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Facile-effective Hole Transporting Materials Based on Dibenzo[a,c]carbazole: The Key Role of Linkage Position to Photovoltaic Performance of Perovskite Solar Cells
摘要： Film morphology of hole-transporting layer is proved as the key element to charge transfer and interfacial property in perovskite solar cells. In this text, a new dibenzo[a,c]carbazole (DBC) core with multiple reaction sites has been formed with Y-shape, in which, the phenathrene group was integrated as a plane π structure into the common carbazole moiety. Accordingly, three DBC-based hole-transporting materials (HTMs) with varied molecular configurations were synthesized by the introduction of N-(4-methoxyphenyl)-9,9-dimethyl-9H-fluoren-2-amine (F(Me)NPh) as the periphery groups at different linkage positions. Once being applied to perovskite solar cells as HTMs, DBC-2 with the twisted and asymmetric structure achieved the highest conversion efficiency of 20.02%. Also, the corresponding dopant-free device exhibited the PCE of 16.43% and good device stability, under glovebox and ambient conditions.
关键词： hole-transporting materials,dibenzo[a,c]carbazole,perovskite solar cells,molecular configurations,photovoltaic performance
更新于2025-09-11 14:15:04
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Self-assembled NiO microspheres for efficient inverted mesoscopic perovskite solar cells
摘要： Perovskite solar cells (PSCs) with both normal (n-i-p) and inverted (p-i-n) mesoscopic structures usually exhibit higher e?ciency than their planar counterparts because the mesoporous charge transport layers can supply heterogeneous nucleation sites for growing high quality perovskite crystals and enlarged charge separation area for better charge extraction. However, comparing with the achieved extremely high or even the certi?ed world record e?ciency of mesoscopic PSCs, the signi?cant improvement of inverted mesoscopic PSCs has yet been made, mainly owing to the lack of suitable p-type semiconductors for preparing mesoporous hole transport layers (HTLs). Here, an emulsion-based bottom-up self-assembly strategy is used to prepare NiO microspheres from well-dispersed NiO nanocrystals. The self-assembled NiO microspheres are further used to fabricate mesoporous NiO HTLs of the inverted mesoscopic PSCs. The as-prepared mesoporous NiO HTL with self-assembled NiO microspheres can provide more suitable graded energy alignment, better charge carrier dynamics and reduced dark recombination in the device comparing with the inverted planar PSC with NiO nanocrystal HTL, contributing to obviously enhanced photovoltaic performance and nearly eliminated photocurrent-voltage hysteresis. Due to the general strategy of emulsion-based bottom-up self-assembly for microspheres synthesis, it will overcome the shortage of p-type materials for preparing e?cient inverted mesoscopic PSCs.
关键词： Self-assembled NiO microspheres,Photovoltaic performance,Inverted mesoscopic perovskite solar cell
更新于2025-09-11 14:15:04
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[IEEE 2019 24th IEEE International Conference on Emerging Technologies and Factory Automation (ETFA) - Zaragoza, Spain (2019.9.10-2019.9.13)] 2019 24th IEEE International Conference on Emerging Technologies and Factory Automation (ETFA) - Towards robust 6-DoF detection in uncontrolled lightning enviroments
摘要： One of the most critical issues that arises when controlling a robot is the necessity to locate itself in the environment. Ranging from industrial processes applications to outdoor mobile robots, landmarks are used to such purpose: by recognizing them, the robots are able to know where they are with the aid of computer vision. Fiducial markers are the cheapest and one of the most common solutions to this issue: 2D planar patterns that embed some information that can be identified using artificial vision techniques. Many different typologies of markers as well as image processing algorithms are being implemented nowadays, using C++ / Python / MATLAB? libraries and ROS as middleware. In this work we have evaluated the robustness of various fiducial marker typologies, documenting the main technical aspects of the used implementations and commenting how each algorithm operates. Aggregated results are presented and discussed, evaluating the different implementations tested.
关键词： fiducial markers,performance evaluation,ROS,pose estimation
更新于2025-09-11 14:15:04
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[IEEE 2019 International Conference on Clean Electrical Power (ICCEP) - Otranto, Italy (2019.7.2-2019.7.4)] 2019 International Conference on Clean Electrical Power (ICCEP) - Application of Dust Mitigation Strategies to Single-Axis-Tracking Photovoltaic Modules in the Semi-Arid Areas of South Africa
摘要： This paper provides field generated data for single-axis-tracker (SAT) photo voltaic (PV) modules subjected to the semi-arid Northern Cape environment of South Africa. The research objectives are the investigation of the effects of dust soiling on PV module performance and the application of experimental dust mitigation methods. This includes the use of a hydrophobic anti-soiling coating and also the execution of a self-cleaning manoeuvre by the SAT systems. Two SAT systems were deployed to serve as experimental platform, from which data was obtained for a three month period (97 days). Raw data validation is established with comprehensive weather monitoring (ambient temperature, wind speed, wind direction, rainfall, pressure, and humidity), irradiance and PV module back sheet temperatures recorded, in accordance with the IEC61724 standard. An intelligent device was used to extract Current-Voltage (I-V) curves from individual PV modules. Maximum PV module power output is derived from the measured I-V curves, validated with a single-diode curve fitting routine. The comparative study between the different PV modules is done with a performance ratio (PR), defined as the temperature and irradiance corrected performance factor of a PV module. Contrary to the initial hypothesis, results indicated that the hydrophobic coating actually promoted dust soiling. The applied self-cleaning capability of the SAT system did not yield any conclusive results as a dust mitigation method. Finally, interesting in-field observations are discussed.
关键词： photovoltaic modules,self-cleaning,hydrophobic coating,performance ratio,dust soiling
更新于2025-09-11 14:15:04
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White LEDs With High Optical Consistency Packaged Using 3D Ceramic Substrate
摘要： Packaging efficiency and optical performances are important indexes for white light-emitting diodes (WLEDs) packaging. In this letter, wafer-level WLEDs packaging were presented by printing phosphor on three-dimensional (3D) ceramic substrate to improve packaging efficiency and optical consistency. The 3D ceramic substrate was prepared by repeatedly electroplating copper cups on the planar direct plated copper (DPC) ceramic substrate. The phosphor concentration was adjusted to realize natural white light. The fabrication errors of the 3D ceramic substrate and the optical performances of WLED modules were analyzed to evaluate the optical consistency of the WLED modules packaged by using 3D ceramic substrate. Consequently, the fabrication errors of 3D ceramic substrate are less than 1%. When the phosphor concentration was set at 12.5 wt%, the packaged LEDs achieve a natural white light with luminous efficiency (LE) of 94.55 lm/W, correlated color temperature (CCT) of 5915 K, and chromaticity coordinate of (0.3166, 0.3345). The WLED modules exhibit small standard deviations in LE (1%), color rendering index (1%), correlated color temperature (98 K), and high reliability. The results indicate that the WLEDs packaged using 3D ceramic substrate have excellent optical consistency.
关键词： direct plated copper (DPC) ceramic substrate,optical performance,White light-emitting diodes (WLEDs),LED packaging,reliability
更新于2025-09-11 14:15:04
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Microwave-Assisted Synthesis of High-Energy Faceted TiO2 Nanocrystals Derived from Exfoliated Porous Metatitanic Acid Nanosheets with Improved Photocatalytic and Photovoltaic Performance
摘要： A facile one-pot microwave-assisted hydrothermal synthesis of rutile TiO2 quadrangular prisms with dominant {110} facets, anatase TiO2 nanorods and square nanoprisms with co-exposed {101}/[111] facets, anatase TiO2 nanorhombuses with co-exposed {101}/{010} facets, and anatase TiO2 nanospindles with dominant {010} facets were reported through the use of exfoliated porous metatitanic acid nanosheets as a precursor. The nanostructures and the formation reaction mechanism of the obtained rutile and anatase TiO2 nanocrystals from the delaminated nanosheets were investigated. The transformation from the exfoliated metatitanic nanosheets with distorted hexagonal cavities to TiO2 nanocrystals involved a dissolution reaction of the nanosheets, nucleation of the primary [TiO6]8? monomers, and the growth of rutile-type and anatase-type TiO2 nuclei during the microwave-assisted hydrothermal reaction. In addition, the photocatalytic activities of the as-prepared anatase nanocrystals were evaluated through the photocatalytic degradation of typical carcinogenic and mutagenic methyl orange (MO) under UV-light irradiation at a normal temperature and pressure. Furthermore, the dye-sensitized solar cell (DSSC) performance of the synthesized anatase TiO2 nanocrystals with various morphologies and crystal facets was also characterized. The {101}/[111]-faceted pH2.5-T175 nanocrystal showed the highest photocatalytic and photovoltaic performance compared to the other TiO2 samples, which could be attributed mainly to its minimum particle size and maximum specific surface area.
关键词： high-energy facets,photocatalytic activity,photovoltaic performance,anatase TiO2 nanocrystals
更新于2025-09-11 14:15:04
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Performance evaluation of building-integrated photovoltaic systems for residential buildings in southern India
摘要： The integration of photovoltaic modules into the building structure is a challenging task with respect to power generation of PV module and the effect of incident solar radiation. The performance of building integrated photovoltaic (BIPV) modules varies depending upon the orientation and azimuth angle of the building. In this work, the year-round performance and economic feasibility analysis of grid-connected building-integrated photovoltaic (GBIPV) modules is reported for the hot and humid climatic regional condition at Kovilpatti (9°10'00"N, 77°52'00"E), Tamil Nadu, India. The appropriate mounting structures are provided, to experimentally simulate the performance of GBIPV modules at various orientations and inclination angles (0° to 90°). The result indicated that the optimum orientation for installation of BIPV modules in the fa?ade and walls is found to be east while that for a pitched roof south orientation is recommended. The overall average annual performance ratio, capacity utilisation factor, array capture loss and system losses are found to be 0.83, 23%, 0.07 (h/day), and 0.17 (h/day), respectively. In addition, the economic feasibility of grid connected PV system for residential buildings in Tamil Nadu, India is analysed using HOMER by incorporating both a net metering process and electricity tariff.
关键词： BIPV,performance ratio,HOMER,net metering,grid-connected,Building integrated photovoltaic
更新于2025-09-11 14:15:04
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The effect of indium doping on photovoltaic properties of chemically synthesized zinc oxide thin-film electrodes
摘要： Photovoltaic (PV) performance of chemically synthesized indium-doped zinc oxide (IZO) nanorod electrodes has been investigated by photocurrent density-voltage (J-V). The indium (In) concentration was varied from 2 to 6 at.% for IZO. The J-V measurements as performed under a dark condition and a simulated white light of 80 mW/cm2 confirmed increase in PV performance with the IZO electrodes, making a peak with the 4 at.% In concentration. The investigated properties of the synthesized In-doped ZnO nanorod electrodes (structural and optical) strongly agreed with the PV results and well support the enhanced PV performance of the IZO electrodes. This clearly indicates that IZO electrodes would be preferred against undoped ones in PV solar cell application.
关键词： IZO electrodes,Photovoltaic performance,In concentration,Wurtzite crystal structure,ZnO nanorods
更新于2025-09-11 14:15:04
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Performance evaluation and analysis of polycrystalline photovoltaic plant located in Northern Morocco
摘要： This paper analyzes and studies the performance of 2 kWp grid-connected photovoltaic system installed on the roof of Faculty of Science and Technology, Tangier, Morocco. The used data in this study was measured from January 2015 to December 2016, where the system supplied a total of 7.10 MWh to the local grid, distributed as follows; 3578.22 kWh in 2015 and 3521.77 kWh in 2016. The measured data were used to evaluate the performance parameters of the photovoltaic system, including final yield, performance ratio, capacity factor and system efficiency. During the year 2015, the final yield of the photovoltaic plant was 4.80 kWh/kWp.day, the annual performance ratio was 78.13%, the annual capacity factor was around 20.02%, and the system efficiency was 11.90%. For the year 2016, these parameters were 4.72 kWh/kWp.day, 77.24%, 19.71%, and 11.76% respectively. These performances are compared with data obtained in similar conditions.
关键词： Morocco,Grid-connected,Meteorological data,PV system,Final yield,Performance
更新于2025-09-11 14:15:04
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Laser cladding process of Cobalt and Nickel based hard-micron-layers on 316L-stainless-steel-substrate
摘要： In the present study, two different types of coatings such as Cobalt (Co-Cr-W-C) and Nickel (Ni-Cr-B-Si-C) based layers have produced using a high power of Ytterbium-doped yttrium aluminum garnet (Yb:YAG) disk laser on 316L stainless steel substrate. Then the coatings were analyzed to expose their phase characterization, microstructure, and hardness using X-ray diffraction analysis, electron microscopes and microhardness tester. Further, tribo-test has performed through a ball-on-plate machine to analyze the wear properties of coatings. Besides, worn-surfaces of cladding and surface roughness have examined. The results showed that both Cobalt and Nickel based cladding have exhibited a dendrite homogeneous structure with some changes in shape and grain size due to higher cooling rates. XRD results indicate that the mixing of a γ-Co peak with other metastable phases such as Cr7C3 and Cr23C6 were noticed on Cobalt coating and γ-Ni rich matrix was the most dominant peak in Nickel-based coating. Microhardness of the cladding layers has remarkably increased than the substrate. The wear performance of Nickel cladding has increased than Cobalt cladding and substrate sample, which reveals that Nickel-based laser cladding plays a role in wear resistance. The analyzed wear track indicates that adhesion and abrasion were the two major wear mechanisms.
关键词： cladding,316L,alloys,wear,microstructure,nickel,steel,performance,roughness,stainless,cobalt,surface
更新于2025-09-11 14:15:04