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Double-layer Electromagnetic Wave Absorber Based on Carbon Nanotubes Doped with La(NO3)3 and Fe3O4 Nanoparticles
摘要: Double-layer structure absorbing materials based on the impedance matching principle and transmission line theory can effectively improve the electromagnetic wave absorbing properties. In this paper, the electromagnetic wave absorbing properties of double-layer absorbers (MWCNT)-La(NO3)3/polyvinyl chloride (PVC) and MWCNT-Fe3O4/PVC composites had been taken turns as the absorption layer and matching layer, were investigated in 2 – 18 GHz range. The absorbing properties of single- and double-layer structure and different each-layer thickness with two types of combinations were compared. The results showed that the design of double-layer structure for composites could effectively broaden the absorption frequency area, and increase the absorption intensity. When MWCNT-La(NO3)3/PVC composite were used as absorption layers with 0.6 mm thickness, the absorption bandwidth (< – 15 dB or > 97 %) of double-layer composite was the widest, reaching a maximum of about 3.36 GHz, and the absorption peak value was also the lowest about – 46.02 dB at 16.24 GHz.
关键词: La(NO3)3,multiwall carbon nanotubes,Fe3O4,electromagnetic wave absorbing properties
更新于2025-09-23 15:22:29
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Ni3S2@MWCNTs films for effective counter electrodes of dye-sensitized solar cells
摘要: Composite films nickel sulfide (Ni3S2) nanoparticles were grown on multiwall carbon nanotubes (MWCNTs) and in situ coated onto conducting glass substrates by the hydrothermal process at 170 °C. These Ni3S2@MWCNTs films were applied for counter electrodes (CEs) of dye-sensitized solar cells (DSSCs). In this work, nanostructure, crystalline structure, electrochemical activities and electron-charge transfer resistance of CEs were studied. In addition, the effective surface areas of CEs were analyzed and discussed as well. The power conversion efficiency (PCE) enhancement of up to 7.48%, compared with that of Ni3S2-DSSC, was demonstrated for a Ni3S2@MWCNTs DSSC.
关键词: Counter electrode,Ni3S2,Dye-sensitized solar cell,Hydrothermal method,Multiwall carbon nanotubes
更新于2025-09-16 10:30:52
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Excellent ambipolar gas sensing response of Eu[Pc(OC4H9)8]2/acidified multiwalled carbon nanotubes hybrid at room temperature
摘要: A new hybrid material has been developed by mixing a sandwich-type double-decker, Eu[Pc(OC4H9)8]2 = 2,3,9,10,16,17,23,24-octabutoxyphthalocyaninate] with acidified multiwalled carbon nanotubes (aMWCNTs) through non-covalent interactions. The UV-vis spectrum, X-ray diffraction and scanning electron microscope have been employed to reveal the J-aggregate mode and optimized morphology of Eu[Pc(OC4H9)8]2 molecules in the Eu[Pc(OC4H9)8]2/aMWCNTs hybrid material. The gas-sensing devices based on this hybrid material are fabricated by a simple solvent-processing quasi-Langmuir–Sh?fer (QLS) progress. The n-type and p-type response is shown by the Eu[Pc(OC4H9)8]2/aMWCNTs hybrid film at room temperature. The detection limit of the hybrid for ammonia and nitrogen dioxide gas is 0.5 ppm and 0.3 ppm, respectively.
关键词: phthalocyanine,gas sensing,multiwall carbon nanotubes,ambipolar organic semiconductor,europium complex
更新于2025-09-12 10:27:22
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Multiwalled carbon nanotube based aromatic volatile organic compound sensor: sensitivity enhancement through 1-hexadecanethiol functionalisation
摘要: Aromatic volatile organic compound (VOC) sensors are attracting growing interest as a response to the pressing market need for sensitive, fast response, low power consumption and stable sensors. Benzene and toluene detection is subject to several potential applications such as air monitoring in chemical industries or even biosensing of human breath. In this work, we report the fabrication of a room temperature toluene and benzene sensor based on multiwall carbon nanotubes (MWCNTs) decorated with gold nanoparticles and functionalised with a long-chain thiol self-assembled monolayer, 1-hexadecanethiol (HDT). High-resolution transmission electron microscopy (HRTEM) and Fourier transform infrared spectroscopy (FTIR) were performed to characterize the gold nanoparticle decoration and to examine the thiol monolayer bonding to the MWCNTs. The detection of aromatic vapours using Au-MWCNT and HDT/Au-MWCNT sensors down to the ppm range shows that the presence of the self-assembled layer increases the sensitivity (up to 17 times), selectivity and improves the response dynamics of the sensors.
关键词: multiwall carbon nanotubes (MWCNTs),vapour sensor,sensitivity,gold-decorated MWCNTs,self-assembled monolayers (SAMs),selectivity
更新于2025-09-11 14:15:04