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Rock-salt CdZnO as a transparent conductive oxide
摘要： Transparent conducting oxides (TCOs) are widely used in applications from solar cells to light emitting diodes. Here, we show that the metal organic chemical vapor deposition (MOCVD)-grown, rock-salt CdZnO ternary, has excellent potential as a TCO. To assess this compound, we use a combination of infrared reflectance and ultraviolet-visible absorption spectroscopies, together with Hall effect, to determine its optical and electrical transport characteristics. It is found that the incorporation of Zn produces an increment of the electron concentration and mobility, yielding lower resistivities than those of CdO, with a minimum of 1:96 (cid:2) 10(cid:3)4 X (cid:4) cm for a Zn content of 10%. Moreover, due to a combination of increasing bandgap energy and band filling, the absorption band-edge energy increases from 2.58 eV in CdO up to 2.89 eV for 15% Zn, yielding a largely enhanced transparency in the visible. The low required growth temperatures, together with the scalability of CVD deposition, provide an excellent ground for the integration of this TCO ternary alloy on foreign devices.
关键词： Hall effect,ultraviolet-visible absorption,MOCVD,infrared reflectance,CdZnO,Transparent conducting oxides
更新于2025-09-10 09:29:36
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All-Thiophene-Based Double Helix: Synthesis, Crystal Structure, Chiroptical Property and Arylation
摘要： The all-thiophene-based double helix DH-1 was designed and prepared originally from the selective deprotonation of cyclooctatetrathiophene (tetra[3,4]thienylene, COTh) and following the Negishi coupling reaction with 3,3′-bithiophene. The X-ray crystallographic studies revealed that DH-1 has a double-helical scaffold. The arylations including tetraphenylation and tetrathienylation were efficiently employed to replace the four α-protons of the central COTh of DH-1 with phenyl and thiophenyl groups via cross-coupling reactions. The chiral resolution of rac-DH-1 was fulfilled via chiral high-performance liquid chromatography, and the chiroptical properties were characterized by circular dichroism spectra and optical rotation. Ultraviolet?visible absorption and fluorescence behaviors of DH-1 and its arylation products were also characterized to describe the extended conjugated scaffold.
关键词： ultraviolet?visible absorption,all-thiophene-based double helix,chiroptical properties,chiral resolution,Negishi coupling reaction,fluorescence behaviors
更新于2025-09-09 09:28:46