- 标题
- 摘要
- 关键词
- 实验方案
- 产品
过滤筛选
- 2019
- charge – discharge energy efficiency
- Lithium-ion battery
- degradation diagnosis
- photovoltaic surplus energy
- working electric vehicle
- Electrical Engineering and Automation
- Ritsumeikan University
-
[IEEE 2019 IEEE 9th International Conference on Consumer Electronics (ICCE-Berlin) - Berlin, Germany (2019.9.8-2019.9.11)] 2019 IEEE 9th International Conference on Consumer Electronics (ICCE-Berlin) - Case Study of Photovoltaic Energy Surplus Absorption by Charging Lithium-Ion Batteries Considering Chargea??Discharge Energy Efficiency
摘要： In Autumn 2018, reductive control of photovoltaic surplus energy was performed in Kyushu, Japan. This was a lost opportunity to utilize renewable energy, which could have been otherwise stored in rechargeable batteries. In this study, we simulated the absorption of the photovoltaic energy surplus by charging battery systems of a working electric vehicle considering the energy efficiency of lithium-ion battery systems to reduce the operation cost. This study clarified the quantitative effects of a real-time energy efficiency diagnosis of lithium-ion battery systems. From the simulation results, we discovered that the improvements of the charge–discharge energy loss and the economic gain of the photovoltaic energy surplus absorption depended on the input–output power of the bidirectional vehicle- to-grid charger and the amount of surplus energy. When the input–output power is sufficiently high and the ratio of surplus energy to total capacity of the battery systems is sufficiently low, is the reasonable. The real-time degradation diagnosis of the battery systems and selection considering charge–discharge energy efficiency is necessary to improve the profit from surplus energy absorption.
关键词： charge – discharge energy efficiency,Lithium-ion battery,degradation diagnosis,photovoltaic surplus energy,working electric vehicle
更新于2025-09-23 15:21:01
-
Xenobiotic Contamination of Water by Plastics and Pesticides Revealed Through Real-time, Ultrasensitive and Reliable Surface Enhanced Raman Scattering
摘要： Uncontrolled utilization and consequent ubiquitous percolation of carcinogenic and xenobiotic contaminants, such as plasticizers and pesticides, into ecosystem has created an immediate demand for robust analytical detection techniques to identify their presence in water. Addressing this demand, we uncover the presence of xenobiotic contaminants such as Bisphenol A (BPA), Triclosan (TC), and Dimethoate (DM) through a robust, ultrasensitive and reliable Surface Enhanced Raman Scattering (SERS) platform. Thereby, conclusive real-time evidence of degradation of polyethylene terephthalate (PET) leading to release of BPA in water is presented. Worryingly, the release of BPA occurs at ambient temperature (40 0C) and within realistic timescales (12 hours) that are regularly encountered during the handling, transport and storage of PET-based water containers. Complementary mass-spectrometric, surface-specific atomic force microscopy and surface selective X-ray Photoelectron spectroscopy confirms the nanoscale surface degradation of PET through loss of C=O and C-O surface functionalities. Such ultra-sensitive (ppm-level), spectroscopic detection is enabled by the bottom-up assemblies of metal nanoparticles (Soret Colloids, SCs) acting as SERS platform to provide high analytical enhancement factor (108) with high reliability (relative standard deviation, RSD <5%). Effective and rapid detection (30 s) of several other potential xenobiotic contaminants such as Triclosan (TC) and Dimethoate (DM) over a wide range of concentrations (10-5 to 10-1 M) has also been demonstrated. Finally, non-destructive real-time spectroscopic “sniffing” of organophosphorous pesticides from the surface of fruits is achieved, illustrating the multi-phasic versatility of this label-free, non-lithography-based SERS platform.
关键词： plastic degradation,Soret colloids,water and food contamination,real-time detection,nanoparticle assembly,surface enhanced Raman scattering,Xenobiotics
更新于2025-09-23 15:21:01
-
[IEEE 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Chicago, IL, USA (2019.6.16-2019.6.21)] 2019 IEEE 46th Photovoltaic Specialists Conference (PVSC) - Thermo-mechanical degradation at finger-solder interface in a crystalline silicon photovoltaic module under thermal fatigue conditions
摘要： The thermo-mechanical performance of fingers in a crystalline silicon photovoltaic (PV) cell is often discussed in the domain of solder layer degradation due to their close proximity, and vulnerability under transient temperature variations. This paper discusses thermo-mechanical damage at common interfaces of the solder layer. It was established that the finger-solder interface is most prone to breakages. Further, effect of variable solder geometrical parameters on damage accumulation at the finger-solder interface was investigated. Solder thickness was found to be a crucial parameter. The variable width simulation demonstrated increased damage accumulation due to the case of over-soldering.
关键词： fingers,photovoltaic modules,solder,thermal cycling,thermo-mechanical degradation
更新于2025-09-23 15:21:01
-
One-step synthesis and deposition of ZnFe2O4 related composite films via SPPS route for photodegradation application
摘要： Binary spinel-type metal oxides (AB2O4) related materials, including ferrites (AFe2O4), are attractive photocatalysts thanks to their excellent visible light response for the photodegradation of organic pollutants. Currently, these materials are synthesized via conventional chemical routes suffering from long preparation duration and multistep. Solution Precursor Plasma Spray (SPPS) process is a single-step method for depositing photocatalytically active zinc ferrite-based films within several minutes. The influence of the precursor ratio on the microstructures and phase compositions of the ZnFe2O4 films was investigated by XRD and Raman analyses. In addition, two optimized ZnFe2O4 films were prepared by increasing the ZnO loading and tailoring injection pattern of the precursor solution. The surface morphologies and optical bandgap were also determined by SEM and UV-visible spectroscopy. The photocatalytic activities of the ZnFe2O4 films were evaluated through the degradation of the Orange II dye and of tetracycline hydrochloride under UV or visible light irradiation. The results show that compositional ratios and composition distribution of the ZnFe2O4 films prepared via SPPS played a key role on the photocatalytic activity. The SPPS route was demonstrated to be a promising method for the synthesis and the deposition of metal oxide (i.e. perovskite type and spinel type) films within a single-step for functional applications.
关键词： Solution Precursor Plasma Spray,Photocatalytic degradation,zinc ferrite,composite films
更新于2025-09-23 15:21:01
-
Effect of Interfacial Layers on the Device Lifetime of Perovskite Solar Cells
摘要： Organic–inorganic hybrid perovskites have excellent optical and electronic properties; exploitation of these traits has increased the power conversion efficiency of perovskite photovoltaics (PePVs) to 25.2%. However, perovskites are chemically unstable, and this deficit has critically impeded their commercialization. Device degradation occurs at the interfaces of PePVs with multiple degradation mechanisms: decomposition of organic cations in perovskites; generation of inorganic byproducts in perovskites; superoxide or trap sites at the interface of the charge-transport layer; excess charge carriers in perovskites; interfacial migration between perovskites and electrodes. This review considers the critical functions of the interfacial materials to overcome the various degradation at the interfaces of the PePVs. The working mechanisms stabilizing the interface of PePVs are categorized: passivation from atmosphere; inactivation of defect states; migration-blocking. Then, the outstanding interfacial layers made of organic materials (defect passivation, physical robustness, and chemical inactivation) and inorganic materials (chemically passivating metal oxide, physically passivating metal oxide, and low-temperature processed inorganic materials) are reviewed according to the stabilizing mechanisms. In addition, the influences of inorganic interconnecting layers in tandem PePVs are reviewed, with respect of various effects of interfacial buffer materials at the interface with perovskites.
关键词： device lifetime,interfacial layers,perovskite solar cells,stability,degradation mechanisms
更新于2025-09-23 15:21:01
-
Decoupling Contributions of Chargea??Transport Interlayers to Lighta??Induced Degradation of pa??ia??n Perovskite Solar Cells
摘要： Perovskite solar cells (PSCs) have demonstrated impressive performance, while their operation stability still requires substantial improvements before this technology can be successfully commercialized. There is a growing evidence that stability of PSCs is strongly dependent on the interface chemistry between the absorber films and adjacent charge transport layers, while the exact mechanistic pathways remain poorly understood. Here we present a systematic approach for decoupling the degradation effects induced by the top electron transport layer (ETL) of the fullerene derivative PC61BM and various bottom hole-transport layer (HTL) materials assembled in p-i-n perovskite solar cells configurations. We show that chemical interaction of MAPbI3 absorber with PC61BM most aggressively affects the operation stability of solar cells. However, washing away the degraded fullerene derivative and depositing fresh ETL leads to restoration of the initial photovoltaic performance when bottom perovskite/HTL interface is not degraded. Following this approach and refreshing ETL after light soaking of the samples and before completing the solar cell architectures, we were able to compare the photostability of stacks with various HTLs. It has been shown that PEDOT:PSS and NiOx induce significant degradation of the adjacent perovskite layer under light exposure, while PTAA provides the most stable perovskite/HTL interface. ToF-SIMS analysis of fresh and aged samples allowed us to identify chemical origins of the interactions between MAPbI3 and HTLs. The proposed research methodology and the revealed degradation pathways should facilitate future development of efficient and stable perovskite solar cells.
关键词： hole transporting materials,perovskite solar cells,TOF-SIMS,stability,interfacial degradation
更新于2025-09-23 15:21:01
-
Understanding degradation of organic light-emitting diodes from magnetic field effects
摘要： The impact of magnetic field effects on the electroluminescence of organic light-emitting diodes is commonly used to characterize exciton dynamics such as generation, annihilation, and performance degradation. However, interpreting these effects is challenging. Here, we show that magnetic field effects in organic light-emitting diodes can be understood in terms of the magnetic response of device characteristics derived from polaron-pair and triplet exciton quenching processes, such as triplet-polaron interactions and triplet-triplet annihilation. Device degradation shows a clear relationship with the amplitude of the magnetic field effects, enabling non-destructive measurement of the degradation. The results and proposed mechanism provide a better understanding of magnetic field effects on organic light-emitting diodes and device degradation phenomena.
关键词： magnetic field effects,device degradation,organic light-emitting diodes,triplet-polaron interactions,triplet-triplet annihilation,exciton dynamics
更新于2025-09-23 15:21:01
-
Preparation and Characterization of CeO2-C60 Nanocomposites and Their Application to Photocatalytic Degradation of Organic Dyes
摘要： Cerium oxide nanoparticles were prepared by the reaction of cerium nitrate hexahydrate and sodium hydroxide. Cetyltrimethyl ammonium bromide (C19H42NBr) was added as a templating agent. The yellow precipitate obtained by the reaction was calcined with fullerene (C60) for 2 h at 700 °C in an electric furnace to synthesize CeO2-C60 nanocomposites. The synthesized samples were characterized by X-ray diffraction, scanning electron microscopy. The photocatalytic activity of the CeO2-C60 nanocomposites for the degradation of organic dyes such as methylene blue, brilliant green, rhodamine B and methyl orange upon irradiation with 254 nm UV light was investigated using a UV-visible spectrophotometer.
关键词： Organic dyes,Photocatalytic activity,Degradation,CeO2-C60 nanocomposites,UV irradiation
更新于2025-09-23 15:21:01
-
Enhanced degradation efficiency of mixed industrial effluent by modified nanocomposite photocatalyst under UVLED irradiation
摘要： The aim of this study is to investigate the enhancement of photocatalytic degradation capacity of mixed industrial effluent using a modified activated charcoal/TiO2 nanocomposite catalyst. These nanocomposite catalysts are synthesized by the sol–gel method. The synthesized nanocomposite materials were characterized to confirmed material morphology and size by DLS, FTIR, crystallographic phase analysis (XRD), SEM, UV–Vis spectra, TGA and BET. This modified AC/TiO2 nanocatalyst removal efficiency is evaluated by photocatalytic degradation of mixed industrial effluent under UVLED light irradiation in different time intervals. The results demonstrate that the COD and BOD show 97% and 94% removal, respectively, at 90 min after that the degradation value becomes constant. Photocatalytic degradation of industrial effluent using AC/TiO2 followed pseudo-first-order reaction kinetics, and reaction rate constant was 1.04 × 10?2. Therefore, the performed experiment concludes that removal efficiency enhances to increase reaction time under UVLED irradiation.
关键词： UVLED irradiation,Photocatalytic degradation,Activated charcoal/TiO2 nanocomposite,Mixed industrial effluent
更新于2025-09-23 15:21:01
-
Degradation of InGaN-based LEDs: Demonstration of a recombination-dependent defect-generation process
摘要： This paper provides insights into the degradation of InGaN-based LEDs by presenting a comprehensive analysis carried out on devices having two quantum wells (QWs) with different emission wavelengths (495 nm and 405 nm). Two different configurations are considered: one with the 495 nm QW closer to the p-side and one with the 495 nm QW closer to the n-side. The original results collected within this work indicate that (i) during stress, the devices show an increase in defect-related leakage both in reverse and low-forward voltage ranges: current increases with the square-root of stress time, indicating the presence of a diffusion process; (ii) stress induces a decrease in the luminescence signal emitted by both quantum wells: the drop in luminescence is stronger when measurements are carried out at low current levels, indicating that degradation is due to the generation of Shockley–Read–Hall recombination centers; (iii) remarkably, the degradation rate is linearly dependent on the luminescence signal emitted before stress by the well, indicating that carrier density impacts on degradation; and (iv) the optical degradation rate has a linear dependence on the stress current density. The results strongly suggest the existence of a recombination-driven degradation process: the possible role of Shockley–Read–Hall and Auger recombination is discussed. The properties of the defects involved in the degradation process are described through steady-state photocapacitance measurements.
关键词： quantum wells,Shockley–Read–Hall recombination,Auger recombination,degradation,steady-state photocapacitance,InGaN-based LEDs
更新于2025-09-23 15:21:01