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Potassium Induced Phase Stability Enables Stable and Efficient Widea??Bandgap Perovskite Solar Cells
摘要： The incorporation of potassium can remarkably stabilize wide-bandgap perovskites with a high Br content by the synergistic effect of the formation of 2D K2PbI4 at the grain boundaries and the interstitial occupancy in the perovskite lattices, which can effectively reduce the trap density and inhibit ion migration, thus suppressing the nonradiative recombination and photoinduced phase segregation.
关键词： phase segregation,wide-bandgap perovskite solar cells,potassium incorporation,defect passivation
更新于2025-09-23 15:21:01
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Angstrom Thick ZnO Passivation Layer to Improve the Photoelectrochemical Water Splitting Performance of a TiO2 Nanowire Photoanode: The Role of Deposition Temperature
摘要： In this paper, we demonstrate that angstrom thick single atomic layer deposited (ALD) ZnO passivation can significantly improve the photoelectrochemical (PEC) activity of hydrothermally grown TiO2 NWs. It is found that this ultrathin ZnO coating can passivate the TiO2 surface defect states without hampering the carrier’s transfer dynamics. Moreover, a substantial improvement can be acquired by changing the deposition temperature of the ZnO layer (80 °C, and 250 °C) and named as 80 °C TiO2-ZnO, and 250 °C TiO2-ZnO. It was found that the deposition of this single layer in lower temperatures can lead to higher PEC activity compared to that deposited in higher ones. As a result of our PEC characterizations, it is proved that photoconversion efficiency of bare TiO2 NWs can be improved by a factor of 1.5 upon coating it with a single ZnO layer at 80 °C. Moreover, considering the fact that this layer is a passivating coating rather than a continuous layer, it also keeps the PEC stability of the design while this feature cannot be obtained in a thick shell layer case. This paper proposes a bottom up approach to control the electron transfer dynamics in a heterojunction design and it can be applied to other metal oxide combinations.
关键词： deposition temperature,atomic layer deposition,photoelectrochemical water splitting,ZnO passivation,TiO2 nanowire
更新于2025-09-23 15:21:01
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Understanding Temperature-Dependent Charge Extraction and Trapping in Perovskite Solar Cells
摘要： Understanding the factors that limit the performance of perovskite solar cells (PSCs) can be enriched by detailed temperature (T)-dependent studies. Based on p-i-n type PSCs with prototype methylammonium lead triiodide (MAPbI3) perovskite absorbers, T-dependent photovoltaic properties are explored and negative T-coefficients for the three device parameters (VOC, JSC, and FF) are observed within a wide low T-range, leading to a maximum power conversion efficiency (PCE) of 21.4% with an impressive fill factor (FF) approaching 82% at 220 K. These T-behaviors are explained by the enhanced interfacial charge transfer, reduced charge trapping with suppressed nonradiative recombination and narrowed optical bandgap at lower T. By comparing the T-dependent device behaviors based on MAPbI3 devices containing a PASP passivation layer, enhanced PCE at room temperature is observed but different tendencies showing attenuating T-dependencies of JSC and FF, which eventually leads to nearly T-invariable PCEs. These results indicate that charge extraction with the utilized all-organic charge transporting layers is not a limiting factor for low-T device operation, meanwhile the trap passivation layer of choice can play a role in the T-dependent photovoltaic properties and thus needs to be considered for PSCs operating in a temperature-variable environment.
关键词： temperature dependence,charge trapping,recombination,charge extraction,passivation layer
更新于2025-09-23 15:21:01
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Phenylhydrazinium Iodide for Surface Passivation and Defects Suppression in Perovskite Solar Cell
摘要： In recent years, hybrid perovskite solar cells (HPSCs) have received considerable research attention due to their impressive photovoltaic performance and low-temperature solution processing capability. However, there remain challenges related to defect passivation and enhancing the charge carrier dynamics of the perovskites, to further increase the power conversion efficiency of HPSCs. In this work, the use of a novel material, phenylhydrazinium iodide (PHAI), as an additive in MAPbI3 perovskite for defect minimization and enhancement of the charge carrier dynamics of inverted HPSCs is reported. Incorporation of the PHAI in perovskite precursor solution facilitates controlled crystallization, higher carrier lifetime, as well as less recombination. In addition, PHAI additive treated HPSCs exhibit lower density of filled trap states (1010 cm?2) in perovskite grain boundaries, higher charge carrier mobility (≈11 × 10?4 cm2 V?1 s), and enhanced power conversion efficiency (≈18%) that corresponds to a ≈20% improvement in comparison to the pristine devices.
关键词： surface passivation,defect suppression,additive material,perovskite,solar cell
更新于2025-09-23 15:21:01
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Plasmonic Hot-Electron-Induced Control of Emission Intensity and Dynamics of Visible and Infrared Semiconductor Quantum Dots
摘要： Plasmonic hot-electron-assisted control of emission intensities and dynamics of CdSe/ZnS and infrared PbS quantum dots are studied. This is done by exploring the impact of Au/Si and Ag/Si Schottky junctions on the decay rates of such quantum dots when these junctions are placed in close vicinity of a Si/Al oxide charge barrier, forming metal-oxide plasmonic metafilms. Such structures are used to investigate how metal-dependent distributions of hot electrons and their capture via Schottky junctions can lead to suppression of the defect environments of quantum dots, offering a novel platform wherein off-resonant (non-Purcell) plasmonic processes are used to control exciton dynamics. These results show that Ag metafilms can enhance the emission of CdSe/ZnS quantum dots and elongate their lifetimes more than Au metafilms. This highlights the more efficient nature of Ag/Si Schottky junctions for hot electron excitation and capture. These results also show that such junctions can significantly suppress the nonradiative decay rates of PbS quantum dots at frequencies far from the plasmon resonances. These results demonstrate a field-effect passivation of quantum dot defects via entrapment of hot electrons and control of emission intensities and dynamics of quantum dots via the nearly frequency-independent electrostatic field of such electrons.
关键词： hot electrons,passivation,quantum dots,plasmons,metal oxide
更新于2025-09-23 15:21:01
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Surface Regulation of CsPbBr <sub/>3</sub> Quantum Dots for Standard Blue-Emission with Boosted PLQY
摘要： It is demonstrated that, via surface treatment of CsPbBr3 perovskite quantum dots (PeQDs) by introducing small amount of organic ammonium chlorides possessing short alkyl chain (C ≤ 4) in methyl acetate in the typical purification process, the emission can be tuned from green to blue region with boosted photoluminescence quantum yield (PLQY). The Cl? mainly works on the surface of PeQDs to fill bromide vacancy, which generates a passivated mixed-halide surface and avoids formation of defects deep within bandgap. Meanwhile, the replacement of initial long-chain ligands with short chain ammonium moiety benefits the film PLQY. Accordingly, a standard blue emission of 461 nm with a high film PLQY of 52% is accessed and the corresponding colloidal shows a PLQY of 80% at 456 nm. This method is also proved to be a versatile tool to boost the PLQY of PeQDs by using short chain ammonium halides bearing the same X with the initial CsPbX3. A near-unity colloidal PLQY of 97% and 98% is achieved for CsPbBr3 and CsPbI3 respectively. Quantum dots light-emitting diode (QLED) with treated CsPbBr3 affords a standard blue electroluminescence of 459 nm and a maximum external quantum efficiency of 0.3%.
关键词： perovskite quantum dots,vacancy passivation,surface regulation,standard blue emission
更新于2025-09-23 15:21:01
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Enhancing Perovskite Solar Cell Performance through Femtosecond Laser Polishing
摘要： Nonradiative recombination loss is a key process that determines the performance of perovskite solar cells, and how to control it is significant for the research and development of perovskites. Generally, traditional chemical modification/passivation methods are complicated and prone to secondary contamination. Here, we demonstrate femtosecond (fs) laser polishing as a promising technique to ameliorate the surface of perovskite films, to reduce nonradiative recombination loss and improve solar cell performance. The high-intensity fs laser pulses can remove around 20-nm thick perovskite top-layer through ionization process, help to decrease the grain boundary density and enlarge the grain size of perovskite films after recrystallization. We believe that fs laser polishing is a time-effective and highly precise technique which is suitable for large-scaled device production, thus will trigger more applications in optoelectronics.
关键词： femtosecond lasers,perovskites,recombination,passivation,solar cells
更新于2025-09-23 15:21:01
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Channel-Length Dependent Performance Degradation of Thermally Stressed IGZO TFTs
摘要： The focus of this work is on the performance degradation of thermally stressed IGZO TFTs with SiO2 for both the gate dielectric and back-channel passivation material. I-V characteristics of TFTs with bottom-gate (BG) and double-gate (DG) electrode configurations were observed to left-shift and degrade with thermal stress. Experimental results indicate the instability occurs either directly or indirectly due to the influence of H2O within the passivation oxide above the IGZO channel region. An atomic layer deposition (ALD) alumina capping layer applied immediately following the passivation oxide anneal was successful in improving thermal stability. Channel length dependence was observed where longer channel DG devices were more prone to degradation. A hypothesis has been developed with H2O as the expected origin of this phenomenon. Experiments have been specifically designed to establish the feasibility of the proposed mechanism. Furthermore, DG devices which exhibit enhanced thermal stability are presented.
关键词： thermal stability,SiO2 passivation,ALD alumina capping,IGZO TFTs,channel length dependence
更新于2025-09-23 15:21:01
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Improved Interface Contact for Highly Stable All-Inorganic CsPbI2Br Planar perovskite solar cells
摘要： Owing to its suitable bandgap and remarkable thermal stability, all-inorganic perovskite CsPbI2Br has caught the eye of the academic research and industry recently. However, it still suffers from a phase transition due to poor stability at ambient atmosphere. Here, we introduce CsBr as an interfacial layer between the electron transport layer and the CsPbI2Br perovskite absorber layer to induce a more favorable perovskite crystal growth and fabricated devices with a facile structure of (ITO/SnO2/CsBr/CsPbI2Br/Spiro-OMeTAD/Ag). The CsBr buffer layer plays a role in reducing the lattice mismatch so that it cannot only induce and manage the formation of CsPbI2Br film but also significantly enhance the phase stability of the perovskite. After the modification, the devices reveal conspicuous improvement in illuminated, thermal, ambient, and long-term stabilities without any encapsulation. Meanwhile, the device performance is also improved. The unencapsulated CsBr treated device manifests illuminated stability with PCE remaining almost above 80 % of its initial value after long-time exposure, the remarkable thermal stability of remaining over 78 % of the initial values, better humid resistance, and only 13% decline after being stored in N2 glove-box over 40 days.
关键词： interface contact,CsPbI2Br,stability,passivation,buffer layer
更新于2025-09-23 15:21:01
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A passivation mechanism exploiting surface dipoles affords high-performance perovskite solar cells
摘要： The employment of 2D perovskites is a promising approach to tackle the stability and voltage issues inherent in perovskite solar cells. It remains unclear however whether other perovskites with different dimensionalities have the same effect on efficiency and stability. Here, we report the use of quasi-3D azetidinium lead iodide (AzPbI3) as a secondary layer on top of the primary 3D perovskite film that results in significant improvements in the photovoltaic parameters. Remarkably, utilization of AzPbI3 leads to a new passivation mechanism due to the presence of surface dipoles resulting in a power conversion efficiency (PCE) of 22.4 %. The open-circuit voltage obtained is as high as 1.18 V, which is among the highest reported to date for single junction perovskite solar cells, corresponding to a voltage deficit of 0.37 V for a bandgap of 1.55 eV.
关键词： Perovskites,dipoles,work function,surface passivation,solar cells
更新于2025-09-23 15:21:01