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ZIF-8 derived hollow CuO/ZnO material for study of enhanced photocatalytic performance
摘要： Tetracycline hydrochloride (TC) is a broad-spectrum antibiotic extensively used in medical and veterinary fields. However, its excess harms the environment and human health. Recently, construction of CuO/ZnO heterojunctions has a very good effect in the treatment of organic matter in water. In this study, we used zeolite imidazolate framework (ZIF-8) as initial material to synthesize porous and hollow CuO/ZnO photocatalysts for catalytic degradation of TC. The results show that the synthesized CuO/ZnO has the characteristics of porous hollow polyhedron when the molar ratio of Cu and Zn is 0.1. Obviously, photocatalytic degradation rate was better comparing to CuO/ZnO nanoparticles as well as pure ZnO and CuO particles, respectively, which could reach 87% at 60min under visible light (λ>420 nm) and has good stability. Porous hollow CuO/ZnO composites are very promising for effective and environmentally friendly degradation of tetracycline hydrochloride in water.
关键词： Photocatalysis,Tetracycline hydrochloride,Zeolite imidazolate frameworks (ZIF-8),Hollow CuO/ZnO
更新于2025-11-14 17:04:02
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Enhanced photocatalytic activity of hydrogenated BiVO4 with rich surface-oxygen-vacancies for remarkable degradation of tetracycline hydrochloride
摘要： In this work, for the first time the hydrogenation treatment was employed to introduce oxygen vacancies on the surface of BiVO4 (BVO) particles, and the influence of hydrogenation on the morphological structure and photocatalytic activity of BVO was explored. Compared to the pristine BVO, a disordered amorphous layer was observed on the surface of the hydrogenated BVO (HBVO) sample. The disordered layer was due to the formation of surface oxygen vacancies in HBVO, as verified by X-ray photoelectron spectroscopy (XPS) and electron paramagnetic resonance (EPR) spectra. Meanwhile, the band gap of HBVO was slightly narrowed accompanying with a higher optical absorption ability. The photocatalytic measurements demonstrated that under 30 min visible light (λ ≥ 420 nm) illumination the HBVO sample could photocatalytically degrade 98% of tetracycline hydrochloride (TCH), which was much higher than the pristine BVO (~52%), and the calculated pseudo-first-order degradation rate constant (k) of HBVO (~0.118 min?1) was about 5 times that of BVO, confirming that the hydrogenation treatment could significantly improve the photocatalytic activity of BVO. In addition, the photocatalytic mechanism of HBVO for enhanced photocatalytic TCH removal was also discussed. The present work demonstrates the feasibility of employing the hydrogenation treatment to develop highly efficient visible light BVO-based photocatalysts for photocatalytic removal of antibiotics, and also deepens the understanding of the correlation between surface oxygen vacancies and photocatalytic performance of semiconductor photocatalysts.
关键词： BiVO4,Photocatalytic activities,Tetracycline hydrochloride removal,Hydrogenation,Surface oxygen vacancies
更新于2025-09-23 15:23:52
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Construction of flower-like MoS2/Ag2S/Ag Z-scheme photocatalysts with enhanced visible-light photocatalytic activity for water purification
摘要： Flower-like MoS2/Ag2S/Ag nanocomposites have been elaborately designed and synthesized successfully for the first time. The prepared MoS2/Ag2S/Ag nanocomposites as a novel photocatalysts present effective photocatalytic performance for the photodegradation of congo red (CR), tetracycline hydrochloride (TC-HCl) and disinfection for Pseudomonas aeruginosa (P. aeruginosa). For the photodegradation of TC-HCl, the effect of the pH of the initial solution and photocatalysts dosage was investigated. Furthermore, intermediates of TC-HCl degradation were verified by GC–MS analysis and the possible pathway of the photodegradation was also proposed. The electron paramagnetic resonance (EPR) technique and trapping experiments verified the electron transport path is Z-scheme system (PS-C-PS). Among them, Ag as an electron mediator enhanced the electron transmission rate and accelerated the separation efficiency of photogenerated carriers.
关键词： MoS2/Ag2S/Ag,Photocatalytic,Tetracycline hydrochloride,Water disinfection,Z-scheme
更新于2025-09-23 15:23:52
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Photocatalytic degradation of tetracycline hydrochloride over rugby-like ?2-Ga <sub/>2</sub> O <sub/>3</sub> with a 3D hierarchically assembled porous structure for environmental remediation
摘要： A novel rugby-like β-Ga2O3 with 3D hierarchically assembled porous structures was successfully constructed through a facile precipitation-calcination method. The synthesized Ga2O3 materials were used to the photocatalytic degradation of tetracycline hydrochloride (TC·HCl) and the effects of calcination temperature on photocatalytic activity were discussed. The conversions of TC·HCl over Ga2O3-900 was 99.0% for Ga2O3-900 after 25 min UV-light irradiation, which was higher than those of commercial Ga2O3 (71.2%) and P25 (82.9%). The best photocatalytic activity of Ga2O3-900 could be attributed to the large specific surface area, intrinsic electronic properties and stable 3D hierarchically assembled porous structure. Based on the liquid chromatography quadrupole time-of-flight mass spectrometry (LC-QTOF-MS) analysis, the photocatalytic mechanism of Ga2O3 and feasible degradation pathway of TC·HCl were proposed. We believe that the present study can exploit an effective avenue to design the photocatalysts with 3D hierarchical porous structures to meet ever-increasing environmental remediation requirements.
关键词： β-Ga2O3,photodegradation pathway,nano-porous structures,tetracycline hydrochloride,optical properties
更新于2025-09-23 15:21:01
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Construction of 1D Ag-AgBr/AlOOH Plasmonic Photocatalyst for Degradation of Tetracycline Hydrochloride
摘要： In this work, the highly ef?cient and low-cost Ag-AgBr/AlOOH plasmonic photocatalyst is successfully prepared via a simple and mild wet-chemical process and used for degrading high concentration methylene blue (MB) and tetracycline hydrochloride (TCH). The optimized 6-Ag-AgBr/AlOOH sample showed a 79% decomposition of TCH in 2 h, which is almost two times higher than that of bare AgBr (37%). For degrading MB, the photocatalytic activity of 6-Ag-AgBr/AlOOH (decomposing 84% in 2 h) showed a large enhancement as compared to bare AgBr (only 57%). The TEM, HRTEM, XRD, DRS, and XPS characterization results con?rm that Ag-AgBr is a composite catalyst formed by loading Ag nanoparticles onto AgBr surfaces and then loaded on to AlOOH. The possible mechanism proposed is that ?O?2 and ?OH radicals produced under sun light are the main active species for degrading MB and TCH. It is hoped that this work will open a new gateway to the synthesis of highly ef?cient and low-cost Ag-AgBr/AlOOH plasmonic photocatalysts for degrading organic pollutants.
关键词： tetracycline hydrochloride,degradation,Ag-AgBr/AlOOH,plasmonic photocatalyst,methylene blue
更新于2025-09-19 17:13:59
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A novel poly(triazine imide) hollow tube/ZnO heterojunction for tetracycline hydrochloride degradation under visible light irradiation
摘要： A novel poly(triazine imide) hollow tube (PTI)/ZnO heterojunction was prepared by a molten salts method. The photocatalyst was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–vis diffuse reflectance spectroscopy (DRS) and photoluminescence (PL) spectroscopy, respectively. The results showed the ZnO nanoparticles were successfully coupled into the PTI hollow tube to form PTI/ZnO heterojunction. The degradation of tetracycline hydrochloride (TC) under visible light irradiation was used to evaluate the activity of photocatalyst. The PTI/ZnO-6 wt% heterojunction exhibits the highest photocatalytic activity, which can degrade almost all TC within 90 min. The kinetic constant of degradation reaction with PTI/ZnO-6 wt% heterojunction (0.034 min?1) is about 5 times as high as that of the PTI (0.0070 min?1). A possible photocatalytic mechanism for heterojunction according to the energy-band theory was proposed.
关键词： ZnO,Tetracycline hydrochloride,Visible light photocatalytic,Poly(triazine imide),Hollow tube
更新于2025-09-10 09:29:36
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Synthesis of In2S3/UiO-66 hybrid with enhanced photocatalytic activity towards methyl orange and tetracycline hydrochloride degradation under visible-light irradiation
摘要： In this study, a series of In2S3/UiO-66 (ISU) hybrids have been fabricated through the growth of In2S3 nanoparticles onto the surface of UiO-66 via a facile hydrothermal process. The as-obtained samples have been characterized by PXRD, SEM, TEM, XPS, UV–Vis DRS, PC, PL and BET. The photocatalytic performance is evaluated by methyl orange (MO) and tetracycline hydrochloride (TCH) degradation under visible light irradiation. The results show that the In2S3/UiO-66 hybrids exhibit a higher photocatalytic activity than that of the pure In2S3 and UiO-66. Interestingly, the ISU-40% possesses the highest photodegradation e?ciency towards MO and TCH, which can be attributed to the strong visible light absorption, high speci?c surface area as well as e?ective separation of photo-generated electrons and holes. In addition, the photocatalysis mechanism in MO degradation process is also explored.
关键词： Hybrids,Visible light,In2S3/UiO-66,Methyl orange,Photocatalysis mechanism,Tetracycline hydrochloride
更新于2025-09-10 09:29:36