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- 2019
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- PIN diode
- reconfigurable structure
- Active frequency selective surface (AFSS)
- multifunctional AFSS (MAFSS)
- label-free detection
- biosensor
- Bloch surface wave
- 1D photonic crystal
- surface wave enhanced fluorescence
- Infrared Thermography
- Optoelectronic Information Science and Engineering
- Materials Science and Engineering
- Optoelectronic Information Materials and Devices
- Ufa State Aviation Technical University
- Chung-Ang University
- BMS College of Engineering
- Fraunhofer Institute for Applied Optics and Precision Engineering IOF
- Sapienza University
- Majmaah University
- Karnataka Institute of Endocrinology and Research (KIER)
- Islamic Azad University
- Aerospace Research Institute
- Tehran University
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Au@Cu Nanoarrays with Uniform Long-Range Ordered Structure: Synthesis and SERS Applications
摘要： The nanostructures with uniform long-range ordered structure are of crucial importance for performance standardization of high-quality surface-enhanced Raman scattering (SERS) spectra. In this paper, we described the fabrication and SERS properties of Au decorated Cu (Au@Cu) nanoarrays. The Cu nanoarrays with uniform long-range ordered structure were first synthesized by in-situ electrochemistry assembly on insulated substrate. The Cu nanoarrays can reach a size of centimeters with strictly periodic nano-microstructure, which is beneficial for the production and performance standardization of SERS substrates. Then Au nanoparticals were decorated on the Cu nanoarrays by galvanic reaction without any capping agent. The obtained Au@Cu nanoarrays exhibit excellent SERS activity for 4-Mercaptopyridine, and the sensitivity limit is as low as 10?8 M. Therefore, this facile route provides a useful platform for the fabrication of SERS substrates based on nano ordered arrays.
关键词： Au nanoparticles,Cu nanoarrays,surface decoration,surface-enhanced Raman scattering (SERS)
更新于2025-09-23 15:23:52
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Silver nanoparticles with reduced graphene oxide for surface-enhanced vibrational spectroscopy of DNA constituents
摘要： Composite of silver nanoparticles with reduced graphene oxide flakes is proposed for surface enhanced vibrational spectroscopy, particularly for detection of adenine and thymine as constituents of deoxyribonucleic acid. Composite was formed by original method implying simultaneous reduction of silver ions and graphene oxide by discharge plasma at the gas–liquid interface. Combination of nanosized silver with reduced graphene oxide provided greater enhancement of Raman light scattering and infrared light absorption in comparison with separately used components. Addition of the composite to water solutions of adenine and thymine allowed detection of these analytes at micromolar concentrations. Composite of nano-silver with reduced graphene oxide can be prospective for surface enhanced spectroscopy as an alternative to the expensive lithographically prepared noble metal substrates.
关键词： Adenine,Surface Enhanced InfraRed Absorption (SEIRA),Thymine,Reduced graphene oxide,Discharge plasma,Silver nanoparticles,Surface Enhanced Raman Scattering (SERS)
更新于2025-09-23 15:23:52
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Reproduction of surface-enhanced resonant Raman scattering and fluorescence spectra of a strong coupling system composed of a single silver nanoparticle dimer and a few dye molecules
摘要： The spectral changes in surface-enhanced resonant Raman scattering (SERRS) and surface enhanced fluorescence (SEF) of single silver nanoparticle dimers adsorbed by near-single dye molecules are reproduced under strong coupling regimes. For the reproduction, the enhancement and quenching factors in SERRS and SEF are derived from the Purcell factors including both radiative and nonradiative plasmon modes. The Purcell factors are estimated using the coupling energies obtained by analyzing the spectral changes in plasmon resonance during SERRS and SEF decay processes on the basis of a classical hybridization model. The model is composed of a plasmon and a molecular exciton with phonon replicas accurately representing the molecular multi-level system. The reproduced SERRS spectral changes are consistent with the experimental ones. Furthermore, the calculated SEF spectral changes can reproduce the experimental ones by phenomenologically assuming transitions from ultra-fast SEF to conventional SEF with decreasing coupling energies.
关键词： strong coupling,hybridization model,silver nanoparticle dimer,dye molecules,Purcell factors,surface enhanced fluorescence,surface-enhanced resonant Raman scattering
更新于2025-09-23 15:23:52
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Cu and Zr surface sites in photocatalytic activity of TiO2 nanoparticles: The effect of Zr distribution
摘要： The present work is focused on the role of ZrO2 modification in the performance of CuO modified TiO2. Zirconia loading leads to formation of more resistant photocatalytic layers compared to samples modified with only copper containing species. Surface modification of mixed phase TiO2 with CuO/ZrO2 improves the degradation of Reactive blue 19 dye under simulated solar irradiation. An in-depth investigation of the catalysts showed that in case of CuO/ZrO2 modification, the covering of the TiO2 surface with zirconium containing species prevents morphological and harmful energetic changes induced by copper species formed on the rutile TiO2 phase at a higher copper loading.
关键词： Hammett indicators,titanium dioxide,surface modification,XAS analysis,surface acidity
更新于2025-09-23 15:23:52
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Surface plasmon resonance on blue GaN-based VCSEL with Al-grating
摘要： Based on the research of surface plasmon (SP) applied to Vertical-Cavity Surface-Emitting Lasers (VCSEL), we proposed a new 465 nm GaN-based VCSEL to enhance illumination by deposit Al rectangular grating onto p-i-n layer. Meanwhile, an increase in the e?ective radiated power was obtained by the control of a surface plasmon mode, which depends strongly on the structural parameters such as material, period, depth and dipole location. Compared to conventional structure, we have a 30% improvement in e?ective radiated power. Such advantages make surface Al-grating be an alternative low-cost and simple technique used in SP-coupled VCSEL for the blue range.
关键词： Finite-di?erence time-domain method,Metal grating,Surface plasmon,Vertical-cavity surface-emitting laser (VCSEL)
更新于2025-09-23 15:23:52
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Bumpy Hollow Gold Nanospheres for Theranostic Application: Effect of Surface Morphology on Photothermal Conversion Efficiency
摘要： The combination of hollow core and rugose surface morphology is highly attractive for photoactive near-infrared (NIR) nanomaterials. Here, we present a facile pH modification to hollow gold nanosphere (HGN) synthesis to enable controlled tuning of the surface morphology from smooth to very bumpy. Unlike other methods, the synthetic protocol does not require harsh surfactants, secondary reducing agents, or organic solvents. The resultant bumpy HGNs (bHGNs) are highly monodisperse with little variation in protrusion length from particle to particle. Mechanistic studies suggest that surface rugosity is mainly controlled by the presence of free OH- ions in solution. We also present the first systematic investigation into the effect of surface morphology on the photothermal conversion efficiency (PCE) of bumpy as well as smooth HGNs, with a maximum PCE reaching 99%. Although expected to have a higher scattering component, the bHGNs retain the excellent PCE of their smooth counterparts, which may be due to efficient reabsorption of scattered light.
关键词： surface plasmon resonance,photothermal conversion efficiency,heat generation,surface morphology,hollow gold nanospheres
更新于2025-09-23 15:23:52
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High-Performance Chromatographic Characterization of Surface Chemical Heterogeneities of Fluorescent Organic–Inorganic Hybrid Core–Shell Silica Nanoparticles
摘要： In contrast to small-molar-mass compounds, detailed structural investigations of inorganic core–organic ligand shell hybrid nanoparticles remain challenging. The assessment of batch-reaction-induced heterogeneities of surface chemical properties and their correlation with particle size has been a particularly long-standing issue. Applying a combination of high-performance liquid chromatography (HPLC) and gel permeation chromatography (GPC) to ultra-small (<10 nm diameter) poly(ethylene glycol)-coated (PEGylated) fluorescent core–shell silica nanoparticles, we elucidate here previously unknown surface heterogeneities resulting from varying dye conjugation to nanoparticle silica cores and surfaces. Heterogeneities are predominantly governed by dye charge, as corroborated by molecular dynamics simulations. We demonstrate that this insight enables the development of synthesis protocols to achieve PEGylated and targeting ligand-functionalized PEGylated silica nanoparticles with dramatically improved surface chemical homogeneity, as evidenced by single-peak HPLC chromatograms. Because surface chemical properties are key to all nanoparticle interactions, we expect these methods and fundamental insights to become relevant to a number of systems for applications, including bioimaging and nanomedicine.
关键词： surface chemistry heterogeneity,high-performance liquid chromatography,nanoparticle characterization,nanoparticle surface functionalization,fluorescence correlation spectroscopy,molecular dynamics,nanoparticle heterogeneity
更新于2025-09-23 15:23:52
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Electron properties of topological insulators. The structure of edge states and photogalvanic effects
摘要： Integrating the ideas of topology and topological transitions into solid-state physics has led to the theoretical prediction and subsequent experimental discovery of topological insulators, a new class of three- or quasi-two-dimensional dielectric crystalline systems exhibiting stable conducting surface states. This paper briefly reviews the electronic properties of topological insulators. The structure of edge and bulk electronic states in two- and three-dimensional HgTe-based topological insulators is described in particular detail. Recent theoretical and experimental results on the interaction of an electromagnetic field with topological insulators and on edge and surface photogalvanic effects are presented.
关键词： photogalvanic effects,topological insulators,edge and surface states
更新于2025-09-23 15:23:52
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Anomalous shape evolution of Ag2O2 nanocrystals modulated by surface adsorbates during electron beam etching
摘要： An understanding of nanocrystal shape evolution is significant for the design, synthesis and applications of nanocrystals with surface-enhanced properties such as catalysis or plasmonics. Surface adsorbates that are selectively attached to certain facets may strongly affect the atomic pathways of nanocrystal shape development. However, it is a great challenge to directly observe such dynamic processes in situ with high spatial resolution. Here, we report the anomalous shape evolution of Ag2O2 nanocrystals modulated by the surface adsorbates of Ag clusters during electron beam etching, which is revealed through in situ transmission electron microscopy (TEM). In contrast to the Ag2O2 nanocrystals without adsorbates, which display the near-equilibrium shape throughout the etching process, Ag2O2 nanocrystals with Ag surface adsorbates show distinct facet development during etching by electron beam irradiation. Three stages of shape changes are observed: a sphere-to-a cube transformation, side etching of a cuboid, and bottom etching underneath the surface adsorbates. We find that the Ag adsorbates modify the Ag2O2 nanocrystal surface configuration by selectively capping the junction between two neighboring facets. They prevent the edge atoms from being etched away and block the diffusion path of surface atoms. Our findings provide critical insights into the modulatory function of surface adsorbates on shape control of nanocrystals.
关键词： surface adsorbates,Ag2O2 nanocrystal,shape evolution,In situ TEM,electron beam etching
更新于2025-09-23 15:23:52
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The bright side of PV production in snow-covered mountains
摘要： Our work explores the prospect of bringing the temporal production profile of solar photovoltaics (PV) into better correlation with typical electricity consumption patterns in the midlatitudes. To do so, we quantify the potential of three choices for PV installations that increase production during the winter months when electricity is most needed. These are placements that favor (i) high winter irradiance, (ii) high ground-reflected radiation, and (iii) steeper-than-usual panel tilt angles. In addition to spatial estimates of the production potential, we compare the performance of different PV placement scenarios in urban and mountain environments for the country of Switzerland. The results show that the energy deficit in a future fully renewable production from wind power, hydropower, and geothermal power could be significantly reduced when solar PV is installed at high elevations. Because the temporal production patterns match the typical demand more closely than the production in urban environments, electricity production could be shifted from summer to winter without reducing the annual total production. Such mountain installations require significantly less surface area and, combined with steeper panel tilt angles, up to 50% of the winter deficit in electricity production can be mediated.
关键词： panel tilt,seasonal energy gap,renewable energy,photovoltaic,surface reflectance
更新于2025-09-23 15:23:52