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Circularly Polarized Rooma??Temperature Phosphorescence and Encapsulation Engineering for MOFa??Based Fluorescent/Phosphorescent WLEDs
摘要： Optical materials with circularly polarized luminescence and room temperature phosphorescence currently attract great attention owing to their unique optoelectronic properties. Herein, via the coordination-induced assembly strategy, a homochiral metal–organic framework (MOF) 1 with high stability and porosity is successfully synthesized by using the achiral triphenylamine-based molecule as the building block. Remarkably, MOF 1 shows circularly polarized luminescence and phosphorescence at room temperature simultaneously, also with excellent anisotropic optical properties. Furthermore, MOF 1 can serve as a nanocontainer to construct dye-encapsulated host–guest systems. Importantly, the multicolor emissions including white-light emission can be achieved. The corresponding color rendering index and correlated color temperature values of light emitting device are 73 and 5541 K, when using dye-loaded MOF 1?RhB 10 (CIE: 0.33, 0.33) as single-phase white light-emitting phosphor. This study first reports circularly polarized phosphorescence based on MOF without precious metals under ambient conditions, and also is first time for phosphorescent polarized materials with high porosity. These results will open up a new pathway to the design of porous chiroptical materials and white-light materials.
关键词： circularly polarized luminescence,host–guest system,room temperature phosphorescence,white light emitting devices,metal–organic frameworks
更新于2025-09-23 15:21:01
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A simple and green synthesis of carbon quantum dots from coke for white light-emitting devices
摘要： Coke is a by-product of coal. This paper reports a simple and green chemical oxidation method for carbon quantum dots (CQDs) from coke for use in novel applications. The CQDs emit blue fluorescence and have a fluorescence quantum yield of 9.2% and blue-green-red spectral composition of 48%. A light-emitting diode (LED) was fabricated by combining the CQDs as a white-light converter with an ultraviolet chip. The Commission Internationale de L'Eclairage chromaticity coordinate (0.31, 0.35) and correlated color temperature (5125 K) of the LED are located in a cool white light zone, suggesting that they have superior potential application in lighting devices.
关键词： carbon quantum dots,white light-emitting devices,fluorescence,coke,chemical oxidation
更新于2025-09-16 10:30:52