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Hydrodynamic modeling and time-resolved imaging reflectometry of the ultrafast laser-induced ablation of a thin gold film
摘要： The ablation of thin metal films using ultrafast laser radiation represents a standard processing procedure in laser technology. However, looking closer to the resulting structures, the arising topology deviates strongly from the expected one. Ablation of thin gold films using ultrafast laser radiation with a Gaussian-shaped spatial intensity distribution results in flat topologies. By synergistically combining space and time-resolved reflectometry with expanded two-temperature hydrodynamic modeling, we explain the formation of bulging and rupture of the thin film-surface by the expansion of strongly stretched liquid material due to the induced rarefaction wave propagating towards the substrate. Also, the formation of a flat ablation structure is described by the interplay of two rarefaction waves, one propagating towards the substrate and the other one propagating towards the vacuum boundary, within the completely molten film. The simulated topology agrees excellent with the experimentally observed ablation structure. Besides, all simulated stages of excitation of the gold film, namely electron-phonon non-equilibrium, hydrodynamic expansion, and rupture, are confirmed by space and time-resolved pump-probe reflectometry.
关键词： Imaging reflectometry,Thin film ablation,Femtosecond laser radiation,Two temperature model hydrodynamics (TTMHD),Gold thin film,Ultrafast metrology
更新于2025-09-16 10:30:52
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Enhancing the sensitivity of a surface plasmon resonance-based optical sensor for zinc ion detection by the modification of a gold thin film
摘要： Surface plasmon resonance (SPR) sensors as novel optical sensors for the detection of a variety of analytes have been receiving increasing attention and their sensitivity has become the research hotspot recently. In this study, the sensitivity of an SPR optical sensor was enhanced by modifying a gold thin film with a nanocrystalline cellulose (NCC)-based material for zinc ion (Zn2+) detection that exists in the environment due to industrial processing. By replacing the gold thin film with a novel modified-gold thin film, Zn2+ can be detected from the range of 0 to 10 ppm using SPR. It is believed that the Zn2+ may interact with the negative charge molecules that exist on the modified-gold thin film, and this was confirmed via X-ray photoelectron spectroscopy (XPS). Moreover, this modified-gold-SPR has a high sensitivity of 1.892° ppm?1 up to 0.1 ppm with an enhanced detection of Zn2+ as low as 0.01 ppm. The SPR results also followed the Langmuir isotherm model with a binding affinity of 1.927 × 103 M?1, which further confirmed the sensitivity of the SPR sensor. In addition, using the modified-gold thin film, SPR has a higher affinity towards Zn2+ compared to other metal ions, i.e. Ni2+, Fe2+, Cr2+, Mn2+, and Co2+.
关键词： optical sensor,Surface plasmon resonance,nanocrystalline cellulose,gold thin film,zinc ion detection
更新于2025-09-16 10:30:52