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Thermophysical Properties of Silicon-Carbide-Based Ceramic Composite Materials Obtained by Spark Plasma Sintering (SPS)
摘要： The factors influencing the thermal conductivity of SiC-based ceramic composite materials obtained by the spark plasma sintering technology with relative density 99% and B4C, AlN, Si3N4, Y2O3, Al2O3, and HfB2 as additives are examined. The thermophysical properties were determined in the temperature range 20 – 1300°C: specific heat, thermal diffusivity, and thermal conductivity of composites. The thermal diffusivity and specific heat were measured by the laser-spark method. The measurements of specific heat are supplemented by measurements performed with a DSC and adiabatic calorimeter. The thermal conductivity is calculated using data on the thermal diffusivity, specific heat, and density.
关键词： laser flash method,specific heat,adiabatic calorimeter,thermal conductivity,ceramic composite materials,thermal diffusivity,thermophysical properties,differential scanning calorimetry (DSC)
更新于2025-09-19 17:15:36
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Improving Thermal Diffusivity Measurements by Including Detector Inherent Delayed Response in Laser Flash Method
摘要： Laser flash experiments are a widely used to determine thermal diffusivity of matter. Especially for thin samples or high diffusive materials, the laser pulse-time delay and its shape may become crucial for precise measurements (“finite pulse-time effect”). An additional delayed response and modification of the shape of the signal can be caused by time delays of detectors and electronic components (e.g., electronic filters) and may be inherent to Laser Flash Apparatuses (LFA). Similar to the correction of the finite pulse-time effect, this detector system inherent delayed response needs to be taken into account, especially for thin or high diffusive materials. To correct for this additional delay, detector signals of direct laser pulses were measured and for correction of this systematic errors a transfer function is derived. It reproduces the detector signal using the pulse shape measured by a diode within the apparatus and thus takes into account the actual laser pulse shape and detector behavior. For the used experimental setup, systematic errors caused by this effect are in the same range than the often considered finite pulse-time effect. As the detector related time delay is system inherent, the developed transfer function can be used to effectively eliminate both, the finite pulse-time delay and the detector inherent delayed response. Besides experimental determinations, synthetic temperature response data are used to quantify the systematic errors related to the additional detector inherent retardation for various thermal diffusivities and sample thicknesses. By not taking the additional delay into account systematic errors > 10 % may arise for both, high and low temperature detectors, indium antimonide (InSb) and MCT (HgCdTe), respectively.
关键词： Uncertainty,Thermal diffusivity,Finite pulse-time effect,Laser flash method
更新于2025-09-19 17:13:59