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oe1(光电查) - 科学论文

2 条数据
?? 中文(中国)
  • Plasmonic solar cells using mohite Cu2SnS3 nanoparticles

    摘要: In this paper, we introduce a new technique for the synthesis of mohite copper tin sulphide (Cu2SnS3) nanoparticles. The method employed is cost effective, non-vacuum, room temperature colloidal synthesis. Here two sulphur sources are used in the synthesis process, sodium sulphide and thioacetamide where the latter is assumed responsible for the mohite crystal structure. The as-prepared sample was characterized using XRD, Laser Raman Spectrometer, SEM/EDS, UV–VIS-NIR spectrophotometer and FTIR spectrophotometer. The sample synthesized appears greenish-black with a metallic lustre. Due to the presence of free electrons on the nanoparticle surface, surface plasmon resonance occurs at 807 nm. Using the uncertainty principle, the plasmon lifetime has been calculated to be 42.5 ns, which is a reasonably longer lifetime, enabling higher photon absorption. Thus mohite copper tin sulphide nanoparticles have a potential application in the absorber layer of low cost plasmonic solar cells.

    关键词: Absorber layer,Surface plasmon resonance,Copper tin sulphide,Plasmonic solar cells,Mohite CTS

    更新于2025-09-23 15:21:01

  • AN EXPLORATION INTO THE QUANTUM CONFINEMENT OF CTS/NATURAL DYE CORE- SHELL QUANTUM DOTS

    摘要: In this work, we have presented a simple way of changing the confinement energies of Copper Tin Sulphide (CTS) quantum dots using natural dyes as shell material. Tetragonal CTS quantum dots in the size range of 1.7nm- 2.2nm, of bandgaps of 2.48eV and 5.0 eV were prepared by means of a green colloidal synthesis technique. These quantum dots were treated with natural dyes such as onion and beetroot skin dyes. Pelargonidin and Betanin (pigments of onion and beetroot skin dye respectively) formed hydrogen bonding with the capping agent, thus forming a shell around the CTS quantum dots. The change in confinement due to the effect of dye as shell was studied from absorption, photoluminescence and infrared spectroscopic techniques. The transitions occurring were analysed using a theoretical approach. CTS quantum dots, with its high transmittance in a wide range of wavelengths find promising applications in the buffer layer of solar cells.

    关键词: Betanin,Copper tin sulphide,quantum dots,Pelargonidin,colloidal synthesis,quantum confinement

    更新于2025-09-12 10:27:22