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oe1(光电查) - 科学论文

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?? 中文(中国)
  • A Novel Despeckling Method for Medical Ultrasound Images Based on the Nonsubsampled Shearlet and Guided Filter

    摘要: Porous maghemite (PM) was prepared by two-step calcinations. The crystallographic and magnetic changes of PM upon SO4^2? and CO3^2? adsorption were investigated. The crystallite size (~ 27 nm) and PM texture remain unchanged after adsorption. Fourier transform infrared spectra showed that SO4^2? and CO3^2? are adsorbed on the PM mainly through outer- and inner-sphere surface complexations, respectively. X-ray photoelectron spectra showed the increase and decrease of binding energy for Fe 2p3/2 electrons after SO4^2? and CO3^2? adsorption, respectively. Sulfate adsorption increases the magnetic susceptibility (χ) of PM by ~ 4.5%, and decreases the saturation magnetization (Ms) of PM by 24.6%. By comparison, carbonate adsorption decreases χ by ~ 3.7% and increases Ms by 17.8%. The magnetic changes upon SO4^2? and CO3^2? adsorption are attributed both to the electronegativity of anions and the size distribution of PM.

    关键词: Adsorption,Electronegativity,Inorganic anion,Porous maghemite,Magnetic property

    更新于2025-09-11 14:15:04