- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Selectively Photocatalytic Oxidation of Low Concentration Methane over Graphitic Carbon Nitride Decorated Tungsten Bronze Cesium
摘要： Although the traditional thermal catalysis is usually used to convert the methane into value-added products, its high reaction temperature results in low performance-price ratio in conversion of low concentration methane. In this regard, we synthesized a series of mace-like g-C3N4 decorated Cs0.33WO3 nanocomposites for photocatalytic conversion of low concentration methane under mild conditions. The optimized g-C3N4@Cs0.33WO3 (weight ratio = 3:7) photocatalyst selectively converted low concentration methane (1000 ppm) into methanol with yield of 4.38 μmol/h/g under light irradiation and at room temperature. Both performance experiments and trapping experiments verified that the methane activation and methyl oxidation involved in photocatalytic conversion process of methane. The ?O2- firstly activated the methane to methyl on the surface of the g-C3N4 in the composite and then the photogenerated electrons from the Cs0.33WO3 in the composite inhibited the peroxidation and increased the generation of methanol. This research provides a new route to design and synthesize photocatalysts for converting methane into value-added chemicals.
关键词： Selective Conversion,Low concentration methane,Tungsten Bronze Cesium,Photocatalytic Methane Conversion,Graphic Carbon Nitride
更新于2025-09-19 17:15:36
-
TiO <sub/>2</sub> /zeolite Bifunctional (Photo)catalysts for a Selective Conversion of Methanol to Dimethoxymethane: On the Role of Br?nsted Acidity
摘要： In the present work, we report the first example of one-step selective methanol photooxidation to dimethoxymethane (DMM) at room temperature over TiO2/zeolite bifunctional catalysts. The effects of the porosity, basicity/acidity of the zeolites on the selectivity of the reaction are discussed. The role of TiO2 active sites and zeolitic Br?nsted acid sites on the DMM production is reported. As the photocatalytic reaction occurs at room temperature, the influence of the reaction temperature is also investigated to extrapolate the results to thermal catalysis. This study demonstrates a clear synergetic effect of the zeolites on the selectivity of the reaction. They can display an important impact on the selectivity of the photocatalytic reaction even at a low temperature (e.g. room temperature). Based on the obtained results, the reaction mechanism of methanol conversion to DMM is elucidated.
关键词： Br?nsted acidity,dimethoxymethane (DMM),selective conversion,methanol photooxidation,TiO2/zeolite bifunctional catalysts
更新于2025-09-09 09:28:46