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Nanostructured apatites grown by laser floating zone
摘要： Apatites (AP) ceramics are important due to their application in the orthopaedics field as bioceramic material. Several processes to produce apatites such as oxyapatite (OAP) and hydroxyapatite (HA) materials are used to apply as a temporary substitute for human bone. In the present work, AP powders were prepared by high-energy ball milling and then by laser floating zone (LFZ) technique to transform into a dense cylinder (fibre). The effect of LFZ processing conditions was assessed by structural and electric characterization. Fibres present strong densification and a uniform polycrystalline microstructure, which could favour the use for natural bone treatments and as bio-sensors. However, further work must be assessed to optimize laser processing conditions.
关键词： Bioceramic,Apatites,Laser floating zone,Bio-sensors,Bone treatment,Hydroxyapatite,Oxyapatite
更新于2025-09-23 15:21:01
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Systematic studies on Sr4La6(SiO4)6M2:Eu3+ (M?=?F/Cl) phosphors: effects of the halogen anions on photoluminescence
摘要： We successfully prepared Sr4La6(SiO4)6F2:Eu3+ (SLSOF:Eu3+) and Sr4La6(SiO4)6Cl2:Eu3+ (SLSOC:Eu3+) oxyapatite phosphors via the traditional solid-state method. The phosphors’ structure and photoluminescence properties were investigated by scanning electron microscope (SEM), X-ray powder diffraction (XRD), photoluminescence (PL) spectroscopy, ultraviolet–visible spectra and temperature-dependent emission spectra. Among them, the irregular morphology of SLSOF and SLSOC particles was displayed by SEM images, and the phase formation of both sets of phosphors was illustrated by XRD analysis. Additionally, PL spectra indicated that the phosphor could be efficiently excited by the near ultraviolet (NUV) light, and then emitted shining red light, agreeing well with that the calculated color coordinates are within the red region. Comparatively, the luminescence intensity of SLSOF:Eu3+ is higher than that of SLSOC:Eu3+ on the basis of the greater electronegativity of F?, which directly leads to the enhancement of 5D0→7F2 transition. The temperature-dependent emission spectra indicated that samples have excellent thermal stability. Internal quantum efficiency value of phosphors were calculated. These results indicated that the halogen anions of these Sr4La6(SiO4)6M2:Eu3+ play important roles in their PL properties and both phosphors have great potential to serve as red emitting phosphor for NUV white light emitting diodes.
关键词： oxyapatite phosphors,Sr4La6(SiO4)6Cl2:Eu3+,white light emitting diodes,photoluminescence,Sr4La6(SiO4)6F2:Eu3+
更新于2025-09-23 15:21:01