[IEEE 2019 44th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) - Paris, France (2019.9.1-2019.9.6)] 2019 44th International Conference on Infrared, Millimeter, and Terahertz Waves (IRMMW-THz) - Optoelectronic Properties of Tin-Based Hybrid Metal Halide Perovskite Thin Films for Photovoltaics

摘要： Due to their exceptional optoelectronic properties, hybrid metal halide perovskites films have shown extraordinary success as active layers in solar cells. One potential drawback of hybrid perovskites, however, is that the highest performing devices are currently based around toxic, lead-containing materials. Tin is a promising replacement for lead, p-doping in tin-based materials has prevented them from achieving the efficiencies of their lead-based analogues. Using optical-pump/THz-probe spectroscopy and THz time-domain spectroscopy, we compare the intrinsic and extrinsic optoelectronic properties formamidinium tin triiodide thin films and comment on the fundamental limits to charge transport.