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CH3NH3PbBr3 Nanocrystals Formed in situ in Polystyrene Used for Increasing the Color Rendering Index of White Leds
摘要: A new method is proposed for the formation of MAPbBr3 nanoparticles in situ in a dispersion of polystyrene in toluene in the absence (MAPbBr3@PS) and presence of a broad-band luminophor (MAPbBr3/GAG:Ce@PS). This method permits the lossless use of perovskite, a uniform distribution of the luminophor nanoparticles in the polymer matrix, and maintenance of a high photoluminescence quantum yield (~46%). The samples derived from MAPbBr3 have green photoluminescence with a maximum showing a blue shift in going from bulk perovskite powder to films due to a size effect. The use of nanocomposite films MAPbBr3/GAG:Ce@PS in white LEDs permits enhancement of the color rendering index to 92 with correlation color temperature >5800 K.
关键词: nanocomposite films,quantum yield,photoluminescence,hybrid halide perovskite
更新于2025-09-11 14:15:04
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Dimensionality engineering of hybrid halide perovskite light absorbers
摘要: Hybrid halide perovskite solar cells were first demonstrated in 2009 with cell efficiency quickly soaring from below 10% to more than 23% in a few years. Halide perovskites have the desirable processing simplicity but are very fragile when exposed to water and heat. This fragility represents a great challenge for the achievement of their full practical potential in photovoltaic technologies. To address this problem, here we review the recent development of the mixed-dimensional perovskites, whereby the trade-off between power conversion efficiency and stability of the material can be finely tuned using organic amine cations with different sizes and functionalities.
关键词: hybrid halide perovskite,organic amine cations,stability,mixed-dimensional perovskites,solar cells,power conversion efficiency
更新于2025-09-09 09:28:46