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Viscosity of chalcogenide glass-formers
摘要： Chalcogenide glass-formers are being used in a remarkable range of various optoelectronic, photonics, photoconducting, sensing and memory device applications. The knowledge of viscosity is essential for the processing of any glass-forming material, in particular for the fabrication of precise optical elements, which is the main application field of chalcogenide glasses. This work presents an extensive collection of all available viscosity data for chalcogenides, including the measurement methods. The Mauro–Yue–Ellison–Gupta–Allan (MYEGA), Arrhenius and VFT equations are used to fit the temperature dependences of viscosity. The viscosity glass transition temperatures, fragilities and apparent activation energies are calculated from these fits. Consequently, these parameters are discussed with regard to the compositional evolution of the respective chalcogenide systems.
关键词： glass transition,chalcogenide,viscous flow,fragility,Viscosity
更新于2025-09-23 15:23:52
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Dynamical processes related to viscous flow in a supercooled arsenic selenide glass-forming liquid: Results from high-temperature 77Se NMR spectroscopy
摘要： Dynamical processes in supercooled AsSe9 liquid are studied using 1D and 2D 77Se NMR spectroscopic techniques. The results demonstrate the coexistence of two distinct dynamical processes: one is a slow process related to the chemical exchange between the various Se environments by bond scission/renewal and the other is the fast Se chain segmental motion, which leads to the rapid averaging of the chemical shift anisotropy. The timescales of these two processes become increasingly similar as the glass transition is approached from above. The slow process is found to be closely coupled to viscosity over the entire temperature range of investigation and its activation energy is consistent with the Se-Se/As bond energies. On the other hand, the activation energy of the fast process is significantly higher, which may be indicative of its cooperative nature. This process becomes coupled to viscosity only in the immediate vicinity of the glass transition.
关键词： Supercooled liquid,Relaxation,Chalcogenide,Viscous flow,Glass transition,NMR spectroscopy
更新于2025-09-11 14:15:04
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Vortex Dynamics and Optical Vortices || Numerical Simulation of Vortex-Dominated Flows Using the Penalized VIC Method
摘要： Vorticity plays a key role in determining fluid flow dynamics, especially in vortex-dominated flows. Vortex methods, which are based on the vorticity-based formulation of the Navier-Stokes equations, have provided deeper insight into physical reality in a variety of flows using vorticity as a primary variable. The penalized vortex-in-cell (VIC) method is a state-of-the-art variant of vortex methods. In the penalized VIC method, Lagrangian fluid particles are traced by continuously updating their position and strength from solutions at an Eulerian grid. This hybrid method retains beneficial features of pure Lagrangian and Eulerian methods. It offers an efficient and effective way to simulate unsteady viscous flows, thereby enabling application to a wider range of problems in flows. This article presents the fundamentals of the penalized VIC method and its implementations.
关键词： pressure,vortex-in-cell method,unsteady viscous flow,vorticity transport equation,vorticity,penalization method
更新于2025-09-10 09:29:36