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Dy(III)-induced aggregation emission quenching effect of single-layered graphene quantum dots for selective detection of phosphate in the artificial wetlands
摘要： Carbon quantum dots (CQDs), prepared by one-step hydrothermal treatment of perylene-3,4,9,10-tetra-carboxylic dianhydride (PTCDA) and triethylamine (TEA), could be exfoliated or delaminated into single-layered graphene quantum dots (s-GQDs) with methanol for the first time, with fluorescence (FL) emission at 500 nm when excited at 417 nm. The s-GQDs, with more sufficient carboxyl groups on the surface than CQDs, could be induced to be aggregated by metal ion dysprosium (Dy3+), resulting in aggregation-induced emission quenching effect subsequently. However, the presence of phosphate (PO4 3-) destroys the Dy3+-induced aggregates of s-GQDs owing to the strong coordination between Dy3+ and PO4 3-, inducing the FL emission recovery of the s-GQDs and providing selective detection method of PO4 3- in the artificial wetlands with the linear range of 0.2–30 μM and determination limit of 0.1 μM (3σ).
关键词： s-GQDs-Dy3+ system,Phosphate detection,Single-layered graphene quantum dots,Carbon quantum dots
更新于2025-11-14 17:04:02
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[IEEE 2018 IEEE International Conference on Electro/Information Technology (EIT) - Rochester, MI, USA (2018.5.3-2018.5.5)] 2018 IEEE International Conference on Electro/Information Technology (EIT) - Electrochemical Phosphate Sensors Using Silver Nanowires Treated Screen Printed Electrodes
摘要： Essential biomolecules of the human body and plant growth depend upon the proper amount of phosphate ions. Phosphorus has critical values in both agricultural and biomedical applications. There is a need for inexpensive, portable, repeatable, highly sensitive and field deployable sensors with wide detection range to monitor the health of water system and to develop an electrochemical phosphate sensor using novel ammonium molybdate (AMT/AgNWs) modified screen printed electrode (SPE) for phosphate detection to achieve simplicity, high sensitivity, wide detection range, and high repeatability and portability. The cyclic voltammetry measurements exhibited the sensitivities of AMT modified SPE without and with AgNWs are 0.1 μA/μM and 0.71 μA/μM, respectively. The use of highly conductive AgNWs significantly increased the sensitivities of the AMT/SPE. Besides, AgNWs and AMT modified SPE (AMT/AgNWs/SPE) showed a very wide detection range of 5 μM -1 mM. Moreover, the proposed sensor demonstrated a good repeatability and recovery. Our work suggests that AMT/AgNWs/SPE is promising for simple, low-cost, and portable phosphate ion detection.
关键词： phosphate detection,ammonium molybdate,screen printed electrodes,electrochemical phosphate sensors,silver nanowires
更新于2025-09-10 09:29:36