensite alpha phase in the surface region and an alpha + beta phase in the transition region between the pores. The MG-63 cells adhered to the structured titanium surface within 30 min and grew with numerous filopodia over and into the pores over the following days. Cell viability was improved on the structured surface compared to pure titanium, indicating good cytocompatibility. In particular, the demonstrated affinity of MG-63 cells to grow into the pores offers the potential to provide significantly improved implant fixation in further in vivo studies.
关键词： orthopedics,titanium,surface,osteointegration,coating,dental,laser
更新于2025-09-23 15:21:01
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Effect of laser shock processing on oxidation resistance of laser additive manufactured Ti6Al4V titanium alloy
摘要： The high-temperature oxidation resistance of laser additive manufactured (LAM) Ti6Al4V before and after laser shock processing (LSP) was investigated. The samples were oxidized at 400?800 °C for 1?50 h in air. The results revealed that the rate of weight gain of the Ti6Al4V fabricated through LAM decreased, and LSP had a positive effect on increasing the oxidation resistance. At an oxidation temperature of 700 °C, an aluminum-rich layer was observed in the cross-section before LSP. After LSP, the aluminum-rich layer changed to three layers. The aluminum-rich layer prevented the diffusion of oxygen, which improved the oxidation resistance of the Ti6Al4V.
关键词： Ti6Al4V titanium alloy,High-temperature oxidation resistance,Laser shock processing,Laser additive manufacturing
更新于2025-09-23 15:21:01
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Comparative Study on Microstructure and Aluminum Distribution Between Laser Beam Welding and Electron Beam Welding of Tia??6Ala??4V Alloy Plates
摘要： Ti–6Al–4V alloy plates with a thickness of 4 mm were joined by electron beam welding (EBW) and laser beam welding (LBW). The comparison of LBW and EBW was performed according to grain morphology, microstructure, aluminum distribution, and microhardness of the joints. Results indicate that compared with LBW joint, more equiaxed grains are observed around the central zone of the EBW joint. The microstructure in fusion zone (FZ) of EBW joint presents more uneven with obviously coarser acicular martensite α′. Moreover, the aluminum element content of EBW joint is substantially lower, which demonstrates a more significant burning loss behavior in EBW process. The lower aluminum content in the upper center areas of the joints is attributed to the more significant element burning loss caused by higher temperature, whereas more uniform aluminum distribution in the upper part of the joints is ascribed to stronger convection form within the upper part of the joint. In addition, the characteristics of convection and thermal field within the molten pool are recognized as vital factors influencing the aluminum distribution. The lower microhardness profile in FZ of the EBW joint is principally attributed to coarser acicular martensite α′ and lower aluminum element in EBW joint.
关键词： Electron beam welding,Microhardness,Microstructure,Burning loss,Titanium alloy,Laser beam welding
更新于2025-09-23 15:21:01
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Surface engineering of a titanium alloy for tribological applications by nanosecond-pulsed laser
摘要： In many applications, surface engineering is needed in order to overcome the poor wear properties of titanium alloys. A fiber laser was used in different operation modes for remelting a Ti6Al4V surface and subsequently smoothing it again, resulting in a smooth, glossy and crack-free surface. The laser treated surface was characterized by tribological experiments, nanoindentation and (transmission) electron microscopy and compared to samples treated by plasma nitridation and thermal oxidation. All surface treatments improved the tribological behavior of Ti6Al4V to different extents. Nanoindentation measurements showed no strict correlation of mechanical properties and tribological behavior. It is hypothesized that apart from mechanical properties, binding of titanium electrons by interstitials plays a role in the occurrence or absence of adhesive wear.
关键词： Titanium alloys,Surface engineering,Adhesive wear,Ti6Al4V
更新于2025-09-23 15:21:01
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Suppressing Shallow Defect of Printable Mesoscopic Perovskite Solar Cells with a N719@TiO <sub/>2</sub> Inorganic-Organic Core-Shell Structured Additive
摘要： Shallow defects are one of the energy states that trap photoexcited electrons leading to charge recombination and limit the increase in the photocurrent of perovskite solar cells (PSCs). Due to the large perovskite thickness and uncontrollable crystallization processes, suppressing shallow defects, especially methylamine (MA) vacancies, has become a key challenge for fully printable PSCs. Herein, nano-TiO2 is unprecedentedly used to load the commercial dye N719, forming N719@TiO2 nanoparticles, which crucially improves the passivation effect of MA vacancies on the surface of perovskite and charge extraction, by the unbounded carboxyl group of N719 as a shell on the surface of TiO2. Meanwhile, the core TiO2 serves as a centre to bind the dyes, assisting the perovskite crystallization and enhancing the passivation effect. It is found that the charge extraction increases to 1.8007 (cid:1) 10 N719@TiO2 from 1.5507 (cid:1) 10 short-circuit current density (Jsc) is signi?cantly enhanced to 23.58 mA cm in the device containing N719@TiO2 over that of the control device (21.95 mA cm PSCs via organic passivator with carboxyl anchoring group loaded on n-type semiconductors (nano-TiO2).
关键词： passivation,printable solar cells,dyes,titanium dioxide,perovskite solar cells
更新于2025-09-23 15:21:01
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Analysis of helium used as protective gas in Laser Metal Deposition of Ti6Al4V highly reactive material
摘要： Laser Material Deposition (LMD) is an additive manufacturing near-net-shape process. Metal powder particles are molten by means of a laser heat source and added to a substrate creating geometries. This technology offers the possibility of generating coatings, repairing damaged high-added-value parts, and manufacturing components with complex 3D geometries. Many industrial sectors, including aerospace and die and mold industries, are interested in this process due to its capabilities and the wide range of materials that can be used with it. Previous works aimed to develop a protective gas module to be able to process highly reactive materials without the necessity of a complete inert atmosphere inside the machine. Additionally, the influence of a mixture of argon and helium on the LMD process for other non-highly reactive alloys was evaluated. Hence, the present work aims to broaden the understanding of how the combination of these two factors may affect the LMD process, combining these previous studies and evaluating the phenomenon for a highly reactive alloy like Ti6Al4V. The study involves the melt-pool temperature measurement and characterization of the deposited clads variating not only the composition of the protective gas but also the flow rates.
关键词： LMD,Ti6Al4V,Helium,Titanium,Shielding gas,protective atmosphere,He,Laser Metal Deposition,Argon,Ar
更新于2025-09-23 15:21:01