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A highly stretchable, transparent and conductive wood fabricated by in-situ photopolymerization with polymerizable deep eutectic solvents
摘要： The rational design of high-performance flexible transparent electrically conducting sensor attracts considerable attention. However, these designed devices predominantly utilize glass and plastic substrates, which are expensive and not environmentally friendly. Here, novel transparent and conductive woods (TCWs) were fabricated by using renewable wood substrate and low-cost conductive polymer. Polymerizable deep eutectic solvents (PDES), acrylic-acid (AA)/choline chloride (ChCl), were used as backfilling agents and in-situ photopolymerized in the delignified wood, which endowed the materials with high transparency (transmittance of 90 %), good stretchability (strain up to 80 %), and high electrical conductivity (0.16 S m-1). The retained cellulose orientation and strong interactions between cellulose-riched template and poly(PDES) render the TCWs excellent mechanical properties. Moreover, the TCWs exhibited excellent sensing behaviors to strain/ touch, even at low strain. Therefore, these materials can be used to detect weak pressure such as human being’s subtle bending-release activities. This work provides a new route to fabricate functional composite materials and devices which have promising potential for electronics applications in flexible displays, tactile skin sensors and other fields.
关键词： deep eutectic solvent,stretchable wood,porous,transparent wood,strain/touch sensor
更新于2025-11-21 11:18:25
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Controlled Fabrication of Flower-Shaped Aua??Cu Nanostructures Using a Deep Eutectic Solvent and Their Performance in Surface-Enhanced Raman Scattering-Based Molecular Sensing
摘要： Controlled synthesis of anisotropic bimetallic nanostructures with tunable morphology is of great current interest in surface-enhanced Raman scattering (SERS), plasmonics, and catalysis. Despite huge effort that has been devoted so far, fabrication of bimetallic nanostructures with controlled morphology and size remained to be a great challenge, especially when their shapes are anisotropic. Here, we report a facile, one-step synthetic approach for the fabrication of anisotropic bimetallic gold?copper nanostructures (Au?Cu NSs) of the 200?300 nm size range, using choline chloride/urea (ChCl/urea)-based deep eutectic solvent (DES) as the soft template. A concentration of the CuCl2 precursor in the reaction mixture was found to impact the reduction kinetics of the metal ions, directly affecting the final morphology of the Au?Cu nanostructures and elemental distributions in them. The fabricated anisotropic Au?Cu NSs revealed a high SERS signal for crystal violet (CV) molecules adsorbed at their surfaces, with the signal enhancement factor as high as 0.21 × 106 and capacity of detecting CV molecules of concentrations as low as 10?10 M in their aqueous solutions. The growth mechanism of the anisotropic bimetallic nanostructures in DES and their SERS performance has been discussed. The simple DES-assisted synthesis strategy presented in this work can be adopted for large-scale nonaqueous fabrication of other bimetallic nanostructures in a quite “greener” way.
关键词： deep eutectic solvent,plasmonics,catalysis,anisotropic bimetallic nanostructures,Au?Cu nanostructures,surface-enhanced Raman scattering
更新于2025-09-23 15:19:57
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Fabrication of Ag@AgCl with Enhanced Plasmonic Photocatalysis Performance via a Deep Eutectic Solvent
摘要： The plasmonic photocatalyst Ag@AgCl was successfully prepared through a facile solvothermal method via a deep eutectic solvent (DES), which is composed of choline chloride and urea. X-Ray diffraction, scanning electron microscopy, energy-dispersive X-ray, element-mapping, X-ray photoelectron spectroscopy, N2 absorption–desorption, and UV-vis diffuse reflectance techniques were adopted to analyse the performance of the plasmonic photocatalyst. Characterisation results indicated that the DES not only served as a solvent and Cl source, but also as a reductant. Meanwhile, the probable mechanism for the formation of Ag@AgCl is discussed, which revealed a visible light enhanced photocatalytic property for the degradation of benzidine. Furthermore, the photocatalyst showed no decrease in its catalytic activity even after five cycles of operation. Finally, a possible photocatalytic oxidation mechanism of Ag@AgCl is proposed.
关键词： solvothermal method,photocatalytic degradation,plasmonic photocatalyst,Ag@AgCl,deep eutectic solvent
更新于2025-09-04 15:30:14