[IEEE 2019 18th International Conference on Optical Communications and Networks (ICOCN) - Huangshan, China (2019.8.5-2019.8.8)] 2019 18th International Conference on Optical Communications and Networks (ICOCN) - Unraveling the Moisture-induced Decomposition Mechanism of Red-Emitting Perovskite CsPbBrI <sub/>2</sub> Nanocrystals and Enhancing their Stability through Copper(II) Substitution

摘要： The red-Emitting perovskite CsPb(BrxI1-x)3 (0<x<1) nanocrystals (NCs) is hindered because of their low structural stability, and the moisture-induced degradation pathways of these red-Emitting perovskite are not well-defined. In the present work, we show that the moisture-induced degradation of CsPbBrI2 NCs spontaneously forms CsPbBr3 (α) and CsPbI3(δ) and other decomposition products. On the other hand, highly stable and luminescent red perovskite CsPbBrI2 NCs were achieved through copper substitution and halide rich passivation strategy. We demonstrated that the incorporation of Cu2+ ions can enhance formation energy, causing a slight lattice contraction, and hence stabilize the cubic phase of these NCs. Cu2+-substituted CsPbBrI2 NCs with higher luminescence were synthesized in a halide-rich passivation method. The highly stable and luminescent Cu2+-substituted CsPbBrI2 NCs can function well as efficient light emitters toward fabrication of the high-performance red perovskite LEDs.