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1000 h Operational Lifetime Perovskite Solar Cells by Ambient Melting Encapsulation
摘要： Improving device lifetime is one of the critical challenges for the practical use of metal halide perovskite solar cells (PSCs), wherein a reliable encapsulation is indispensable. Herein, based on an in-depth understanding of the degradation mechanism for the PSCs, a solvent-free and low-temperature melting encapsulation technique, by employing low-cost paraffin as the encapsulant that is compatible with perovskite absorbers, is demonstrated. The encapsulation strategy enables the full encapsulating operations to be undertaken under an ambient environment. It is found that the strategy not only removes residual oxygen and moisture to prevent the perovskite from phase segregation, but also suppresses the species volatilization to impede absorber decomposition, enabling a PSC devices with good thermal and moisture stability. As a result, the as-encapsulated PSCs achieve a 1000 h operational lifetime for the encapsulated device at continuous maximum power point output under an ambient environment. This work paves the way for scalable and robust encapsulation strategy feasible to hybrid perovskite optoelectronics in an economic manner.
关键词： stability,perovskite solar cells,solvent-free,ambient encapsulation,low-temperature
更新于2025-09-16 10:30:52
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Regulated Crystallization of Efficient and Stable Tin-based Perovskite Solar Cells via Self-sealing Polymer
摘要： Tin-based perovskite solar cells (PVSCs) have emerged as the most promising lead-free perovskite materials owing to their superior optoelectronic properties. However, the deficiency of accurate control for the tin-based perovskite crystallization process increases the possibility of unexpected perovskite film morphology and defects, resulting in inferior power conversion efficiency (PCE). Meanwhile, the poor environmental stability of tin-based perovskite film hinders its further development. In this work, a unique polymer [poly(ethylene-co-vinyl acetate) (EVA)] is introduced into anti-solvent during spin coating of formamidinium tin tri-iodide (FASnI3) precursor solution. The C=O groups contained in EVA have a powerful Lewis acid-base complexation with uncoordinated tin atoms in perovskite grains, which can greatly improve grain size, optimize grain orientation and decrease surface defects of FASnI3 films. This strategy offers an impressive PCE of 7.72% with favorable reproducibility. More importantly, the PVSCs devices based on FASnI3-EVA absorber have a self-encapsulation effect, which exhibits distinguished moisture and oxygen barrier property, thereby retaining 62.4% of the original efficiency value after aging for 48 h in air environment with humidity of 60%. Such convenient strategy provides a new inspiration for the establishment of stable and high performance tin-based PVSCs.
关键词： environmental stability,self-encapsulation,poly(ethylene-co-vinyl acetate),crystallization,tin-based perovskite solar cells
更新于2025-09-16 10:30:52
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Enhanced Stability of MAPbI3 Perovskite Solar Cells using Poly(p-chloro-xylylene) Encapsulation
摘要： We demonstrated an effective poly(p-chloro-xylylene) (Parylene-C) encapsulation method for MAPbI3 solar cells. By structural and optical analysis, we confirmed that Parylene-C efficiently slowed the decomposition reaction in MApbi3. From a water permeability test with different encapsulating materials, we found that parylene-c-coated MApbi3 perovskite was successfully passivated from reaction with water, owing to the hydrophobic behavior of parylene-c. As a result, the parylene-c-coated MApbi3 solar cells showed better device stability than uncoated cells, virtually maintaining the initial power conversion efficiency value (15.5 ± 0.3%) for 196 h.
关键词： perovskite solar cells,MAPbI3,stability,Parylene-C,encapsulation
更新于2025-09-12 10:27:22
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Slot-die processing and encapsulation of non-fullerene based ITO-free organic solar cells and modules
摘要： Organic photovoltaic (OPV) devices have shown remarkable performance progress in recent years, reaching current record power conversion efficiency (PCE) values of 16.4% for single junction and 17.3% for multi junction devices, owing mostly to the impressive developments made within synthesis of new non-fullerene acceptors. This progress places organic solar cells at the forefront of thin-film photovoltaic technology. However, in order to meet industrial demands and reach high performance values in industrial settings, further research and development efforts within Roll-to-Roll (R2R) and Sheet-to-Sheet (S2S) processing of OPV devices under ambient conditions are required. Furthermore, OPV modules being manufactured through such up-scaled processing techniques should ideally be developed from low cost materials, and show good stability towards various different operational stress conditions. In this work, we demonstrate combined R2R and S2S development of ITO-free OPV devices, which are based on the non-fullerene material system PBDB-T:ITIC. The devices are processed from R2R vacuum sputtering and S2S slot-die coating at ambient conditions, and reach cell PCE values of 5.5%. In addition, we introduce a correlation between different barrier films, both commercial and sputtered inorganic coatings on ultra-clean PET, and the lifetime of the developed devices. The results therefore demonstrate an important step in the development of OPV devices from R2R and S2S processes in industrial settings.
关键词： organic solar cells and modules,Roll-to-Roll (R2R),Sheet-to-Sheet (S2S),organic photovoltaics (OPV),slot-die coating,device encapsulation,non-fullerene acceptors
更新于2025-09-12 10:27:22
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Optical Voltammetry of Polymer-Encapsulated Single-Walled Carbon Nanotubes
摘要： The semiconducting single-walled carbon nanotube (SWCNT), noncovalently wrapped by a polymeric monolayer, is a nanoscale semiconductor?electrolyte interface under investigation for sensing, photonics, and photovoltaic applications. SWCNT complexes are routinely observed to sensitize various electrochemical/redox phenomena, even in the absence of an external ?eld. While the photoluminescence response to gate voltage depends on the redox potential of the functionalized nanotube, analogous optical voltammetry of carbon nanotubes could be conducted in suspension without applying voltage but by varying the solution conditions as well as the chemistry of the encapsulating polymer. Steady-state photoluminescence, absorbance, and in situ measurements of O2/H2O reactivity show correlation with the pH/pKa-dependent reactivity of π-rich coatings. The nanotube emission responses suggest that the presence of photogenerated potential may explain the observed coating electrochemical reactivity. This work ?nds that electronic and chemical interactions of the nanotube with the encapsulating polymer may play a critical role in applications that depend on radiative recombination, such as optical sensing.
关键词： redox phenomena,optical voltammetry,single-walled carbon nanotubes,photoluminescence,polymer encapsulation
更新于2025-09-12 10:27:22
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Oxidising and carburising catalyst conditioning for the controlled growth and transfer of large crystal monolayer hexagonal boron nitride
摘要： Hexagonal boron nitride (h-BN) is well-established as a requisite support, encapsulant and barrier for 2D material technologies, but also recently as an active material for applications ranging from hyperbolic metasurfaces to room temperature single-photon sources. Cost-effective, scalable and high quality growth techniques for h-BN layers are critically required. We utilise widely-available iron foils for the catalytic chemical vapour deposition (CVD) of h-BN and report on the significant role of bulk dissolved species in h-BN CVD, and specifically, the balance between dissolved oxygen and carbon. A simple pre-growth conditioning step of the iron foils enables us to tailor an error-tolerant scalable CVD process to give exceptionally large h-BN monolayer domains. We also develop a facile method for the improved transfer of as-grown h-BN away from the iron surface by means of the controlled humidity oxidation and subsequent rapid etching of a thin interfacial iron oxide; thus, avoiding the impurities from the bulk of the foil. We demonstrate wafer-scale (2”) production and utilise this h-BN as a protective layer for graphene towards integrated (opto-)electronic device fabrication.
关键词： monolayer,hexagonal boron nitride,transfer,2D materials,large crystal,chemical vapor deposition,encapsulation
更新于2025-09-12 10:27:22
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Selective Laser Melting Titanium with nanonet topography inhibits osteoclast differentiation through MAPK signaling pathway
摘要： Penetrating into the inner surface of porous metal-oxide nanostructures to encapsulate the conductive layer is an efficient but challenging route to exploit high-performance lithium-ion battery electrodes. Furthermore, if the bonding force on the interface between the core and shell was enhanced, the structure and cyclic performance of the electrodes will be greatly improved. Here, vertically aligned interpenetrating encapsulation composite nanoframeworks were assembled from Cl?/SO3 2?-codoped poly(3,4-ethylenedioxythiophene) (PEDOT) that interpenetrated and coated on porous Fe2O3 nanoframeworks (PEDOT-IE-Fe2O3) via a one-step Fe3+-induced in situ growth strategy. Compared with conventional wrapped structures and methods, the special PEDOT-IE-Fe2O3 encapsulation structure has many advantages. First, the codoped PEDOT shell ensures a high conductive network in the composites (100.6 S cm?1) and provides interpenetrating fast ion/electron transport pathways on the inner and outer surface of a single composite unit. Additionally, the pores inside offer void space to buffer the volume expansion of the nanoscale frameworks in cycling processes. In particular, the formation of Fe?S bonds on the organic?inorganic interface (between PEDOT shell and Fe2O3 core) enhances the structural stability and further extends the cell cycle life. The PEDOT-IE-Fe2O3 was applied as lithium-ion battery anodes, which exhibit excellent lithium storage capability and cycling stability. The capacity was as high as 1096 mA h g?1 at 0.05 A g?1, excellent rate capability, and a long and stable cycle process with a capacity retention of 89% (791 mA h g?1) after 1000 cycles (2 A g?1). We demonstrate a novel interpenetrating encapsulation structure to highly enhance the electrochemical performance of metal-oxide nanostructures, especially the cycling stability, and provide new insights for designing electrochemical energy storage materials.
关键词： porous Fe2O3,lithium-ion battery,PEDOT,organic?inorganic interface,interpenetrating encapsulation
更新于2025-09-11 14:15:04
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3.4: Applications of TFE mask‐less technology for foldable AMOLED displays
摘要： Thin-film encapsulation (TFE) for foldable AMOLED display is necessary to have good reliability and excellent bendability. TFE mask induces particles easily and crack occurs in thick TFE layer during panel bending. We developed TFE with Al2O3 layer for high water-proof and very thin thickness, satisfying the requirement of reliability and bendability. The Al2O3 layer in TFE structure was deposited by low temperature atomic layer deposition (ALD) method，and we realized TFE mask-less process through adapting dry-etch parameters for Al2O3 etch, finding that BCl3 has very excellent dry-etch selectivity between inorganic layer (SiOx/SiNx/SiOxNy) and Al2O3. Besides, we also attempted to make the organic layer of TFE acted as etch mask, and it proved to be feasible, indicating that all the TFE masks could be taken out effectively. Moreover, we proved good optic and reliability characteristics of AMOLED display with mask-less TFE structure.
关键词： Atomic Layer Deposition (ALD),mask-less,Thin-Film Encapsulation (TFE),AMOLED
更新于2025-09-11 14:15:04
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AIP Conference Proceedings [AIP Publishing 15th International Conference on Concentrator Photovoltaic Systems (CPV-15) - Fes, Morocco (25–27 March 2019)] 15th International Conference on Concentrator Photovoltaic Systems (CPV-15) - Solid lipid nanoparticles made of self-emulsifying lipids for efficient encapsulation of hydrophilic substances
摘要： In the last decades, most attention has been paid to solid lipid nanoparticles (SLN) as nanocarriers for pharmaceutical purposes due to their low toxicity, possible production on large scale and delivery of active principles by several administration routes. For example, lung delivery will necessitate direct administration, e.g. by aerosolisation, to maximize deposition into the airways and minimize systemic side effects. However, SLN based on common solid lipids preferentially incorporate lipophilic drugs, while the hydrophilic ones are loaded in low amount. To overcome this drawback, it seemed interesting to evaluate SLN based on self-emulsifying (SE) lipids, which are mixtures of lipids, surfactant and cosurfactants able to form emulsions in contact with aqueous media. Thus, we evaluated the preparation of SLN based on Gelucire? 50/13, selected as a SE lipid model, encapsulating glutathione (GSH) or proanthocyanidins occurring in grape seed extract (GSE), as hydrophilic model substances according to the melt-emulsification method. The encapsulation efficiency of such GSH- or GSE-SLN resulted satisfactory for both the hydrophilic compounds examined. However, to draw definitive conclusions on the scope and limitations of this approach based on SE lipids, further studies are necessary. Moreover, GSH-SLN were investigated for their performance in delivering the antioxidant peptide to immunocompetent fish cells, while GSE-SLN were evaluated for their possible application in the treatment of pulmonary diseases. It was found that GSH-SLN were not internalized by fish cells, while GSE-SLN showed favorable properties for lung delivery.
关键词： lung delivery,proanthocyanidins,solid lipid nanoparticles,self-emulsifying lipids,hydrophilic substances,encapsulation,glutathione
更新于2025-09-11 14:15:04
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32.2: Multifunctional electrohydrodynamic printing and its industrial applications in flat panel display manufacturing
摘要： Inkjet printing has become a robust, effective and powerful technique for display manufacturing due to its compatibility with large-area substrates, and cost effectiveness. However, conventional thermal or piezoelectric actuation falls short to fabricate the high-resolution components, and is inapplicable to highly viscous materials. Electrohydrodynamic (EHD) printing, which adopts electrical field force to pull the fluid flow from the Taylor cone at the nozzle, exhibits the ultra-high resolution (even to the nanoscale) and excellent compatibility with highly viscous inks. This paper has presented the promising applications of EHD printing in display manufacturing, e.g. micro dams for boundary definition, organic thin films for encapsulation, and micro lens array for light extraction. Dams with width/thickness of 1~20 μm/0.5~3 μm have been directly written on test element group border in a cost-effective and high-efficient manner, to replace traditional lithography and etching process in boundary definition. By adopting EHD printing to eject smaller droplets, the thickness of the organic layer in thin film encapsulation has been decreased to less than 6 μm, which is far beyond the current industrial level (8~12 μm), and making the device to be more flexible. Further, micro lens array with diameters ranging from 3 μm to 20 μm have been directly fabricated on the encapsulation layer of OLED, which make light outcoupling more effective.
关键词： electrohydrodynamic printing,micro lens,thin film encapsulation,dam
更新于2025-09-10 09:29:36