Chlorine Vacancy Passivation in Mixed Halide Perovskite Quantum Dots by Organic Pseudohalides Enables Efficient Rec. 2020 Blue Light-Emitting Diodes

摘要： Blue-emitting perovskites are easily attainable by precisely tuning the halide ratio of mixed halide (Br/Cl) perovskites (MHPs). However, the adjustable halide ratio also hinders the passivation of Cl vacancies – the main source of trap states leading to inferior performance blue MHP light-emitting diodes (LEDs). Here, we report a strategy to passivate Cl vacancies in MHP quantum dots (QDs) using non-polar-solvent-soluble organic pseudohalide (n-dodecylammonium thiocyanate (DAT)), enabling blue MHP LEDs with greatly enhanced efficiency. Density-functional-theory calculations reveal that the thiocyanate (SCN-) groups fill in the Cl vacancies and remove electron traps within the bandgap. DAT-treated CsPb(BrxCl1-x)3 QDs exhibit near unity (~100%) photoluminescence quantum yields; and their blue (~470 nm) LEDs are spectrally stable with an external quantum efficiency (EQE) of 6.3% – a record for perovskite LEDs emitting in the 460-480 nm range relevant to Rec. 2020 display standards – and a half-lifetime of ~99 s.