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Identification of heavy metal-contaminated Tegillarca granosa using laser-induced breakdown spectroscopy and linear regression for classification
摘要： Tegillarca granosa (T. granosa) is susceptible to heavy metals, which may pose a threat to consumer health. Thus, healthy and polluted T. granosa should be distinguished quickly. This study aimed to rapidly identify heavy metal pollution by using laser-induced breakdown spectrometry (LIBS) coupled with linear regression classification (LRC). Five types of T. granosa were studied, namely, Cd-, Zn-, Pb-contaminated, mixed contaminated, and control samples. Threshold method was applied to extract the significant variables from LIBS spectra. Then, LRC was used to classify the different types of T. granosa. Other classification models and feature selection methods were used for comparison. LRC was the best model, achieving an accuracy of 90.67%. Results indicated that LIBS combined with LRC is effective and feasible for T. granosa heavy metal detection.
关键词： laser-induced breakdown spectrometry,shellfish,linear regression classification,heavy metal
更新于2025-09-23 15:21:01
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The classification of plants by laser-induced breakdown spectroscopy based on two chemometric methods
摘要： The applications of laser-induced breakdown spectroscopy (LIBS) on classifying complex natural organics are relatively limited and their accuracies still needs to be improved. To study the methods on classification of complex organics, three kinds of fresh leaves were measured by LIBS in this work. 100 spectra from 100 samples of each kind of leaves were measured and then they were divided into training set and test set in a ratio of 7:3. Two algorithms of chemometric methods including the partial least squares discriminant analysis (PLS-DA) and principal component analysis Mahalanobis distance (PCA-MD) were used to identify these leaves. By using 23 lines from 16 elements or molecules as input data, these two methods can both classify these three kinds of leaves successfully. The classification accuracies of training set are both up to 100% by PCA-MD and PLS-DA, respectively. The classification accuracies of test set are 93.3% by PCA-MD and 97.8% by PLS-DA, respectively. It means that PLS-DA is better than PCA-MD in classifying plant leaves. Because the components in PLS-DA process are more suitable for classification than those in PCA-MD process. We think that this work can provide a reference for plant traceability using LIBS.
关键词： classification of complex organics,partial least squares discriminant analysis,principal component analysis Mahalanobis distance,laser-induced breakdown spectroscopy
更新于2025-09-23 15:21:01
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EXPRESS: Potentialities of a Laser-Induced Breakdown Spectroscopy Technique in the Study of Polymer Composites
摘要： A laser-induced breakdown spectroscopy (LIBS) technique was used to evaluate the filler content in particulate epoxy–copper composites. A potential application for a direct and fast measurement of the filler in composites through the LIBS results is suggested using calibrated samples. The methodology used in this work makes possible the incorporation of LIBS as a quantitative technique for the study of particle metal filled epoxy composites, providing a method to obtain a direct estimation of the filler volume fraction.
关键词： LIBS,Laser-induced breakdown spectroscopy,epoxy composites,copper,plasma
更新于2025-09-23 15:21:01
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A Study of the Optical and Acoustic Spectral Characteristics by Laser Breakdown of Water in an Ultrasonic Field
摘要： A strong dependence of the optical breakdown in a liquid in the ultrasonic field on the amplitude and frequency of ultrasound is demonstrated. The increase in the intensity of spectral lines of potassium and oxygen during the optical breakdown is detected by the increase in the amplitude and frequency of ultrasound. At the same time, the effect of saturation is observed at high frequencies (above 200 kHz) and for high ultrasonic powers, when the growth in the intensity of spectral lines slows sharply down. This shows that there is no necessity to use high powers and frequencies of ultrasound to study the opto-acoustic effects during optical breakdown in a liquid.
关键词： ultrasound,spectral lines,optical breakdown,laser-spark spectroscopy,opto-acoustic effects
更新于2025-09-23 15:21:01
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Potential Application of Lasera??Induced Breakdown Spectroscopy (LIBS) Data for the Determination of Cation Exchange Capacity (CEC) of Agricultural Soils
摘要： The potential for Laser Induced Breakdown Spectroscopy (LIBS) technique to predict cation exchange capacity (CEC) values in agricultural soils, based on a partial least square (PLS) regression model, was investigated by analysing soils (N = 225) using a portable LIBS system. The prediction from the validation set was 0.75 and the RMSE was 5.4 cmol + /kg. Analysis of the PLS loading weights showed that emission lines that correlate with the exchangeable cations (Ca, Mg, K and Na) and clay (Al and Si) are significant. Good quality predictions could be obtained from the model as described by the ratio of performance to deviation (RPD) values calculated for calibration (RPDc = 1.99) and validation (RPDv = 2.02). The ratio of performance to interquartile distance (RPIQ) for calibration (RPIQc = 3.20) and validation (RPIQv = 3.32) indicated excellent prediction capability. It has been demonstrated that LIBS spectra coupled with multivariate data analysis could be used to predict CEC of agricultural soils which is considered fast and a chemical-free technique.
关键词： cation exchange capacity,agricultural soil,analytical chemistry,spectroscopic method,laser induced-breakdown spectroscopy
更新于2025-09-23 15:21:01
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Rapid quality assessment of isogams using laser plasma spectroscopy
摘要： In this paper, the quality assessment of isogams is demonstrated by laser-induced breakdown spectroscopy (LIBS) using the comparative standardization method. Here, the mass concentrations of carbon and hydrogen, as basic elements of tar, relative to that of calcium, as an undesired element, are taken into account as principal parameters to determine the quality of isogams. Hence, the intensity ratios of H?? line of hydrogen (656.28?nm), the (0, 0) band of CN (388.34?nm), and the (0, 0) band of C2 (516.52?nm) to the line intensity of once-ionized calcium (317.93?nm) are considered as determinant markers for five different pre-known isogam brands. Qualitatively, classification of the isogams based on this approach is in full agreement with that obtained from the results of Fourier-transform infrared (FTIR) spectroscopy. In FTIR spectra, two stronger transitions of 2849?cm?1 and 2917?cm?1 related to the symmetric and asymmetric stretching vibrations of C–H play the principal role in the analysis of samples. Furthermore, the results obtained from energy-dispersive X-ray (EDX) analysis quantitatively confirm the LIBS outcomes. And finally, to reveal the differences between isogams from various aspects, the linear discriminant analysis (LDA) is exploited as a statistical approach.
关键词： FTIR spectroscopy,EDX analysis,Linear discriminant analysis (LDA),Laser-induced breakdown spectroscopy (LIBS),Isogams,Quality assessment
更新于2025-09-23 15:21:01
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Spectral Characterization of Collinear Double-Pulse Laser Induced Breakdown Spectroscopy (DP-LIBS) for the Analysis of the Chinese Traditional Medicine <i>Artemisia annua</i>
摘要： A collinear dual-pulse laser induced breakdown spectroscopy (DP-LIBS) method was employed to analyze Chinese traditional medicine Artemisia annua. The spectral intensities and signal-to-background ratios of magnesium (II) 279.54 nm, CN 388.29 nm, calcium (II) 393.37 nm, and iron (II) 404.27 nm were used to evaluate the optical emission characteristics of A. annua induced by DP-LIBS. The temporal evolution characteristics, inter-pulse time, and laser energy values were optimized. In particular, the electron density and the temperatures of the plasma were reported as functions of the delay time. The results showed that the DP-LIBS had stronger intensity and better accuracy compared to single-pulse (SP) LIBS. The enhancement factors obtained using DP-LIBS for Mg, CN, Ca, and Fe were 7.2, 8.9, 13.8, and 3.4, respectively. This study provides important information about A. annua.
关键词： signal enhancement,plasma parameters,double-pulse laser induced breakdown spectroscopy (DP-LIBS),Artemisia annua
更新于2025-09-23 15:21:01
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Analysis of Salt Mixture Contamination on Insulators via Laser-Induced Breakdown Spectroscopy
摘要： The composition of contamination deposited on transmission line insulators can affect their surface flashover voltage. Currently, there is no rapid on-line method to detect this contamination composition in power grids. In this paper, we applied laser-induced breakdown spectroscopy (LIBS) to analyze contamination on insulator surfaces. Usually, Na and Ca salts are found in contamination along with various sulfate, carbonate, and chloride compounds. As an element’s detection method, LIBS can only measure a certain element content, for example, Ca. The mixture of various compounds with the same cations can influence the LIBS signal. The influence of mixing ratios on the calibration curves and relative spectral intensity was studied via LIBS. Na2CO3, NaHCO3, CaSO4, and CaCO3 samples containing different proportions of Na and Ca were prepared. The linear correlation coefficients (R2) for the Na and Ca calibration curves generated using various mixing ratios were analyzed. The results showed that the mixture ratio did not dramatically affect the linear calibration curves for mixtures containing the same cations. This finding may significantly reduce the difficulty of applying LIBS analysis for complex contamination on insulators. The laser energy density had effects on the spectral characteristics of the measured elements. The partial least-square regression (PLSR) model can improve the accuracy of Na and Ca prediction.
关键词： salt,insulators,calibration curves,laser-induced breakdown spectroscopy,contamination
更新于2025-09-23 15:21:01
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[IEEE 2019 IEEE MTT-S International Microwave Workshop Series on Advanced Materials and Processes for RF and THz Applications (IMWS-AMP) - Bochum, Germany (2019.7.16-2019.7.18)] 2019 IEEE MTT-S International Microwave Workshop Series on Advanced Materials and Processes for RF and THz Applications (IMWS-AMP) - New approach for the simulation of bent and crumpled antennas on a flexible substrate
摘要： First-ever 28 nm embedded split-gate MONOS (SG-MONOS) ?ash macros have been developed to increase memory capacity embedded in micro controller units and to improve performance over wide junction temperature range from C to 170 C as demanded strongly in automotive uses. Much attention has been paid to the degradation of the reliability characteristics along with the process shrinkage. Temperature-adjusted word-line overdrive scheme improves random read access frequency by 15% and realizes both of 6.4 GB/s read throughput by 200 MHz no-wait random access of code ?ash macros and more than ten times longer TDDB lifetime of WL drivers. Temperature-adaptive step pulse erase control (TASPEC) improves the TDDB lifetime of dielectric ?lms between metal interconnect layers by three times. TASPEC is particularly useful for a data ?ash macro with one million rewrite cycles. Source-side injection (SSI) program with negative back-bias voltage achieves 63% reduction of program pulse time and, consequently, realizes 2.0 MB/s write throughput of code ?ash macros. A spread spectrum clock generation and a clock phase shift technique are introduced for charge pump clock generation in order to suppress EMI noise due to high write throughput of code ?ash macros, and peak power of EMI noise is reduced by 19 dB.
关键词： high reliability,spread spectrum clock generation,word-line overdrive,Automotive application,split-gate MONOS(SG-MONOS),embedded ?ash memory,time dependent dielectric breakdown,high-temperature operation,Fast random read operation
更新于2025-09-23 15:19:57
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Determination of uranium in ores using laser-induced breakdown spectroscopy combined with laser-induced fluorescence
摘要： The plasma emission spectrum of uranium in laser-induced breakdown spectroscopy (LIBS) is weak and susceptible to spectral interference, especially in a complex ore matrix. In this study, laser-induced breakdown spectroscopy combined with laser-induced fluorescence (LIBS-LIF) technology was proposed to enhance the spectral intensity of uranium in ores and eliminate spectral interference. Different combinations of excitation lines and analytical lines of the U element were investigated. In contrast with atomic lines, uranium ion lines are more suitable for determination of uranium. The relative number of U ions in plasma was studied for the best selection of excitation lines and analytical lines. The analytical performance of LIBS-LIF and LIBS for U determination in ores was compared. The results showed that all indicators had been significantly improved by LIBS-LIF. The slope, R2, LoD, RMSECV, ARE, and ARSD values of LIBS-LIF were 1.1 (cid:1) 105 counts per wt%, 0.998, 35 mg g(cid:3)1, 0.05 wt%, 6.69%, and 6.37%, respectively. This work demonstrates that LIBS-LIF has excellent potential in the exploration of uranium resources.
关键词： laser-induced breakdown spectroscopy,uranium,spectral interference,laser-induced fluorescence,ore matrix
更新于2025-09-23 15:19:57