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Analysis of the optical band positions for manganese (IV) ions in trigonal barium titanium hexafluoride and barium silicon hexafluoride crystals
摘要： The optical band positions (or crystal field energy levels) of manganese (IV) ions in trigonal barium titanium hexafluoride and barium silicon hexafluoride crystals are computed from the full diagonalization (of energy matrix) method founded on the two-spin–orbit-parameter model which consists of the effects from both the spin–orbit parameters of dn ion and ligand ions. The computed results are in rational agreement with the experimental values. It is found that the large difference of first excited state splitting DE (2E) between the manganese (IV)-doped barium titanium hexafluoride and barium silicon hexafluoride crystals is owing mainly to the great difference of trigonal distortion between the fluorine octahedral clusters in the two host crystals.
关键词： barium titanium (silicon) hexafluoride [BaMF6 (M ? Ti; Si)],manganese (IV),diagonalization method,crystal- and ligand-field theory,optical spectra
更新于2025-09-23 15:21:01
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Luminescent manganese(II) complexes: Synthesis, properties and optoelectronic applications
摘要： Luminescent manganese(II) complexes have been extensively studied owing to their excellent photophysical properties. The facile synthesis and tunable optoelectronic performance of manganese(II) complexes render them attractive candidates for developing low-cost organic light-emitting diodes, information storage and security, as well as opto-electronic switches. In this review, we focus on the material category and synthesis, luminescence process, and various luminescent properties of manganese(II) complexes, together with their applications in functional devices. Finally, the challenge and outlook on the future research for manganese(II) complexes are given.
关键词： Triboluminescence,Photoluminescence,Manganese(II) complexes,Electroluminescence,Optoelectronic devices
更新于2025-09-23 15:19:57
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Polydopamine Coated PB-MnO <sub/>2</sub> Nanoparticles as an Oxygen Generator Nanosystem for Imaging-Guided Single-NIR-Laser Triggered Synergistic Photodynamic/Photothermal Therapy
摘要： Exploring a combined phototherapeutic strategy to overcome the limitations of a single mode therapy and inducing high anticancer efficiency is highly promising for precision cancer nanomedicine. However, a single-wavelength laser activates dual photothermal/photodynamic therapy (PTT/PDT) treatment is still a formidable challenge. Herein, we strategically design and fabricate a multifunctional theranostic nanosystem based on chlorin e6-functionalized polydopamine (PDA) coated prussian blue/manganese dioxide nanoparticles (PB-MnO2@PDA-Ce6 NPs). the obtained PB-MnO2@PDA NPs not only offer an effective delivery system for Ce6 but also provide strong optical absorption in the near-infrared range, endowing high antitumor efficacy of PTT. More importantly, the as-prepared PB-MnO2@PDA-Ce6 nanoagents exhibit an effective oxygen generation, superior reactive oxygen species (ROS), and outstanding photothermal conversion ability to greatly improve PTT and PDT treatments. As a result, both in vitro and in vivo treatments guided by MR imaging on liver cancer cells reveal the complete cell/tumor eradication under a single wavelength of 660 nm laser irradiation, implying the simultaneous synergistic PDT/PTT effects triggered by PB-MnO2@PDA-Ce6 nanoplatform, which are much higher than individual treatment. Taken together, our phototherapeutic nanoagents exhibit an excellent therapeutic performance, which may act as a nanoplatform to find safe and clinically translatable routes to accelerate cancer therapeutics.
关键词： photodynamic therapy,nanomedicine,prussian blue,photothermal therapy,MRI,cancer therapy,polydopamine,chlorin e6,manganese dioxide
更新于2025-09-23 15:19:57
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A Microfluidic Biosensor Based on Magnetic Nanoparticle Separation, Quantum Dots Labeling and MnO2 Nanoflower Amplification for Rapid and Sensitive Detection of Salmonella Typhimurium
摘要： Screening of foodborne pathogens is an effective way to prevent microbial food poisoning. A microfluidic biosensor was developed for rapid and sensitive detection of Salmonella Typhimurium using quantum dots (QDs) as fluorescent probes for sensor readout and manganese dioxide nanoflowers (MnO2 NFs) and as QDs nanocarriers for signal amplification. Prior to testing, amino‐modified MnO2 nanoflowers (MnO2‐NH2 NFs) were conjugated with carboxyl‐modified QDs through EDC/NHSS method to form MnO2‐QD NFs, and MnO2‐QD NFs were functionalized with polyclonal antibodies (pAbs) to form MnO2‐QD‐pAb NFs. First, the mixture of target Salmonella Typhimurium cells and magnetic nanoparticles (MNPs) modified with monoclonal antibodies (mAbs) was injected with MnO2‐QD‐pAb NFs into a microfluidic chip to form MNP‐bacteria‐QD‐MnO2 complexes. Then, glutathione (GSH) was injected to dissolve MnO2 on the complexes into Mn2+, resulting in the release of QDs. Finally, fluorescent intensity of the released QDs was measured using the fluorescent detector to determine the amount of Salmonella. A linear relationship between fluorescent intensity and bacterial concentration from 1.0 × 102 to 1.0 × 107 CFU/mL was found with a low detection limit of 43 CFU/mL and mean recovery of 99.7% for Salmonella in spiked chicken meats, indicating the feasibility of this biosensor for practical applications.
关键词： quantum dots,manganese dioxide nanoflowers,Salmonella Typhimurium,Microfluidic biosensor,magnetic nanoparticles
更新于2025-09-23 15:19:57
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Raman spectroscopy and laser-induced degradation of groutellite and ramsdellite, two cathode materials of technological interest
摘要： Manganese oxides are important geomaterials, used in a large number of applications. For instance, as pigments in art works or in the treatment and removal of heavy metals from drinking water. Particularly, ramsdellite [Mn4+O2] and groutellite [(Mn0.54+,Mn0.53+)O1.5(OH)0.5], because of their 2 × 1 frameworks that enable proton diffusion, are very important cathode materials. Manganese oxides commonly occur as crypto-crystalline and very fine mixtures of different Mn-phases, iron oxides, silicates and carbonates. Thus, proper characterization can be a difficult task using XRPD. The lack of Raman data on groutellite and the little and conflicting data on ramsdellite do not allow their proper identification by Raman spectroscopy. In this work we characterize natural mixtures of ramsdellite and groutellite by combining SEM-EDS, XRPD, FT-IR and Raman spectroscopy, to provide reference Raman spectra. Our data show that they have a typical and unmistakable spectra, allowing clear recognition. Moreover, we have investigated their laser-induced degradation. Our data show that groutellite transforms into ramsdellite, by the loss of H+ and the oxidation of Mn3+ to Mn4+, already at a very low laser power. Further increasing the laser power the formation of hausmannite [Mn2+Mn23+O4] occurs via the reduction of Mn cations. Our data can be used to study the discharge mechanism in cathodic battery materials, by monitoring the Mn reduction from ramsdellite to groutellite, and finally to groutite [α-Mn3+OOH]. Moreover, Raman mapping allows the study of their distribution in all the investigated samples and, indirectly, those of H+ and Mn3+, which plays a key-role in electrochemical activity of these compounds.
关键词： Raman spectroscopy,Manganese oxides,cathode materials,ramsdellite,laser-induced degradation,groutellite
更新于2025-09-19 17:13:59
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Facile synthesis, structure analysis and optical performance of manganese oxide-doped PVA nanocomposite for optoelectronic and optical cut-off laser devices
摘要： In the present work, successful manganese oxide (Mn2O3) nanoparticles (NPs) were synthesized by a combustion technique, while the casting process was employed for the manufacturing of polymer nanocomposites with various weights of Mn2O3 based on Poly(Vinyl Alcohol), PVA. Multiple methods such as X-ray diffraction (XRD), HR-TEM, EDAX, EDS, SEM, FT-IR, DTA analysis, optical spectroscopy from UV to IR regions, and optical reduction (CUT-OFF) setup were used to characterize the structural, elemental chemical analysis, morphological, optical properties, and cut-off laser characteristic of nanocomposite samples. Mn2O3 nanoparticles have a crystallite size of 22.08 nm as calculated using the Debye–Scherer formula from XRD, while the HR-TEM shows a spherical particle of size 30–38 nm range. EDAX spectra and EDS mapping were used to detect the elemental particles of the nanocomposite. The external morphology of the films by SEM images shows an increase in the agglomeration size of the cluster with the percentage of Mn2O3 nanoparticles in PVA. FT-IR spectra show excellent incorporation between the matrix of polymer and the Mn2O3 via the hydroxyl group. Moreover, with increasing the doping rate of nanoparticles, the thermal stability of PVA increased. A significant change of optical transmittance, absorption edge, Urbach energy, and transition bandgap have been observed due to the influence of Mn2O3. The comparison between the bandgap values that have been estimated from Tauc’s relation and thus resulting from optical dielectric loss indicates a direct allowed transition of electrons in the nanocomposites. The light is entirely UV–Vis absorbed by PVA with a high percentage of Mn2O3 nanoparticles. Moreover, the efficiency of the films to decrease the power of two laser beams (635 nm and 533 nm) has been observed. The flexible films of PVA with an elevated rate of Mn2O3 are considered a successful option for low-cost technologies of optical limiting.
关键词： Casting process,Combustion technique,PVA nanocomposite,Optoelectronic,Manganese oxide,Optical cut-off laser devices
更新于2025-09-19 17:13:59
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Cobalt/Manganese Oxides as Theragnosis Nanoplatforms With Magnetic Resonance/Near-Infrared Imaging for Efficient Photothermal Therapy of Tumors
摘要： The combination of near-infrared (NIR) response and imaging response is a hot research area in which the functions of nanomaterials are maximized. However, the types of such materials reported so far present problems such as requiring complex synthesis. In this study, hydrophilic, porous, and hollow cobalt/manganese oxide (CMO) nanocrystals (NCs) were successfully prepared via a facile and green hydrothermal route. The CMO NCs show strong near-infrared (NIR) absorption, which results from their defect structure due to the coexistence of Co2+ and Co3+ in the as-prepared CMO NCs. Thus, the CMO NCs exhibit excellent photothermal performance, showing photothermal efficiency of up to 43.2%. In addition, the CMO NCs possess good magnetic resonance (MR) imaging performance, with longitudinal relaxivity (r1) of up to 3.48 mM?1 s?1. Finally, for the first time, we prove that the CMO nanocrystals are a promising photothermal agent. Our work provides insights into the application of Mn-based control agents and photothermal agents for photothermal theragnosis therapy.
关键词： cobalt/manganese oxides,photothermal agents,magnetic resonance imaging,photothermal theragnosis therapy,near-infrared absorption
更新于2025-09-16 10:30:52
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Aloe vera-peel derived porous carbon integrated Co/Mn-oxide based nano-hybrids: An efficient electrocatalyst in advanced photovoltaics
摘要： We propose a facile strategy to synthesize highly electrocatalytic active nanohybrids by the integration of aloe vera-peel derived porous carbon into manganese-based and cobalt/manganese-based oxides. These nanohybrids exhibit unique three-dimensional porous network structures and possess high surface areas, providing numerous catalytic sites and multiple rapid electron transfer channels. In this work, the as-synthesized nanohybrids are used as accelerants for tri-iodide reduction in dye-sensitized solar cells, resulting in attractive cell efficiency and superior electrochemical stability. The solar cell with low-cost bio-based carbon integrated cobalt/manganese-oxide counter electrode exhibits higher photovoltaic efficiency than that of platinum electrode (7.01% vs. 6.44%). In addition, hybrid catalyst loaded counter electrodes also demonstrate long-term electrochemical stability in I3?/I? electrolyte, retaining 97% of its initial efficiency (6.83%/7.01%) in working cell, after going through multiple cyclic voltammetry scans. The utilization of synergistic effects of high performance constituents and controlled morphology is a key strategy to intensify the catalytic activity, electrochemical stability, and power conversion efficiency in advanced photovoltaics.
关键词： Dye-sensitized solar cell,Bio-based porous carbon,Cobalt manganese oxide,Morphology transformation,Electrocatalytic accelerants
更新于2025-09-16 10:30:52
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Investigation on Surface Properties of Mn-Doped CdSe Quantum Dots Studied by X-ray Photoelectron Spectroscopy
摘要： In this work, we report on the effects of incorporating manganese (Mn) dopant into different sizes of cadmium selenide (CdSe) quantum dots (QDs), which improves the electronic and optical properties of the QDs for multiple applications such as light-emitting diodes, lasers, and biological labels. Furthermore, the greener inverse Micelle method was implemented using organic ligand, which is oleic acid. This binding of the surface enhanced the QDs’ surface trap passivation of Mn-doped CdSe, which then increased the quantity of the output. In addition, the inverse Micelle technique was used successfully to dope Mn into CdSe QDs without the risk of Mn dopants being self-purified as experienced by wurtzite CdSe QDs. Also, we report the X-ray photoelectron spectroscopy (XPS) results and analysis of zinc blended manganese-doped cadmium selenide quantum dots (Mn-doped CdSe QDs), which were synthesized with physical sizes that varied from 3 to 14 nm using the inverse Micelle method. The XPS scans traced the existence of the Se 3d and Cd 3d band of CdSe crystals with a 54.1 and 404.5 eV binding energy. The traced 640.7 eV XPS peak is proof that Mn was integrated into the lattice of CdSe QDs. The binding energy of the QDs was related to the increase in the size of the QDs.
关键词： quantum dots,semiconductor,chemical synthesis,cadmium selenide,X-ray photoelectron spectroscopy,manganese doped
更新于2025-09-16 10:30:52
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Colloidal Seconda??Neara??infrareda??emitting Mna??doped Ag2S Quantum Dots
摘要： Incorporation of transition metal dopants within a semiconductor nanocrystal has a tremendous effect on the optical and magnetic properties of the semiconductor nanocrystals. Herein, we showed the novel synthesis of second-near-infrared-emitting photoluminescent Mn2+-doped Ag2S quantum dots via co-pyrolysis of silver and manganese single source precursors. The Mn2+ doping level was flexibly tuned in Ag2S quantum dots, which was confirmed by elemental analysis and electron paramagnetic resonance spectroscopy. The Mn2+ doping induced negligible change in the pristine monoclinic acanthite Ag2S crystal structure but significantly decreased the photoluminescent intensity. Mn2+ doped Ag2S QDs exhibit the second-near-infrared-emission and ferromagnetic ordering, which show potential applicability for multimodal fluorescence/MRI probes.
关键词： Second Near-infrared,Manganese Dopant,Ferromagnetism,Quantum Dot,Silver Sulfide
更新于2025-09-16 10:30:52