- 标题
- 摘要
- 关键词
- 实验方案
- 产品
-
Crystalline Cooperativity of Donor and Acceptor Segments in Double‐Cable Conjugated Polymers toward Efficient Single‐Component Organic Solar Cells
摘要： Capacitive deionization (CDI) has aroused extensive attention as a prospective technology for different ionic species from aqueous solutions. Traditional studies on the removal adsorption and desorption of fluoride from wastewater are energy-intensive and may have harmful effects on the environment. Herein, the feasibility of fluoride removal from wastewater by CDI has been investigated. NiCoAl-layered metal oxide (NiCoAl-LMO) nanosheets and reduced graphene oxide (rGO) composites (NiCoAl-LMO/rGO) were synthesized and used as CDI electrode materials for fluoride ion removal. The as-obtained NiCoAl-LMO/rGO with unique structure and high conductivity is beneficial to the adsorption of fluoride ions. In addition, the introduction of Co element in the laminate enhances the pseudocapacitive behavior of the electrode material. As expected, the CDI system with NiCoAl-LMO/rGO composites as anode and activated carbon treated by nitric acid (H-AC) as cathode exhibits outstanding defluorination performance. The maximum adsorption capacity of NiCoAl-LMO/rGO, 24.5 mg g?1, can be reached when the initial NaF concentration is 500 mg L?1 at 1.4 V applied voltage. The composites also show good cycle stability over 40 consecutive cycles of the CDI defluorination process. The excellent defluorination performance of NiCoAl-LMO/rGO makes it possible for its practical application in wastewater treatment.
关键词： capacitive deionization,defluorination,layered double hydroxides,NiCoAl-LMO/rGO,removal capacity
更新于2025-09-19 17:13:59
-
Nitrogen-Doping Chemical Behavior of Graphene Materials with Assistance of Defluorination
摘要： Heteroatom-doping reactions are essential to achieve advanced graphene-based materials for energy and biological areas. Unfortunately, considerably less is known regarding the detailed reaction pathways up to now. Here, we focus on investigating the nitrogen (N) doping process of fluorinated graphene (FG) under the assistance of defluorination based on modified in situ fourier transform infrared spectroscopy. It was demonstrated FG possesses a higher and more effective reactivity with ammonia in comparison with other graphene derivatives, which enable N-doping to proceed efficiently with assistance of defluorination even at a lower temperature (16.8 at % of N at 300 °C, 19.9 at % of N at 400 °C). Combining with Density functional theory, it was proved that, at the initial reaction step of N-doping, ammonia molecule attacked and substituted the C-F of FG by the new C-NH2. Sequentially, amino group was cyclized to the three-membered ring of ethylenimine. More importantly, the dissociation and migration of C-F bonds facilitates the dissociating of C-C bonds and the recombining of C-N bonds, thus significantly promoting the N atom in ethylenimine ring to transform to the pyridinic-N or graphitic-N in graphene skeleton.
关键词： Fluorinated graphene,Reaction pathway,Defluorination,Nitrogen doping,Two-dimensional chemistry
更新于2025-09-04 15:30:14