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- 2018
- tumor imaging
- conductivity
- MRI
- EPT
- Electrical properties tomography
- Optoelectronic Information Science and Engineering
- Ghent University
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High-Performance PEDOT:PSS/Hexamethylene Diisocyanate-Functionalized Graphene Oxide Nanocomposites: Preparation and Properties
摘要： Graphene oxide (GO) has emerged as an ideal ?ller to reinforce polymeric matrices owing to its large speci?c surface area, transparency, ?exibility, and very high mechanical strength. Nonetheless, functionalization is required to improve its solubility in common solvents and expand its practical uses. In this work, hexamethylene diisocyanate (HDI)-functionalized GO (HDI-GO) has been used as ?ller of a conductive polymer matrix, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The nanocomposites have been prepared via a simple solution casting method, and have been characterized by scanning electron microscopy (SEM), UV–Vis and Raman spectroscopies, X-ray diffraction (XRD), thermogravimetric analysis (TGA), tensile tests, and four-point probe measurements to get information about how the HDI-GO functionalization degree (FD) and the HDI-GO concentration in the nanocomposite in?uence the ?nal properties. SEM analysis showed a very homogenous dispersion of the HDI-GO nanosheets with the highest FD within the matrix, and the Raman spectra revealed the existence of very strong HDI-GO-PEDOT:PSS interactions. A gradual improvement in thermal stability was found with increasing HDI-GO concentration, with only a small loss in transparency. A reduction in the sheet resistance of PEDOT:PSS was found at low HDI-GO contents, whilst increasing moderately at the highest loading tested. The nanocomposites showed a good combination of stiffness, strength, ductility, and toughness. The optimum balance of properties was attained for samples incorporating 2 and 5 wt % HDI-GO with the highest FD. These solution-processed nanocomposites show considerably improved performance compared to conventional PEDOT:PSS nanocomposites ?lled with raw GO, and are highly suitable for applications in various ?elds, including ?exible electronics, thermoelectric devices, and solar energy applications.
关键词： hexamethylene diisocyanate,PEDOT:PSS,functionalization degree,nanocomposite,optical transmittance,sheet resistance,graphene oxide,mechanical properties
更新于2025-09-04 15:30:14
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Surface-Plasmon Assisted Transmission Through an Ultrasmall Nanohole of ~ 10 nm with a Bull’s Eye Groove
摘要： We simulate the light transmission through an extremely small nanoscale aperture having a 10 nm diameter punctured in a metal ?lm positioned at the center of a plasmonic bull’s eye grating. A considerable directive emission of transmitted light with a divergence angle of 5.7 degrees was observed at 10 μm from the nanohole opening at the frequency of surface plasmon polariton excitation, an con?rmed by measuring the distance dependent transmission amplitude. Observations of the electric ?eld in cross-sectional, near-?eld, and far-?eld views near-?eld enhancement associated with the surface plasmon excitation, and the interference of the electric ?eld light through the nanohole in the near-?eld region is responsible for such a considerable directive emission.
关键词： Plasmons on surface and interface,Optical di?raction,Optical properties of nanostructures
更新于2025-09-04 15:30:14