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Temperature independent low firing [Ca0.25(Nd1-xBix)0.5]MoO4 (0.2 ≤ x ≤ 0.8) microwave dielectric ceramics
摘要： A scheelite structured [Ca0.25(Nd1-xBix)0.5]MoO4 (0.2 (cid:1) x (cid:1) 0.8) ceramics were prepared via solid state reaction method. All the ceramics can be well densi?ed below 780 (cid:3)C. As x value increased from 0.2 to 0.8, microwave dielectric permittivity increased from 14.0 to 27.8, Qf (Q ? quality factor ? 1/dielectric loss; f ? resonant frequency) value decreased from 42,000 GHz to 19,000 GHz, and TCF shifted from (cid:4)50 ppm/oC to t18 ppm/oC. The best microwave dielectric properties with permittivity between 23.54 and 23.56, Qf value between 24,000 GHze21,000 GHz and TCF value ~ (cid:4)8 ppm/oC in wide temperature range 25 (cid:3)Ce130 (cid:3)C were obtained in x ? 0.6 ceramic. This work showed that Bi played an important role to modify the TCF from negative to positive value in scheelite materials and this result further accelerate the application of scheelite materials in low temperature co-?red ceramics (LTCC) technology.
关键词： Microwave dielectric properties,Low temperature sintering,MoO3,Scheelite
更新于2025-09-23 15:23:52
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Structure stability, bond characteristics and microwave dielectric properties of co-substituted NdNbO4 ceramics
摘要： Structure-property relationship of co-substituted (Mg2+1/4Mo6+3/4)5+, (Al3+1/3Mo6+2/3)5+, (Si4+1/2Mo6+1/2)5+, (Zr4+1/2Mo6+1/2)5+ for Nb5+ in NdNbO4 ceramics was investigated systematically. The remarkable differences in dielectric properties of each composition originated from their bond characteristics and structure stability. The elongated/compressed bonds have an effect on the cell volume and polarization. And the average bond covalency of Nb-O bond was responsible for the development of permittivity. Q×f values and the total lattice energy went up to maximum when (Si0.5Mo0.5) occupied Nb-site. Variations of lattice energy together with Nb-O bond energy suggest that a more stable structure was obtained through co-substitution. The optimal microwave dielectric properties is: εr=18.97, Q×f=49466GHz, τf=7.34 ppm/℃ for NdNb0.97(Si0.5Mo0.5)0.03O4, sintered at 1250℃.
关键词： bond characteristics,Rietveld refinement,NdNbO4,microwave dielectric properties
更新于2025-09-23 15:21:01
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Crystal structure, microwave dielectric properties and low temperature sintering of (Al0.5Nb0.5)4+ co-substitution for Ti4+ of LiNb0.6Ti0.5O3 ceramics
摘要： The phase composition, microstructure, microwave dielectric properties of (Al0.5Nb0.5)4+ co-substitution for Ti site in LiNb0.6Ti0.5O3 ceramics and the low temperature sintering behaviors of Li2O-B2O3-SiO2 (LBS) glass were systematically discussed. XRD patterns and EDS analysis result confirmed that single phase of Li1.075Nb0.625Ti0.45O3 solid solution was formed in all component. The increase of dielectric constant (εr) is ascribed to the improvement of bulk density. The restricted growth of grain has a negative influence on quality factor (Q×f) value. The τf value could be continuously shifted to near zero as the doping content increases. Great microwave dielectric properties were obtained in LiNb0.6Ti(0.5-x)(Al0.5Nb0.5)xO3 ceramics (x = 0.10) when sintered at 1100℃ for 2 h: εr = 70.34, Q×f = 5144 GHz, τf = 4.8ppm/℃. The sintering aid, LBS glass, can effectively reduce the temperature and remain satisfied microwave performance. Excellent microwave dielectric properties for x = 0.10 were obtained with 1.0 wt. % glass: εr = 70.16, Q×f = 4153 GHz (at 4 GHz), τf = -0.65ppm/℃ when sintered at 925℃ for 2 h.
关键词： LiNb0.6Ti0.5O3 ceramics,low temperature sintering,Li2O-B2O3-SiO2 (LBS) glass,microwave dielectric properties
更新于2025-09-10 09:29:36
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Influence of Bi Substitution on the Microstructure and Dielectric Properties of Gd3Fe5O12 Ceramics
摘要： The exponential growth in microwave communications in recent years demands innovations and high yield microwave materials. Rare earth iron garnets are well known for their remarkable performance in microwave devices owing to their superior features. In this work we investigate the microstructure and dielectric properties of Bismuth substituted Gd3Fe5O12 ceramics prepared by the conventional solid state reaction route. The variation of lattice parameter, microstructure, permittivity, quality factor and temperature coef?cient of resonant frequency (sf) of Gadolinium Iron Garnet (GIG) with several concentrations of bismuth was investigated. The Bi3+ ion is effectively incorporated into Gadolinium Iron Garnet, due to which the sintering temperature is considerably reduced, and the densi?cation is improved signi?cantly. Moreover, with increase in Bi concentration, the dielectric constant of GIG also increases, while the quality factor is slightly reduced, which is correlated with the higher ionic polarizability of bismuth. At an appreciably low sintering temperature of 1050(cid:2)C, Gd2BiFe5O12 possess a porosity corrected relative permittivity value of 27.3 ± 0.2, unloaded quality factor (Qu 9 f) of 2990 ± 60 GHz (f = 7.3 GHz) and temperature coef?cient of resonant frequency + 60 ± 1 ppm/(cid:2)C.
关键词： microstructure,Low-temperature sintering,microwave dielectric properties,garnet structure
更新于2025-09-09 09:28:46