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Color-center formation and thermal recovery in X-ray and electron-irradiated magnesium aluminate spinel
摘要: We have studied the formation of color centers in magnesium aluminate spinel (MgAl2O4) by X-ray and electron irradiations near room temperature (RT). For this purpose, Cu Kα radiation and three electron energies (1.0, 1.4, and 2.5 MeV) were used for variable fluences (up to 4.2 × 10^18 cm^?2). Off-line UV-visible absorption spectra were recorded at RT as well as at low temperature down to 27 K after electron irradiation. The dependence of the production rate of F centers (oxygen vacancies) on the electron energy yields a threshold displacement energy of 190 ± 10 eV for oxygen atoms at RT, which is much higher than the determinations by molecular-dynamics simulations. Such a discrepancy is discussed on the basis of available migration data of point defects in spinel. Equipartition of F0 and F+ centers, i.e., the neutral (VO^x) and singly ionized (VO^.) oxygen vacancies, is reached for high electron fluences. Moreover, the evolution of the width of color-center absorption bands versus temperature is interpreted with the classical theory for F centers (neutral halogen vacancies) in alkali halides. The Stokes shifts are deduced from the temperature dependence of the absorption bandwidths of color centers like for alkali halides and alkaline-earth oxides. Finally, isothermal annealing data for long annealing time show a non-zero asymptotic behavior for both F0 and F+ centers. This uncommon behavior is interpreted by charge exchange processes leading to an equilibrium state between those two color centers.
关键词: thermal recovery,X-ray irradiation,color centers,threshold displacement energy,F centers,electron irradiation,absorption spectroscopy,magnesium aluminate spinel
更新于2025-09-23 15:23:52
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Luminescent Electrochromic Devices for Smart Windows of Energy-Efficient Buildings
摘要: To address the challenges of the next generation of smart windows for energy-efficient buildings, new electrochromic devices (ECDs) are introduced. These include indium molybdenum oxide (IMO), a conducting oxide transparent in the near-infrared (NIR) region, and a NIR-emitting electrolyte. The novel electrolytes are based on a sol-gel-derived di-urethane cross-linked siloxane-based host structure, including short chains of poly (ε-caprolactone) (PCL(530) (where 530 represents the average molecular weight in g mol?1). This hybrid framework was doped with a combination of either, lithium triflate (LiTrif) and erbium triflate (ErTrif3), or LiTrif and bisaquatris (thenoyltri?uoroacetonate) erbium (III) ([Er(tta)3(H2O)2]). The ECD@LiTrif-[Er(tta)3(H2O)2] device presents a typical Er3+ NIR emission around 1550 nm. The ?gures of merit of these devices are high cycling stability, good reversibility, and unusually high coloration ef?ciency (CE = ?OD/?Q, where Q is the inserted/de-inserted charge density). CE values of ?8824/+6569 cm2 C?1 and ?8243/+5200 cm2 C?1 were achieved at 555 nm on the 400th cycle, for ECD@LiTrif-ErTrif3 and ECD@LiTrif-[Er(tta)3(H2O)2], respectively.
关键词: erbium β-diketonate complex,poly(ε-caprolatone)/siloxane hybrids,erbium triflate,lithium triflate,NIR-transparent IMO,sol–gel,zero-energy buildings,electrochromic devices
更新于2025-09-23 15:23:52
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Characterisation of Timepix3 with 3D sensor
摘要: Tests were performed at the SPS facilities at CERN using a 40 GeV/c pion beam with prototype 3D-Timepix3 detectors (3D detector). A planar-Timepix3 (planar detector) was placed along the beam axis together with the 3D detectors in a telescope arrangement for comparison and reference. We demonstrate that the combination of 3D-geometry silicon sensors and Timepix3 module can reduce the effect of charge sharing and lowers the carrier drift-time, while giving the same spectroscopy performance without sacrificing the timing or any performance advantages of the Timepix3 module.
关键词: Performance of High Energy Physics Detectors,databases),Detector control systems (detector and experiment monitoring and slow-control systems,hardware,algorithms,architecture
更新于2025-09-23 15:23:52
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Nanoporous Fe-doped BiVO4 Modified with MIL-53 (Fe) for Enhanced Photoelectrochemical Stability and Water Splitting Perfromances
摘要: Great interest has been attracted to enhancing the photoelectrochemical performances of BiVO4. However, there have rarely been reported about addressing their PEC stability. Herein, it is proposed that Fe ions doping could enhance the stability and PEC performances of BiVO4, which may because it could improve the crystalline structure and eliminates the crystal defects of BiVO4. Moreover, it is found that metal–organic framework can play a co-catalyst role during the PEC experiments. We designed and fabricated nanoporous Fe-doped BiVO4 modified with MIL-53(Fe), which exhibits much higher PEC performance and stability than pristine BiVO4 and Fe-doped BiVO4. It is believed that MIL-53(Fe) can capture the photogenerated holes and thus facilitates the charge separation efficiency.
关键词: BiVO4,MIL-53(Fe),Stability,Nanocomposites,Energy storage and conversion,Photoelectrochemical
更新于2025-09-23 15:23:52
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Dynamics of interatomic Coulombic decay in neon dimers by XUV-pump–XUV-probe spectroscopy
摘要: We apply the Monte Carlo wave-packet approach to study the interatomic Coulombic decay (ICD) dynamics of neon dimers after removing a 2s electron from one of the Ne atoms by one-photon absorption from an XUV pulse. This method reproduces well both the lifetime for the 2s inner-valence vacancy in Ne2+(2s?1) and the kinetic energy release (KER) spectra for the coincident Ne+ and Ne2+ fragments following triple ionization, i.e., two photoionizations and one ionization via ICD, of Ne2 measured in an XUV-pump–XUV-probe experiment [K. Schnorr et al., Phys. Rev. Lett. 111, 093402 (2013)]. Comparisons between the calculated and measured nuclear KER spectra give physical insights in the considered process. For example, an analysis of the ratios between the low- and high-energy peaks in the nuclear KER spectra for large delays provides an estimate of the photoionization cross sections for removing a 2p electron from the excited states in Ne2+(2s?1). Such comparisons also allow an estimate for the ICD rates for the 2s inner-valence vacancy in the single-site two-hole state in Ne2+(2s?12p?1). Finally, the influence of photon statistics of the free electron laser pulses on the nuclear KER spectra is considered.
关键词: neon dimers,interatomic Coulombic decay,kinetic energy release spectra,XUV-pump–XUV-probe spectroscopy,Monte Carlo wave-packet approach
更新于2025-09-23 15:23:52
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Parametric Study and Optimization of Linear and Nonlinear Vibration Absorbers Combined with Piezoelectric Energy Harvester
摘要: In this work, a harmonically excited generalized two degree of freedom non-linear system is used to manifest the functions of both the vibration absorber and energy harvester simultaneously. The generalized system has been reduced to a linear primary system with linear/nonlinear absorber and harvester or nonlinear primary system with linear/nonlinear absorber and harvester. Multi-harmonic balance method (MHBM) along with arc length continuation is used for generating frequency response plots for different absorber and energy harvester system parameters with constant primary system parameters and excitation amplitude. The frequency response plots show multiple branches of stable periodic solutions and jump at certain frequency ranges for systems with nonlinearity. The absorber and energy harvester parameters are optimized using an optimization procedure based on genetic algorithm in combination with response surface methodology. The method is validated with analytical solutions available in the literature for a linear primary system with linear absorber and harvester and nonlinear primary system with nonlinear absorber alone. This study demonstrates that the proposed optimization framework along with MHBM is suitable for generating the optimal frequency response for multifunctional energy harvesting systems or systems with nonlinear absorber. The frequency response plots with optimal parameter values reiterates the fact that the absorber system with nonlinear element perform better compared to its linear counterpart over a wider band of frequencies. The study also reports the comparison of the performance of a combined nonlinear absorber harvester system with that of a nonlinear energy sink (NES) absorber harvester system.
关键词: vibration absorber,multi-harmonic balancing,energy harvesting,optimization,response surface method,genetic algorithm
更新于2025-09-23 15:23:52
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[IEEE 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - Waterloo, ON (2018.8.19-2018.8.22)] 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - Excitation of Hyperbolic Plasmons and Transition Radiation in Phosphorene by a Swift Electron
摘要: We analyze the energy loss channels for a fast electron traversing a monolayer phosphorene under oblique incidence taking the retardation effects into account.
关键词: transition radiation,electron energy loss,retardation effects,Phosphorene,hyperbolic plasmon polariton
更新于2025-09-23 15:23:52
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[IEEE 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - Waterloo, ON (2018.8.19-2018.8.22)] 2018 18th International Symposium on Antenna Technology and Applied Electromagnetics (ANTEM) - Plasmon Excitation and Transition Radiation in Graphene Traversed by a Fast Charged Particle
摘要: A progress report is presented on recent theoretical investigations of the interaction of fast charged particles with single and multiple graphene layers. By adopting a fully relativistic formulation of the problem, special focus is placed on retardation effects in the energy loss of a charged particle due to electronic excitations in graphene, which include its plasmon polariton modes, as well as the energy that is emitted from graphene in the form of transition radiation. Using both empirical and ab initio models for the dynamic in-plane conductivity of graphene allows the exploration of energy losses at frequencies ranging from the terahertz to the ultraviolet.
关键词: transition radiation,electron energy loss,graphene,relativistic effects,plasmon polariton
更新于2025-09-23 15:23:52
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Practical performance of a small PTC solar heating system in winter
摘要: The active solar house-heating in winter is a novel technology that is eco-friendly and economical. The performance of a small solar heating system composed of parabolic trough collector (PTC) and ventilation pipelines has been experimentally investigated in the current study. With an automatic solar-tracking device, the system adopted a PTC device of aperture area 2.407 m2. The air stream was heated in the tube collector and then driven into the test room. By examining the heat gain of the air stream passing through the PTC as well as the temperature distribution of the indoor air, the working characteristic of the solar-heating system in winter was evaluated practically. The experimental results showed that for the generally-insulated room that was located in 39.87°N latitude, the daily solar heating time reached to 6–7 h, and the thermal efficiency of the PTC device was above 60%. Supposing the heat loss is reduced effectively along the outdoor pipelines in the future, such active solar heating system will be a promising heating technology in regions that are not far north on the earth.
关键词: Thermal efficiency,Solar energy,PTC,House heating
更新于2025-09-23 15:23:52
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Preferential Positioning, Stability, and Segregation of Dopants in Hexagonal Si Nanowires
摘要: We studied the physics of common p- and n-type dopants in hexagonal-diamond Si –a Si polymorph that can be synthesized in nanowire geometry without the need of extreme pressure conditions– by means of first-principles electronic structure calculations and compared our results with those for the well-known case of cubic-diamond nanowires. We showed that i) as observed in recent experiments, at larger diameters (beyond the quantum confinement regime) p-type dopants prefer the hexagonal-diamond phase with respect to the cubic one as a consequence of the stronger degree of three-fold coordination of the former, while n-type dopants are at a first approximation indifferent to the polytype of the host lattice; ii) in ultra-thin nanowires, because of the lower symmetry with respect to bulk systems and the greater freedom of structural relaxation, the order is reversed and both types of dopant slightly favor substitution at cubic lattice sites; iii) the difference in formation energies leads, particularly in thicker nanowires, to larger concentration differences in different polytypes, which can be relevant for cubic-hexagonal homojunctions; iv) ultra-small diameters exhibit, regardless of the crystal phase, a pronounced surface segregation tendency for p-type dopants. Overall these findings shed light on the role of crystal phase in the doping mechanism at the nanoscale and could have a great potential in view of the recent experimental works on group IV nanowires polytypes.
关键词: density functional theory,Nanowires,formation energy,dopants,2H-Si,hexagonal diamond silicon
更新于2025-09-23 15:23:52