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Challenges and opportunities for efficiency boost of next generation Cu(In,Ga)Se <sub/>2</sub> solar cells: prospect for a paradigm shift
摘要： Cu(In,Ga)Se2 photovoltaic technology has notably progressed over the past years. Power conversion efficiencies above 23% were reached in spite of the absorber polycrystalline nature. Although efficiencies are still far from the practical limits, the material quality is approaching that of III-V compounds that yield the most efficient solar cells. High carrier lifetime, low open circuit voltage deficit and external radiative efficiency in single-digit percentage range, suggest the next efficiency boost may arise from the implementation of alternative device architectures. In this perspective paper, we describe the current challenges and pathways to enhance the power conversion efficiency of Cu(In,Ga)Se2 solar cells. Specifically, we suggest the use of non-graded absorbers, integration of charge selective contacts and maximization of photon recycling. We examine these concepts by a semi-empirical device modelling approach, and show that these strategies can lead to efficiencies of 29% under the AM1.5 global spectrum. An analysis whether or not current state-of-the-art Cu(In,Ga)Se2 solar cells already benefit from photon recycling is also presented.
关键词： Cu(In,Ga)Se2,charge selective contacts,photon recycling,power conversion efficiency,solar cells
更新于2025-09-23 15:21:01
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Performance analysis of MAPbI3 based perovskite solar cells employing diverse charge selective contacts: Simulation study
摘要： The rapid development in the field of organo-metal halide perovskite solar cells (PSCs) has led to the report of power conversion efficiency of > 25%. However, their large-scale deployment and possible commercialization endeavor are currently limited due to the presence of high-temperature processed electron transport material (ETM) such as TiO2 and the expensive hole transport material (HTM) in the state-of-the-art devices. By employing Solar Cell Capacitance Simulator (SCAPS)-1D, we attempted to propose low cost charge selective materials as ETM and HTM, which can deliver high photovoltaic performance. For this, the evaluation of TiO2, ZnO and SnO2 as ETMs was validated. Besides this, the role of thickness of ETMs was also investigated in a PSCs using CH3NH3PbI3 as light harvester and Spiro-OMeTAD as HTM. Our simulation results suggests that 90 nm of SnO2 layer outperforms as ETM for device fabrication. Furthermore, in our pursuit to avoid the usage of Spiro-OMeTAD, different organic and inorganic HTMs (P3HT, CuSbS2, Cu2O, CuSCN) have been investigated, and specifically the HTM thickness was optimized for high performance. We have found that by using the configuration of FTO/SnO2 (90 nm)/MAPbI3/CuSCN (100 nm)/Au a PCE of 26.74% with a Voc of 1180 mV can be acheived. The role of metal cathode work function was also studied to replace the expensive gold (Au) electrode.
关键词： Charge selective contacts,Hole transporting materials,Solar cells,Electron transporting materials,Perovskite
更新于2025-09-19 17:13:59